31.
    发明专利
    未知

    公开(公告)号:AT384112T

    公开(公告)日:2008-02-15

    申请号:AT05770210

    申请日:2005-08-06

    Applicant: BASF AG

    Abstract: Processes for preparing a C5 aldehyde and propene are disclosed, the processes comprising: (a) providing a feedstream, the feedstream comprising butane, 1-butene, 2-butene and 1,3-butadiene, the 1,3-butadiene present in the feedstream in an amount up to 1000 ppm; (b) contacting the feedstream with hydrogen and carbon monoxide in the presence of a hydroformylation catalyst to form a 2-butene-rich butane stream and a C5 aldehyde; (c) separating the 2-butene-rich butane stream and the C5 aldehyde; and (d) contacting the 2-butene-rich butane stream with ethene in the presence of a metathesis catalyst to form a propene-containing hydrocarbon stream.

    PROCESS FOR PREPARING METAL ORGANIC FRAMEWORKS COMPRISING METALS OF TRANSITION GROUP IV

    公开(公告)号:CA2648225A1

    公开(公告)日:2007-10-25

    申请号:CA2648225

    申请日:2007-04-18

    Applicant: BASF AG

    Abstract: The invention relates to methods for producing a porous metal-organic framework material which contains at least one at least bidentate compound that is coordinately bound to at least one metal ion. Said method comprises the step of reacting at least one metal compound with at least one at least bidentate organic compound which is capable of coordinately binding to the metal. The metal ion of the at least one metal compound is selected from the group of metals including titanium, zirconium, and hafnium. The at least bidentate compound is derived from a di-, tri- or tetracarboxylic acid and t he metal compound is an inorganic salt.

    METAL-ORGANIC FRAMEWORK MATERIALS MADE OF ZIRCONIUM

    公开(公告)号:CA2648222A1

    公开(公告)日:2007-10-25

    申请号:CA2648222

    申请日:2007-04-17

    Applicant: BASF AG

    Abstract: The invention relates to a porous metal-organic framework material, containi ng at least one organic bidentate compound that is coordinately bound to at lea st one metal ion, the at least one metal ion being zirconium and the at least o ne at least bidentate organic compound being derived from a di-, tri- or tetracarboxylic acid. The invention also relates to methods for producing sa id materials and to the use thereof.

    METAL ORGANIC FRAMEWORKS OF TRANSITION GROUP III

    公开(公告)号:CA2630035A1

    公开(公告)日:2007-05-24

    申请号:CA2630035

    申请日:2006-11-14

    Applicant: BASF AG

    Abstract: The present invention relates to processes for preparing a porous organometallic framework material, comprising the step of reacting at least one metal compound with at least one at least bidentate organic compound which can bond coordinatively to the metal, in the presence of a non-aqueous organic solvent, the metal being ScIII, YIII or a trivalent lanthanide, and the organic compound having at least two atoms each selected independently from the group consisting of oxygen, sulphur and nitrogen, and via which the organic compound can bond coordinatively to the metal, the reaction taking place with stirring and at a pressure of not more than 2 bar (absolute). The invention further relates to porous organometallic framework materials which have been prepared by this process, and also to their use.

    MESOPOROUS METAL-ORGANIC FRAMEWORK
    38.
    发明专利

    公开(公告)号:CA2618869A1

    公开(公告)日:2007-03-01

    申请号:CA2618869

    申请日:2006-08-16

    Applicant: BASF AG

    Abstract: The present invention relates to a porous metal-organic framework comprising AlIII and at least one at least bidentate compound, wherein the at least one at least bidentate organic compound is a six-membered aromatic hydrocarbon ring A in which one or more ring carbons may be replaced by nitrogen and which has three substituents X and optionally one or more substituents selected from the group consisting of R, NRR′, OR, SR, F, Cl and Br, where R, R′ are each, independently of one another, hydrogen, methyl which may optionally be substituted by one or more fluorine atoms or ethyl which may optionally be substituted by one or more fluorine atoms and each X is, independently of the others, C(═O)O−, C(═S)O−, C(═O)S−, C(═S)S− or a protonated form thereof. The invention further provides a process for preparing it and provides for the use of the new porous metal-organic framework.

    39.
    发明专利
    未知

    公开(公告)号:DE102005022844A1

    公开(公告)日:2006-11-23

    申请号:DE102005022844

    申请日:2005-05-18

    Applicant: BASF AG

    Abstract: The present invention relates to a method for separating off odor substances from gases, comprising gas with at least one filter comprising a porous metal-organic framework material, the framework material comprising at least one, at least bidentate, organic compound which is bound by coordination to at least one metal ion.

    Preparation of propene from 2-butene and isobutene rich feed stream comprises contacting 4 carbon hydrocarbon stream with ethene in a metathesis step, and separating the streams

    公开(公告)号:DE102005009665A1

    公开(公告)日:2006-08-31

    申请号:DE102005009665

    申请日:2005-02-28

    Applicant: BASF AG

    Abstract: Preparation of an ethene stream (C 2), a propene stream (C 3), an isobutene and optionally a 4C-olefin stream (C 4), a 2-methyl-2-butene and optionally 2-butene stream (C 5), and optionally other hydrocarbons containing stream (C x), optionally several separate components containing streams, comprises contacting a C4-hydrocarbon stream with ethene in a metathesis step; and separating the streams. Preparation of an ethene stream (C 2), a propene stream (C 3), an isobutene and optionally 4C olefin stream (C 4), a 2-methyl-2-butene and optionally 2-butene stream (C 5), and optionally other hydrocarbons containing stream (C x), optionally several separate components containing streams, comprises: (A) a metathesis step, in which a C4-hydrocarbon stream, containing at least 2-butene (15 wt.%), at least isobutene (5 wt.%) and 1-butene (less than 5 wt.%) (feed stream), is contacted with ethene in the presence of usual metathesis catalysts; and (B) separation of the streams (C2, C3, C4 and optionally Cx) from the obtained hydrocarbon stream, with the stream (C5) completely or partially led back to the metathesis step. Independent claims are included for methods for preparing feed stream, comprising subjecting naphtha or other hydrocarbon compounds to steam cracking or fluid catalytic cracking (FCC)-process, or dehydrating butane containing hydrocarbon stream and followed by purifying the obtained C4-olefin-mixture containing isobutene, 2-butene, butadiene, optionally butyne and optionally 1-butene, and removing the obtained stream of C4-olefin-mixture; and removing butadiene and butyne by means of selective hydrogenation to butene or butane hydride, or butadiene and butyne by extractive distillation of the obtained C4-olefin-mixture (raffinate I), where the content of 1,3-butadiene is at a maximum of 1000 wt. ppm.

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