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公开(公告)号:DE4231749A1
公开(公告)日:1994-03-24
申请号:DE4231749
申请日:1992-09-23
Applicant: BASF AG
Inventor: MUELLER HANS-JOACHIM DR , FOLLMER GODOFREDO DR , KONRAD RAINER DR , SAIVE ROLAND DR , LUX MARTIN DR , GOERTZ HANS-HELMUT DR , FUNK GUIDO DR
Abstract: Process for the preparation of a supported catalyst for the polymerisation of alpha -olefins, in which (1) a support gel containing silicon dioxide is prepared by (1.1) introducing a sodium or potassium waterglass solution into a rotating stream of an aqueous mineral acid both longitudinally and tangentially to the stream, spraying the silicic acid hydrosol thus formed in droplet form into a gaseous medium, allowing it to solidify into a hydrogel and freeing the hydrogel thus obtained of salt by washing without prior aging, (1.2) drying the hydrogel resulting from (1.1) to form the support gel, and (2) the support gel (1) is loaded with chromium trioxide or a chromium compound which can be converted into chromium trioxide under the conditions of the process step (3), which results in a chromium-containing support gel, and (3) the chromium-containing support gel (2) is heated in an anhydrous gas stream containing oxygen in a concentration of over 10% by volume for from 10 to 1000 minutes at from 400 to 1100 DEG C, the hydrogel resulting from the process step (1.1) being dried in the process step (1.2) over a time of not more than 60 seconds in a shaping flash dryer at an inlet temperature of from 80 to 400 DEG C .
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32.
公开(公告)号:AT82579T
公开(公告)日:1992-12-15
申请号:AT88116095
申请日:1988-09-29
Applicant: BASF AG
Inventor: GOERTZ HANS-HELMUT DR , STRAUB FERDINAND DR , VOGEL FRIEDRICH DR , FROSCH FRANZ DR , NAEGELE PAUL , RAUBENHEIMER HANS-JUERGEN
IPC: C08F2/06 , C08F4/04 , C08F8/14 , C08F216/18 , C08F222/16
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公开(公告)号:DE4106909A1
公开(公告)日:1992-09-10
申请号:DE4106909
申请日:1991-03-05
Applicant: BASF AG
Inventor: GOERTZ HANS-HELMUT DR , HATZMANN GUENTER DR , OSCHMANN WERNER DR
IPC: C08F2/22 , C08F285/00 , C08L27/06 , C08L51/00
Abstract: The invention relates to graft copolymers obtainable by …… A) Emulsion polymerisation of from 5 to 35% by weight of a monomer mixture comprising …… a1) 60-80% by weight of at least one vinyl aromatic monomer, … a2) 20-40% by weight of at least one ethylenically unsaturated nitrile … a3) 0-10% by weight of at least one di- or polyethylenically unsaturated monomer, … and … B) subsequent emulsion polymerisation, in the presence of the emulsion polymer obtained from step A), of 20-45% by weight of a monomer mixture comprising …… b1) 50-75% by weight of at least one vinyl aromatic monomer, … b2) 25-50% by weight of at least one C1-C18-alkyl acrylate … b3) 0-10% by weight of at least one di- or polyethylenically unsaturated monomer, … and … C) subsequent emulsion polymerisation, in the presence of the emulsion polymer obtained in step B), of 5-35% by weight of a monomer mixture comprising …… c1) 60-80% by weight of at least one vinyl aromatic monomer, … c2) 20-40% by weight of at least one ethylenically unsaturated nitrile … c3) 0-10% by weight of at least one di- or polyethylenically unsaturated monomer, … and … D) subsequent emulsion polymerisation, in the presence of the emulsion polymer obtained in Step C), of 15-45% by weight of a monomer mixture comprising …… d1) 80-99.9% by weight of at least one C1-C18-alkyl acrylate, … d2) 0.1-10% by weight of at least one di- or polyethylenically unsaturated monomer. ……
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公开(公告)号:DE3870072D1
公开(公告)日:1992-05-21
申请号:DE3870072
申请日:1988-07-23
Applicant: BASF AG
Inventor: GOERTZ HANS-HELMUT DR , OFTRING ALFRED DR , VOGEL FRIEDRICH DR
IPC: B01D21/01 , A61K8/72 , A61K8/81 , A61Q5/12 , C02F1/54 , C07C51/58 , C07D233/60 , C08F20/36 , C08F20/52 , C08F20/60 , C08F26/00 , C08F26/02 , C08F120/36 , C08F120/60 , C08F126/02 , H01B1/12 , A61K7/06
Abstract: New water-soluble cationic homopolymers (IA) and new water-soluble copolymers (IB) are obtd. by free radical polymerisation from water-soluble monomers with a polymerisable olefinic double bond and a quat. N atom of the formula (II) and opt. 98-2 (wt.%) polymerisable water-soluble unsatd. comonomers (III) (R1 is 2-4C alkenyl or a gp. of the formula -(CH2)n-X-CO-CR6:CH2 (IV); n is 1-18, X is O or NH, R6 is H or Me, R2 is 1-18C alkyl or 2-18C hydroxyalkyl, R3 is 2-4C alkenyl, 1-18C alkyl or 2-18C hydroxyalkyl or R1+R2+3 + quat. N atom is a 5-6 membered heterocycle substd. by a polymerisable olefinic double bond and opt. contg. another N atom and/or one of two 1-4C alkyl substits.; R4 and R5 are H, 1-28C alkyl or 1-10C alkoxy-substd. methyl; A(-) is the equiv. of an anion except halide.
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公开(公告)号:DE58900265D1
公开(公告)日:1991-10-17
申请号:DE58900265
申请日:1989-02-28
Applicant: BASF AG
Inventor: AYDIN ORAL DR , ROCKSTROH HERMANN , GOERTZ HANS-HELMUT DR
IPC: C07C43/11 , C07C41/00 , C07C67/00 , C08G65/26 , C08L71/02 , C09J157/00 , C09J171/00 , C09J171/02 , C09J201/00 , C09K3/00
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公开(公告)号:CS270222B2
公开(公告)日:1990-06-13
申请号:CS253187
申请日:1987-04-08
Applicant: BASF AG
Inventor: KLIMESCH ROGER G DR , BLECKMANN GERHARD , FARWERCK KARL-PETER , GOERTZ HANS-HELMUT DR , SCHLEMMER LOTHAR
Abstract: Extrudable pharmaceutical mixtures are tableted by a continuous method in which the mixture is extruded and the still deformable extrudate is pressed between two rollers which are driven in opposite directions and possess depressions opposite one another in the roller shell, the form of these depressions determining the tablet shape.
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公开(公告)号:DE3815291A1
公开(公告)日:1989-11-23
申请号:DE3815291
申请日:1988-05-05
Applicant: BASF AG
Inventor: BAUR RICHARD DR , STOECKIGT DIETER , NEUMANN HANS-WERNER DR , GOERTZ HANS-HELMUT DR , WAGNER NORBERT DR
Abstract: The compositions contain as essential components… (a) 1 to 20% by weight of at least one non-ionic surfactant based on alkoxylated fatty alcohols, fatty acids, fatty amines, fatty acid amides or alkanesulphonamides,… (b) 0.1 to 15% by weight of at least one polyether polyol which is obtainable by reaction of 2 to 6-hydric alcohols, which have 2 to 10 C atoms, with alkylene oxides containing 2 to 4 C atoms, and reaction of these reaction products with 1,2-alkylene oxides, alkyl or alkenyl glycidyl ethers containing 8 to 30 C atoms and… (c) 1 to 40% by weight of at least one acid.
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公开(公告)号:DE3807234A1
公开(公告)日:1989-09-14
申请号:DE3807234
申请日:1988-03-05
Applicant: BASF AG
Inventor: DERSCH ROLF DR , WISTUBA ECKEHARDT DR , GOERTZ HANS-HELMUT DR , FISCHER GERHARD DIPL ING , HAARDT AXEL , NEUBERT GERHARD DR
IPC: C09D5/02 , C09D5/00 , C09D7/00 , C09D171/00 , C09D171/02
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39.
公开(公告)号:DE3725449A1
公开(公告)日:1989-02-09
申请号:DE3725449
申请日:1987-07-31
Applicant: BASF AG
Inventor: GOERTZ HANS-HELMUT DR , OFTRING ALFRED DR , VOGEL FRIEDRICH DR
IPC: A61K8/72 , A61K8/81 , A61Q5/12 , C02F1/54 , C08F2/10 , C08F20/36 , C08F20/60 , C08F26/02 , H01B1/12
Abstract: The invention relates to polymers obtained by polymerisation of water-soluble monomers which, in addition to at least one polymerisable olefinic double bond, contain a quaternary nitrogen atom which is substituted by at least one hydroxyalkyl group, and which are in the form of halide-free salts, optionally with further comonomers, and to their preparation and use.
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公开(公告)号:AT29220T
公开(公告)日:1987-09-15
申请号:AT83102132
申请日:1983-03-04
Applicant: BASF AG
Inventor: DENZINGER WALTER , GOERTZ HANS-HELMUT DR , SANNER AXEL DR , HARTMANN HEINRICH DR
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