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    SUPPORTED CATALYST SYSTEM FOR POLYMERIZING ALK-1-ENES
    35.
    发明专利
    SUPPORTED CATALYST SYSTEM FOR POLYMERIZING ALK-1-ENES 未知

    公开(公告)号：CA2283437A1

    公开(公告)日：1998-09-17

    申请号：CA2283437

    申请日：1998-02-18

    Applicant: BASF AG

    Inventor： KRISTEN MARC OLIVER ,  FISCHER DAVID

    IPC: C08F4/646 ,  C08F4/02 ,  C08F4/6192 ,  C08F4/622 ,  C08F4/642 ,  C08F4/645 ,  C08F4/65 ,  C08F4/68 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16

    Abstract: The invention relates to a catalyst system for polymerizing C2 to C12-alk-1-enes containing; A) one organic or inorganic support; B) at least one metallocene complex; C) oligomeric aluminum oxide compounds; D) at least one boron compound of general formula (I) or a cyclic boron compound of general formula (II) or mixtures from boron compounds (I) and (II). The substituents in said formulas (I) and (II) have the following significance: R1 to R4 a C1 to C20 alkyl group which can be substituted by halogen atoms, C6 to C15 aryl groups and/or C1 to C10 alkoxy groups; a C4 to C7 cyclo-alkyl group which can be substituted by halogen atoms, C1 to C10 alkyl groups and/or C1 to C10 alkoxy groups; a C1 to C10 alkoxy or alkyl sulfide group which can be substituted by halogen atoms, C1 to C10 alkyl groups and/or C6 to C15 aryl groups; a C6 to C15 aryl group which can be substituted by halogen atoms, C1 to C10 alkyl groups, C1 to C10 halogen alkyl groups, C4 to C10 cyclo-alkyl groups, C6 to C15 aryl groups, C1 to C10 alkenyl groups, amino groups, monoor dialkyl amino groups, nitro-groups, formyl groups, acetamido-groups and/or C1 to C10 alkoxy groups, or a saturated or unsaturated C3 to C15 heterocycle containing one to three oxygen, sulfur and/or nitrogen atoms in the ring system and which can be substituted by halogen atoms, C6 to C15 aryl groups, additional C3 to C15 heterocycles and/or C1 to C10 alkyl groups; R1 to R4 are also defined as above and also carry one to three additional B(OR')(OR'') groupings or if R1 to R4 contain an aromatic ring, said ring is part of a metallocene system; R' and R'' are the same or different and each signify hydrogen or a C1 to C10 alkyl group.

    39.
    发明专利
    未知

    公开(公告)号：DE4203753A1

    公开(公告)日：1993-08-12

    申请号：DE4203753

    申请日：1992-02-10

    Applicant: BASF AG

    Inventor： LANGHAUSER FRANZ DR ,  LUX MARTIN DR ,  MUELHAUPT ROLF PROF DR ,  FISCHER DAVID

    IPC: C08F4/645 ,  C07F5/06 ,  C08F4/60 ,  C08F4/623 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/642 ,  C08F4/646 ,  C08F4/6592 ,  C08F4/68 ,  C08F10/00 ,  C08F110/06

    Abstract: Catalyst systems for polymerising C2 to C10 alkenes, containing as active components metallocene complexes of metals of sub-groups IV and V of the periodic system, an oligomeric aluminium oxide compound and a cyclic boron compound of general formula (IV) in which R to R are C1 to C10 alkyl groups which may be substituted singly to triply by halogen atoms, C6 to C15 aryl groups or C1 to C10 alkoxy groups; C4 to C7 cycloalkyl groups which may be substituted singly to triply by halogen atoms, C1 to C10 alkyl groups or C1 to C10 alkoxy groups; C1 to C10 alkoxy groups which may be substituted singly to triply by halogen atoms, C1 to C10 alkyl groups or C6 to C15 aryl groups; or C6 to C15 aryl groups which may be substituted singly to fivefold by halogen atoms, C1 to C10 alkyl groups or C1 to C10 alkoxy groups.

    40.
    发明专利
    未知

    公开(公告)号：AT208786T

    公开(公告)日：2001-11-15

    申请号：AT96924832

    申请日：1996-07-01

    Applicant: BASF AG

    Inventor： FISCHER DAVID ,  LANGHAUSER FRANZ ,  STUERMER RAINER ,  KERTH JUERGEN ,  SCHWEIER GUENTHER ,  BRINTZINGER HANS-HERBERT ,  SCHMIDT KATRIN

    IPC: C07F17/00

    Abstract: PCT No. PCT/EP96/02869 Sec. 371 Date Jan. 8, 1998 Sec. 102(e) Date Jan. 8, 1998 PCT Filed Jan. 7, 1996 PCT Pub. No. WO97/03081 PCT Pub. Date Jan. 30, 1997In a process for converting the achiral meso form or the racemate of an ansa-metallocene complex or a mixture thereof into one of its enantiomers, the conversion is carried out photochemically in the presence of an enantiomerically pure auxiliary reagent.

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