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公开(公告)号:ES2199593T3
公开(公告)日:2004-02-16
申请号:ES99948746
申请日:1999-09-10
Applicant: BASF AG
Inventor: BICHNER KARL-HEINZ , EHLE MICHAEL , PERNER JOHANNES , OPPENLINDER KNUT , HARTMANN MARKUS , GINTHER WOLFGANG
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公开(公告)号:DE60005839D1
公开(公告)日:2003-11-13
申请号:DE60005839
申请日:2000-07-05
Applicant: BASF AG
Inventor: BOECKH DIETER , BORZYK OLIVER , EHLE MICHAEL , NOERENBERG RALF , GOSSELINK P , DUPONT S , ROHRBAUGH H , PRICE N , DEINHAMMER S
IPC: C08G65/329 , C08G73/02 , C11D3/37
Abstract: A zwitterionic polyamine comprising a linear or branched hydrophobic polyamine backbone having 2 to 10 tertiary amino nitrogen atoms and a spacer between two tertiary nitrogen atoms wherein the spacer is, for example selected from C8-C16-alkylene, C5-C15-cyloalkylene, wherein in formula (IV) R = C1- to C22-alkyl or C7-C22-aralkyl and n = 3 to 6, at least one tertiary amine end group of the polyamine backbone contains two groups having formula (V) or (VI), wherein A means an ethylene oxide unit, a propylene oxide unit, a unit of butylene oxides and a tetrahydrofuran unit, n is a number of from 1 to 50, X is an anionic group such as -SO3M, with the proviso that in formula (VI) one X may also be hydrogen and M is hydrogen, alkali metal or ammonium, or contains one group of formula (V) or (VI) and one group selected from radicals consisting of formula (VII), C1- to C22-alkyl and C7-C22-aralkyl, the meaning of A and n is the same as in formula (V) or (VI), said zwitterionic polyetherpolyamine having a molecular weight up to 9000 and optionally containing up to 100 % of the nitrogen atoms quaternized, and a process for the production of zwitterionic polyamines by alkoxylating said polyamines, introducing anionic groups into the alkoxylated polyamines and optionally quaternizing them before or after the introduction of anionic groups. The zwitterionic polyamines are used in detergents.
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公开(公告)号:DE59905502D1
公开(公告)日:2003-06-12
申请号:DE59905502
申请日:1999-09-10
Applicant: BASF AG
Inventor: BUECHNER KARL-HEINZ , EHLE MICHAEL , PERNER JOHANNES , OPPENLAENDER KNUT , HARTMANN MARKUS , GUENTHER WOLFGANG , KRONER MATTHIAS
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公开(公告)号:ZA200201296B
公开(公告)日:2003-04-30
申请号:ZA200201296
申请日:2002-02-15
Applicant: BASF AG
Inventor: BOECKH DIETER , BORZYK OLIVER , DEINHAMMER RANDALL S , DUPONT JEFFREY S , EHLE MICHAEL , GOSSELINK EUGENE P , NOERENBERG RALF , PRICE KENNETH N , ROHRBAUGH ROBERT H
IPC: C08G65/329 , C08G73/02 , C11D3/37 , C08G , C11D
Abstract: A zwitterionic polyamine comprising a linear or branched hydrophobic polyamine backbone having 2 to 10 tertiary amino nitrogen atoms and a spacer between two tertiary nitrogen atoms wherein the spacer is, for example selected from C8-C16-alkylene, C5-C15-cyloalkylene, wherein in formula (IV) R = C1- to C22-alkyl or C7-C22-aralkyl and n = 3 to 6, at least one tertiary amine end group of the polyamine backbone contains two groups having formula (V) or (VI), wherein A means an ethylene oxide unit, a propylene oxide unit, a unit of butylene oxides and a tetrahydrofuran unit, n is a number of from 1 to 50, X is an anionic group such as -SO3M, with the proviso that in formula (VI) one X may also be hydrogen and M is hydrogen, alkali metal or ammonium, or contains one group of formula (V) or (VI) and one group selected from radicals consisting of formula (VII), C1- to C22-alkyl and C7-C22-aralkyl, the meaning of A and n is the same as in formula (V) or (VI), said zwitterionic polyetherpolyamine having a molecular weight up to 9000 and optionally containing up to 100 % of the nitrogen atoms quaternized, and a process for the production of zwitterionic polyamines by alkoxylating said polyamines, introducing anionic groups into the alkoxylated polyamines and optionally quaternizing them before or after the introduction of anionic groups. The zwitterionic polyamines are used in detergents.
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公开(公告)号:DE10227100A1
公开(公告)日:2003-01-23
申请号:DE10227100
申请日:2002-06-18
Applicant: BASF AG
Inventor: WITTKOWSKI LARS , DECKERS ANDREAS , KASEL WOLFGANG , MALLM HEIKE , GAST SIEGFRIED , ZEITZ KATRIN , EHLE MICHAEL
IPC: C08F10/00 , C08F210/02 , C09D191/06
Abstract: A new emulsified wax containing an ethylene/crotonic acid polymerizate forms an excellent component of metallic paints. They are prepared by radical copolymerization of ethylene and crotonic acid in a high pressure autoclave at 160-320 deg C under a pressure of 1000 to 3500 bar in the presence of a regulator such as aliphatic aldehydes or ketones. Independent claims are included for: (1) A process for preparation of aqueous emulsions by emulsification of the wax as above; (2) a floor and carpet cleaning agent containing the aqueous emulsion; (3) a metallic paint containing the wax; (4) a surface coated with the metallic paint; and (5) a process for preparation of metallic paints by mixing of the waxes with hydrocarbons and solvents.
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公开(公告)号:DE69901034T2
公开(公告)日:2002-07-11
申请号:DE69901034
申请日:1999-06-12
Applicant: BASF AG
Inventor: BOECKH DIETER , EHLE MICHAEL , ROSER ANGELIKA , MOHR JUERGEN , CLEARY ALBERT , ZHANG SHULIN , GOSSELINK PAUL
Abstract: The present invention relates to an alkoxylated polyalkyleneimine soil dispersant having the formula: wherein R is C2-C6 linear alkylene, C3-C6 branched alkylene, and mixtures thereof; B is a continuation by branching; E is an alkyleneoxy unit having the formula:-(R1O)m(R2O)nR3wherein R1 is 1,2-propylene, 1,2-butylene, and mixtures thereof; R2 is ethylene; R3 is hydrogen, C1-C4 alkyl, and mixtures thereof; m is from about 1 to about 10; n is from about 10 to about 40; w, x and y are each independently from about 4 to about 200; provided at least one -(R1O) unit is attached to the backbone prior to attachment of an -(R2O) unit and further provided m+n is at least 12.
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公开(公告)号:DE10008931A1
公开(公告)日:2001-08-30
申请号:DE10008931
申请日:2000-02-25
Applicant: BASF AG
Inventor: WITTKOWSKI LARS , DECKERS ANDREAS , WEBER WILHELM , WEISS STEFAN , EHLE MICHAEL , GAST SIEGFRIED
IPC: C11D3/37 , C08F8/12 , C08F210/02 , C09D5/02 , C09D123/08 , C11D7/22 , C11D17/00 , C11D17/08 , C08F220/04
Abstract: Emulsifiable ethylene polymers comprising copolymers offrom 90 to 95% by weight of ethylene,from 4 to 10% by weight of one or more C3-C12 alkenecarboxylic acids, andfrom 0 to 1.2% by weight of one or more tertiary esters of the corresponding C3-C12 alkenecarboxylic acids,where the wax has a cinematic melt viscosity of from 800 to 3000 mm2/s, measured at 120° C.;and a process for preparing the novel emulsifiable ethylene polymers, emulsions comprising the novel ethylene polymers, a process for preparing the emulsions from the novel ethylene polymers, and also floor cleaners, car cleaners, leather cleaners and stone cleaners, and coatings for surfaces made from wood, metal, paper, glass or from plastics, comprising aqueous emulsions of the novel emulsifable waxes.
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公开(公告)号:AU1135501A
公开(公告)日:2001-04-30
申请号:AU1135501
申请日:2000-10-10
Applicant: BASF AG
Inventor: BORZYK OLIVER , WILD JOCHEN , HERTEL DIETER , EHLE MICHAEL , BOECKH DIETER
IPC: C07C303/06 , B01J10/02 , C07C305/06 , C08G65/26 , C08G65/334 , C11D3/37
Abstract: A process for the production of zwitterionic polyamines by sulfation of alkoxylated and quaternized amines and subsequent neutralization which comprises continuously sulfating an alkoxylated and quaternized polyamine having at least two tertiary or quaternary amino nitrogen atoms in the molecule and containing at least one quaternized nitrogen atom, in the form of a film having a thickness of from 100 mu m to 4 mm in the absence of a solvent with a sulfur trioxide-containing inert gas at a temperature of up to 90 DEG C.
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公开(公告)号:CA2384138A1
公开(公告)日:2001-04-26
申请号:CA2384138
申请日:2000-10-10
Applicant: BASF AG
Inventor: BORZYK OLIVER , HERTEL DIETER , EHLE MICHAEL , BOECKH DIETER , WILD JOCHEN
IPC: C07C303/06 , B01J10/02 , C07C305/06 , C08G65/26 , C08G65/334 , C11D3/37
Abstract: A process for the production of zwitterionic polyamines by sulfation of alkoxylated and quaternized amines and subsequent neutralization which comprises continuously sulfating an alkoxylated and quaternized polyamine having at least two tertiary or quaternary amino nitrogen atoms in the molecule and containing at least one quaternized nitrogen atom, in the form of a film having a thickness of from 100 .mu.m to 4 mm in the absence of a solvent with a sulfur trioxide-containing inert gas at a temperature of up t o 90 ~C.
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公开(公告)号:BR9911436A
公开(公告)日:2001-03-20
申请号:BR9911436
申请日:1999-06-12
Applicant: BASF AG
Inventor: BOECKH DIETER , EHLE MICHAEL , ROSER ANGELIKA , MOHR JUERGEN , CLEARY JAMES ALBERT , ZHANG SHULIN , GOSSELINK EUGENE PAUL
Abstract: The present invention relates to an alkoxylated polyalkyleneimine soil dispersant having the formula: wherein R is C2-C6 linear alkylene, C3-C6 branched alkylene, and mixtures thereof; B is a continuation by branching; E is an alkyleneoxy unit having the formula:-(R1O)m(R2O)nR3wherein R1 is 1,2-propylene, 1,2-butylene, and mixtures thereof; R2 is ethylene; R3 is hydrogen, C1-C4 alkyl, and mixtures thereof; m is from about 1 to about 10; n is from about 10 to about 40; w, x and y are each independently from about 4 to about 200; provided at least one -(R1O) unit is attached to the backbone prior to attachment of an -(R2O) unit and further provided m+n is at least 12.
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