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公开(公告)号:DE3919839A1
公开(公告)日:1990-12-20
申请号:DE3919839
申请日:1989-06-17
Applicant: HOECHST AG
Inventor: ESCHER CLAUS DR , DUEBAL HANS-ROLF DR , HARADA TAKAMASA , ILLIAN GERHARD DR , MURAKAMI MIKIO , OHLENDORF DIETER DR
Abstract: The liquid-crystal element described consists of a housing with transparent discs and electrodes, polarisation foils, orientation films, plus a smectic ferro-electric liquid-crystalline material. This FLC material is dielectrically positive (i.e. DELTA epsilon >0), with the result that the liquid-crystal element has a high contrast and, in addition, is switchable even when high voltages (e.g. greater than 15 V) are applied. Unlike LC elements with dielectrically negative material, no change in surface texture occurs under such conditions. The increase in the effective cone angle produced by applying an electric field to the element described above can also be used to produce so-called grey shades.
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公开(公告)号:NO902111A
公开(公告)日:1990-11-14
申请号:NO902111
申请日:1990-05-11
Applicant: HOECHST AG
Inventor: MEIJERE ARMIN DE , DUEBAL HANS-ROLF , ESCHER CLAUS , HARADA TAKAMASA , HEMMERLING WOLFGANG , ILLIAN GERHARD , MUELLER INGRID , MURAKAMI MIKIO , OHLENDORF DIETER , WINGEN RAINER
IPC: G02F1/13 , C07C13/04 , C07C13/28 , C07C22/00 , C07C25/00 , C07C43/184 , C07C43/21 , C07C69/92 , C07C255/45 , C07D213/30 , C07D237/08 , C07D237/14 , C07D237/16 , C07D237/18 , C07D239/26 , C07D239/34 , C07D239/38 , C07D241/12 , C07D241/18 , C07D285/12 , C07D285/125 , C07D285/13 , C07D405/12 , C09K19/20 , C09K19/30 , C09K19/34
CPC classification number: C07D213/30 , C07C43/184 , C07C43/21 , C07C69/92 , C07D239/26 , C07D239/34 , C09K19/30 , C09K19/3066 , C09K19/3444 , C09K19/3469
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公开(公告)号:DE3909355A1
公开(公告)日:1990-09-27
申请号:DE3909355
申请日:1989-03-22
Applicant: HOECHST AG
Inventor: DUEBAL HANS-ROLF DR , ESCHER CLAUS DR , HARADA TAKAMASA , HEMMERLING WOLFGANG DR , ILLIAN GERHARD DR , MUELLER INGRID DR , MURAKAMI MIKIO , OHLENDORF DIETER DR , WINGEN RAINER DR
Abstract: Ferroelectric liquid crystal mixtures are based on at least 2 mixing components of general formula (I) and contain, in addition, at least one optically active dopant from one or more of the following groups: (a) optically active esters of tetrahydrofuran-2-carboxylic acid; (b) optically active aryl-2,3-epoxyalkyl ethers; (c) optically active 1,3-dioxolan-4-yl-ethers. Said mixtures possess high spontaneous polarization and permit substantial compensation of the pitch of the helix in a nematic phase.
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公开(公告)号:DE59107399D1
公开(公告)日:1996-03-28
申请号:DE59107399
申请日:1991-04-10
Applicant: HOECHST AG
Inventor: HARADA TAKAMASA , ROESCH NORBERT DR , WEGENER PETER DR
IPC: C09K19/06 , C09K19/30 , C09K19/32 , C09K19/34 , C09K19/40 , C09K19/54 , C09K19/56 , C09K19/58 , G02F1/13 , G02F1/137
Abstract: A liquid-crystal mixture comprising at least two components and containing, as one component, a macrocyclic compound of the formula (1) … … where a, b, c, d, e and f, independently of one another, are an integer from zero to 4, where a+b+c+d+e+f is >/= 7, and -A-, -B-, -C-, -D-, -E- and -F- are identical or different and are, for example, -CH2-, -CH=CH-, -CO- or -COO-,… results, in FLC displays, in the formation of uniform alignment and in the avoidance of twist states, which is expressed in significantly improved contrast.
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公开(公告)号:DE59107368D1
公开(公告)日:1996-03-21
申请号:DE59107368
申请日:1991-04-10
Applicant: HOECHST AG
Inventor: ESCHER CLAUS DR , ILLIAN GERHARD DR , ROESCH NORBERT DR , HARADA TAKAMASA
IPC: C07D225/02 , C07D273/08 , C07D323/00 , G02F1/133 , C07D405/12 , C07D498/08 , C09K19/54 , C09K19/56 , G02F1/13 , G02F1/1337 , G02F1/137 , G02F1/141 , G09F9/35
Abstract: Addition of coronands and cryptands to FLC-mixtures makes it possible to bring the FLC material into a homogeneous "bookshelf" or "quasi-bookshelf" geometry. When such a FLC mixture is used, displays which have been shock-damaged can be regenerated by applying a suitable electric field for a short period of time.
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公开(公告)号:DE59009764D1
公开(公告)日:1995-11-16
申请号:DE59009764
申请日:1990-07-31
Applicant: HOECHST AG
Inventor: ESCHER CLAUS DR , DUEBAL HANS-ROLF DR , FELDHUES MICHAEL DR , HARADA TAKAMASA , ILLIAN GERHARD DR , MECKLENBURG THOMAS DR , MURAKAMI MIKIO , OHLENDORF DIETER DR , PAMPUS KARL DR
IPC: C08G61/12 , G02F1/1337 , G02F1/141 , G09F9/35
Abstract: Switching and display elements based on ferroelectric liquid-crystals often exhibit a pronounced optical hysteresis which results in the appearance of so-called ghost images. This phenomenon can be markedly reduced or even suppressed if at least one of the two orienting layers are in direct contact with the electrodes and is composed of an electrically conductive polymer of the formula (I): (I) in which R1, R2=independently of each other, H, or straight-chain or branched alkyl or alkoxy containing 1-16 carbon atoms, or halogen, X=S, NH, Y-=BF4-, PF6-, PO43-, AsF6-, SbCl6-, SO42-, HSO4-, alkyl-SO3-, perfluoroalkyl-SO3-, aryl-SO3, F- or Cl-, and n is an integer from 4 to 100 and m is an integer from 1 to 30.
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公开(公告)号:DE59008550D1
公开(公告)日:1995-03-30
申请号:DE59008550
申请日:1990-11-26
Applicant: HOECHST AG
Inventor: ESCHER CLAUS , HARADA TAKAMASA , ILLIAN GERHARD , ROESCH NORBERT , WINGEN RAINER
IPC: C09K20060101 , C09K19/02 , C09K19/34 , C09K19/52 , C09K19/58
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公开(公告)号:AT116676T
公开(公告)日:1995-01-15
申请号:AT91105700
申请日:1991-04-10
Applicant: HOECHST AG
Inventor: HARADA TAKAMASA , ROESCH NORBERT DR , WINGEN RAINER DR
Abstract: The occurrence of twist states in FLC displays can be suppressed by adding ionophores to FLC mixtures. Applicable ionophores are amides of the general formula I (I) wherein R1, R2, R3 and R4 e.g. are alkyl, cyclohexyl, phenyl or benzyl and X is alkylene with -CH2-groups being replaced by -O-, 1,2-phenylene or 1,2-cyclohexylene.
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公开(公告)号:PL165258B1
公开(公告)日:1994-12-30
申请号:PL28803890
申请日:1990-11-30
Applicant: HOECHST AG
Inventor: ESCHER CLAUS , HARADA TAKAMASA , ILLIAN GERHARD , ROESCH NORBERT , WINGEN RAINER
IPC: C09K20060101 , C09K19/02 , C09K19/34 , C09K19/52 , C09K19/58
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公开(公告)号:DE59006153D1
公开(公告)日:1994-07-21
申请号:DE59006153
申请日:1990-03-21
Applicant: HOECHST AG
Inventor: DUEBAL HANS-ROLF , ESCHER CLAUS , HARADA TAKAMASA , HEMMERLING WOLFGANG , ILLIAN GERHARD , MUELLER INGRID , MURAKAMI MIKIO , OHLENDORF DIETER , WINGEN RAINER
Abstract: PCT No. PCT/EP90/00458 Sec. 371 Date Nov. 6, 1991 Sec. 102(e) Date Nov. 6, 1991 PCT Filed Mar. 21, 1990 PCT Pub. No. WO90/11336 PCT Pub. Date Oct. 4, 1990.The novel liquid-crystalline mixtures (in the case of ferroelectric behavior they additionally contain an optically active compound as dope) are based on at least two mixture components of the general formula (I) and at least one carboxylate of the general formula (II), (III) or (IV). (* CHEMICAL STRUCTURE *) (I) (* CHEMICAL STRUCTURE *) (II) X = O or a single bond (* CHEMICAL STRUCTURE *) (III) (* CHEMICAL STRUCTURE *) (IV) The mixtures have favorable properties for use in electrooptical display elements, such as high contrast, low melting point and short switching times.
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