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公开(公告)号:JPH04211640A
公开(公告)日:1992-08-03
申请号:JP6026091
申请日:1991-03-25
Applicant: KAO CORP
Inventor: NAKAGAWA SHOJI , KOJIMA MASAYO , YOKOTA YUKINAGA , YAHAGI KAZUYUKI , TASHIRO KAZUHIRO
IPC: A61K8/30 , A61K8/00 , A61K8/06 , A61K8/42 , A61Q5/00 , B01F17/22 , B01F17/38 , C07C231/02 , C07C233/18 , C10M173/00 , C10N30/00
Abstract: PURPOSE:To obtain a new fatty acid amide having uniform dispersibility to water, satisfying demanding characteristics of cosmetic base, emulsifying agent, lubricant, etc., such as compatibility with various solvents, producible in high purity and in high yield from inexpensive and readily obtainable raw materials. CONSTITUTION:A compound shown 1 [R is 4-27C branched alkyl, preferably group shown by formula II (m and n are 0-20 integer, m+n is 1-20, preferably 20-16 and m is 1-24 integer and m is 0)] such as N-tris (hydroxymethyl)methyl- isostearic acid amide. The compound is obtained by reacting a compound shown by formula 3 with a compound shown by formula 4 to give a compound shown by formula 5 and then hydrolyzing this compound in a mixed solvent of 1-4C alcohol and water.
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公开(公告)号:JPH03277696A
公开(公告)日:1991-12-09
申请号:JP13687290
申请日:1990-05-25
Applicant: KAO CORP
Inventor: YAMADA ISAO , YAMAGUCHI YUKIYOSHI , SUZUKI SATORU , IMANAKA TAKEHIRO , MIZUSHIMA HIROMOTO , NAKAGAWA SHOJI
IPC: C11D1/10 , C11D1/04 , C11D1/12 , C11D1/22 , C11D1/29 , C11D1/68 , C11D1/72 , C11D1/722 , C11D1/83
Abstract: PURPOSE:To improve the detergency on inorganic staining by providing a composition containing a nonionic surface active agent and a specific anionic surface active agent. CONSTITUTION:A nonionic surface active agent, (A), an anionic surface active agent (B) containing 1 or more 6-24C hydrophobic groups and 2 or more anionic groups, the weight ratio of A/B being 100-1/1-20, and having a chelate stability constant with Ca of 2 or more, a Kraft point of 5 deg.C or below when Ca is chelated, and a Ca holding capacity of 50mg (in terms of CaCO3)/g or more, and if necessary, an organic alkaline agent, divalent metal ion sequestering agent, solubilizing agent, saturated or unsaturated 10-20C fatty acid or salt thereof, extending agent, antiredeposition agent, enzyme (stabilizer), bleaching (activating) agent, coloring agent, perfume, preservative, etc., are mixed.
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33.
公开(公告)号:JPH03271265A
公开(公告)日:1991-12-03
申请号:JP6897090
申请日:1990-03-19
Applicant: KAO CORP
Inventor: NAKAGAWA SHOJI , TATEZAWA OSAMU , YOKOTA YUKINAGA
IPC: A61K8/00 , A61K8/44 , A61Q5/02 , C07C231/02 , C07C231/12 , C07C233/47 , C07C233/49 , C11D1/10
Abstract: NEW MATERIAL:An aspartic acid derivative expressed by formula I or salt of said derivative (R is linear or branched 1-21C alkyl or 2-21C alkenyl; R and R are 1-6C alkyl; n is 1-6). EXAMPLE:An N-lauroyl-N-(3-dimethylaminopropyl) aspartic acid. USE:Useful as a low-irritant surfactant. Widely usable in various fields having mild property to skin, excellent resistance to hard water and foaming property with excellent biodegradability. PREPARATION:A compound expressed by formula II (R to R are able to be same or different 1-6C alkyl) is reacted with fatty acid expressed by formula III or a reactive derivative of said acid to obtain a compound expressed by formula IV. Next, the compound is hydrolyzed to afford the aimed compound expressed by formula I. The reaction of the compound expressed by formula II and the compound expressed by formula III is performed at 0-50 deg.C. The compound expressed by formula IV is a new compound.
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公开(公告)号:JPH0236160A
公开(公告)日:1990-02-06
申请号:JP22286888
申请日:1988-09-06
Applicant: KAO CORP
Inventor: KOIKE TOYOMI , MATSUMURA YOSHIHISA , NAKAGAWA SHOJI , SUGITA JUNICHI
IPC: C07C255/29 , C07C231/06 , C07C233/47 , C07C233/49
Abstract: NEW MATERIAL:A compound expressed by formula I (R is 1-21C alkyl or alkenyl; R and R are 1-6C alkyl; n is 1-6) and salt thereof. EXAMPLE:N-Lauroyl-N-(3-dimethylaminopropyl)-beta-alanine. USE:A surfactant mild to skin and having excellent foaming force and hard water resistance and good biodegradability and solubility to water. PREPARATION:A dialkylaminoalkylamine expressed by formula II is reacted with acrylonitrile to give 3-(dialkylaminoalkylamino)propionitrile expressed by formula III, which is then acylated to afford 3-[N-acyl-N-(dialkylaminoalkyl) amino]propionitrile expressed by formula IV. Further, the compound expressed by formula IV is hydrolyzed under an alkali condition to provide the compound expressed by formula I.
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公开(公告)号:JPH0224397A
公开(公告)日:1990-01-26
申请号:JP17414688
申请日:1988-07-13
Applicant: KAO CORP
Inventor: SUGITA JUNICHI , OGINO SHUICHI , HIROTA HAJIME , NAKAGAWA SHOJI
Abstract: PURPOSE:To provide a detergent compsn. having low irritating properties and improved detergency and hard water resistance by using a particular N-acyl-N- dialkylaminoalkylamino acid (salt). CONSTITUTION:A dialkylaminoalkylamine and a mixture of acrylonitrile, hydroxyacetonitrile and a halogenated acetonitrile are cyanoalkylated at -20 to 70 deg.C to prepare a (dialkylaminoalkylamino)alkylnitrile compd. This compd. is reacted with an acyl chloride at -20 to 70 deg.C in a solvent to prepare an acyl compd. This acyl compd. is hydrolyzed at 60 to 105 deg.C under an alkaline condition, neutralized, dehydrated and desalted, thereby obtaining an N-acyl-N- dialkylaminoalkylamino acid (salt) of the formula (wherein R1 is a 1-21C alkyl or alkenyl; each of R2 and R3 is a 1-6C lower alkyl; m is 1-2; and n is 1-6). The product and, if desired, other surfactants, with the balance being water (C), are mixed together and its pH is adjusted to 4-6. As a result, a detergent is obtd in the form of a liq. or a paste.
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公开(公告)号:JPH0141131B2
公开(公告)日:1989-09-04
申请号:JP22088882
申请日:1982-12-16
Applicant: KAO CORP
Inventor: NAKAGAWA SHOJI
IPC: C07C67/08 , A01N37/08 , A01N37/34 , A01N43/08 , A01N43/38 , C07C67/00 , C07C69/753 , C07C201/00 , C07C201/12 , C07C205/12 , C07C205/56 , C07C253/00 , C07C255/38 , C07D209/48 , C07D307/42 , C07D307/45
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公开(公告)号:JPH0129164B2
公开(公告)日:1989-06-08
申请号:JP22088782
申请日:1982-12-16
Applicant: KAO CORP
Inventor: NAKAGAWA SHOJI
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公开(公告)号:JPH0920772A
公开(公告)日:1997-01-21
申请号:JP19245595
申请日:1995-07-04
Applicant: KAO CORP
Inventor: NAKAGAWA SHOJI , TOGASHI HIROYASU , HAGIWARA TOSHIYA
IPC: C07D317/22
Abstract: PROBLEM TO BE SOLVED: To obtain a new cyclic acetal exhibiting liquid state having moderate viscosity near the room temperature, having excellent compatibility with hydrofluorocarbons, producible at a low cost and useful for synthetic lubricating oil and working fluid composition for refrigerator. SOLUTION: The objective compound is expressed by formula I [R is H or methyl and R is a 3-21C (branched) alkyl or R is a 2-21C (branched) alkyl and R is a 2-21C (branched) alkyl], e.g. 4,4'-[oxybis(methylene)]bis[2-methyl-2-(2- methylpropyl)-1,3-dioxolan]. The compound of formula I can be produced by reacting diglycerol of formula II with a compound of formula III or ketal or acetal which is a reactive derivative of the compound of formula III in the presence of an acid catalyst.
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公开(公告)号:JPH0920771A
公开(公告)日:1997-01-21
申请号:JP19245695
申请日:1995-07-04
Applicant: KAO CORP
Inventor: NAKAGAWA SHOJI , TOGASHI HIROYASU , HAGIWARA TOSHIYA
IPC: C07D317/12 , C07D493/04
Abstract: PROBLEM TO BE SOLVED: To obtain a new cyclic acetal exhibiting liquid state having moderate viscosity near the room temperature, having excellent compatibility with hydrofluorocarbons, producible at a low cost and useful for synthetic lubricating oil and working fluid composition for refrigerator. SOLUTION: The objective compound is expressed by formula I [R is H and R is a 3-21C (branched) alkyl, R is methyl and R is a 2-21C (branched) alkyl or R is a 2-21C (branched) alkyl and R is a 3-21C (branched) alkyl] or formula II, e.g. 1.2:3.4-di-O-(1-methylpropylidene)erythritol. The compound of formula I or formula II can be produced by reacting erythritol of formula III with a compound of formula IV or ketal or acetal which is a reactive derivative of the compound of formula IV in the presence of an acid catalyst.
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公开(公告)号:JP2551466B2
公开(公告)日:1996-11-06
申请号:JP22286988
申请日:1988-09-06
Applicant: KAO CORP
Inventor: NAKAGAWA SHOJI , KOIKE TOYOMI , MATSUMURA YOSHIHISA , SUGITA JUNICHI
IPC: A61K8/30 , A61K8/00 , A61K8/06 , A61K8/41 , A61K8/46 , A61Q5/02 , B01F17/38 , C07C303/22 , C07C309/15 , C11D1/28
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