PROCESS FOR PREPARING NITROBIPHENYLENE

    公开(公告)号:HU9902419A2

    公开(公告)日:1999-11-29

    申请号:HU9902419

    申请日:1997-03-06

    Applicant: BASF AG

    Abstract: The invention concerns a process for preparing nitrobiphenylene of formula (I) wherein m stands for 1 or 2, R means halogen, R' or OR', R' being a C-organic group which can carry groups which are inert in the reaction conditions, n stands for 0, 1, 2 or 3 and, if n is 2 or 3, the R groups can also be different. According to the invention, a chloronitrobenzene of formula (II) is reacted in the presence of a palladium catalyst and a base in a solvent with a phenyl boric acid (IIIa), one of its alkyl esters of formula (IIIb), R meaning C1-C6 alkyl, or one of its anhydrides. The compounds (I) are suitable as initial products for biphenylamines which are in turn intermediate products for fungicidal plant-growth substances.

    35.
    发明专利
    未知

    公开(公告)号:BR9708047A

    公开(公告)日:1999-07-27

    申请号:BR9708047

    申请日:1997-03-06

    Applicant: BASF AG

    Abstract: The invention concerns a process for preparing nitrobiphenylene of formula (I) wherein m stands for 1 or 2, R means halogen, R' or OR', R' being a C-organic group which can carry groups which are inert in the reaction conditions, n stands for 0, 1, 2 or 3 and, if n is 2 or 3, the R groups can also be different. According to the invention, a chloronitrobenzene of formula (II) is reacted in the presence of a palladium catalyst and a base in a solvent with a phenyl boric acid (IIIa), one of its alkyl esters of formula (IIIb), R meaning C1-C6 alkyl, or one of its anhydrides. The compounds (I) are suitable as initial products for biphenylamines which are in turn intermediate products for fungicidal plant-growth substances.

    36.
    发明专利
    未知

    公开(公告)号:ES2129951T3

    公开(公告)日:1999-06-16

    申请号:ES96900963

    申请日:1996-01-17

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP96/00170 Sec. 371 Date Jul. 7, 1997 Sec. 102(e) Date Jul. 7, 1997 PCT Filed Jan. 17, 1996 PCT Pub. No. WO96/22967 PCT Pub. Date Aug. 1, 1996A process for preparing aromatic or heteroaromatic hydroxylamines of the general formula I (I) where R1 is an unsubstituted or substituted aryl radical or an unsubstituted or substituted hetaryl radical from the pyridine or quinoline groups, by hydrogenation of nitro compounds of the general formula IIR1-NO2(II)where R1 has the meaning indicated above, in the presence of a platinum catalyst on an activated carbon support or in the presence of a palladium catalyst doped with sulfur or selenium on an activated carbon support, by carrying out the reaction in the presence of a nitrogen-substituted morpholine compound of the general formula III (III) R2 being alkyl radicals having 1 to 5 carbon atoms and R3 to R10 being hydrogen atoms or alkyl radicals having 1 to 5 carbon atoms is described.

    37.
    发明专利
    未知

    公开(公告)号:AT178586T

    公开(公告)日:1999-04-15

    申请号:AT96900963

    申请日:1996-01-17

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP96/00170 Sec. 371 Date Jul. 7, 1997 Sec. 102(e) Date Jul. 7, 1997 PCT Filed Jan. 17, 1996 PCT Pub. No. WO96/22967 PCT Pub. Date Aug. 1, 1996A process for preparing aromatic or heteroaromatic hydroxylamines of the general formula I (I) where R1 is an unsubstituted or substituted aryl radical or an unsubstituted or substituted hetaryl radical from the pyridine or quinoline groups, by hydrogenation of nitro compounds of the general formula IIR1-NO2(II)where R1 has the meaning indicated above, in the presence of a platinum catalyst on an activated carbon support or in the presence of a palladium catalyst doped with sulfur or selenium on an activated carbon support, by carrying out the reaction in the presence of a nitrogen-substituted morpholine compound of the general formula III (III) R2 being alkyl radicals having 1 to 5 carbon atoms and R3 to R10 being hydrogen atoms or alkyl radicals having 1 to 5 carbon atoms is described.

    Process for preparing nitrobiphenylene

    公开(公告)号:AU1925797A

    公开(公告)日:1997-10-01

    申请号:AU1925797

    申请日:1997-03-06

    Applicant: BASF AG

    Abstract: The invention concerns a process for preparing nitrobiphenylene of formula (I) wherein m stands for 1 or 2, R means halogen, R' or OR', R' being a C-organic group which can carry groups which are inert in the reaction conditions, n stands for 0, 1, 2 or 3 and, if n is 2 or 3, the R groups can also be different. According to the invention, a chloronitrobenzene of formula (II) is reacted in the presence of a palladium catalyst and a base in a solvent with a phenyl boric acid (IIIa), one of its alkyl esters of formula (IIIb), R meaning C1-C6 alkyl, or one of its anhydrides. The compounds (I) are suitable as initial products for biphenylamines which are in turn intermediate products for fungicidal plant-growth substances.

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