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公开(公告)号：DE2901576A1
公开(公告)日：1980-07-31
申请号：DE2901576
申请日：1979-01-17
Applicant: BASF AG
Inventor： HEINZ GERHARD DIPL CHEM DR , SWOBODA JOHANN DR , PRIEBE EDMUND DIPL CHEM DR , BRANDSTETTER FRANZ DIPL CHEM D
Abstract: Polymer blend is based ona hard component (A) and 2 graft copolymers (b) and (c). (A) consists of copolymer(s) of styrene and/or alpha-methylstyrene with 20-40 wt. % acrylonitrile (AN); (b) of (Bl) 40-80 (50-60)% butadiene polymer of average particle size 0.20-0.45 (0.26-0.35) mu m and (B2) 20-60 (40-50)% grafted mixt. of styrene and AN in 75:25 to 65:35 ratio; and (c) of (Cl) 40-80 (70-60)% crosslinked acrylic ester polymer, with Tg below 0 degree C and average particle size 0.05-0.15 (0.06-0.08) mu m, and (C2) 20-60 (30-40)% grafted mixt. of styrene and AN in 75:25 to 65:35 ratio. The ratio of (B1) to (Cl) is 70:30 to 30:70 (60:40 to 50:50) and the amt. of (B1 + Cl) in the blend ca. 10-35 (15-30)%. The blend can also contain conventional additives, esp. ethylene and/or propylene oxide polymer or a dyestuff or coloured pigment. Mouldings with high (cold) impact strength and good surface structure and good processing properties are obtd..
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公开(公告)号：DE3312151A1
公开(公告)日：1983-10-20
申请号：DE3312151
申请日：1983-04-02
Applicant: BASF AG
IPC: C08F210/02
Abstract: The invention relates to ethylene copolymers containing, in copolymerised form, 40-99.5 parts by weight of ethylene, 0.5-30 parts by weight of the acrylic acid ester of tricyclodecenyl alcohol and 0-50 parts by weight of at least one other ethylene-copolymerisable monomer.
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公开(公告)号：DE3203488A1
公开(公告)日：1983-08-11
申请号：DE3203488
申请日：1982-02-03
Applicant: BASF AG
Inventor： BRANDSTETTER FRANZ DIPL CHEM D , HAMBRECHT JUERGEN DIPL CHEM DR , SCHARF BERNHARD DIPL CHEM DR
Abstract: The invention relates to a thermoplastic moulding composition comprising from 90 to 99% by weight, based on the moulding composition, of at least one copolymer A made from at least one vinylaromatic monomer and at least one ethylenically unsaturated monomer. The moulding composition furthermore contains from 0.5 to 5% by weight of a polyalkylene polyether B of the formula with the proviso that n may adopt values from 3 to 200, R' is H and/or CH3 and X is RCO- or R-, where R can contain 1 to 30 carbon atoms. The moulding composition furthermore contains a component C in a proportion of from 0.5 to 5% by weight which is a copolymer made from styrene and at least one further monomer unit containing at least one carboxyl function. The moulding composition may contain conventional additives and is used to produce mouldings.
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公开(公告)号：DE3139958A1
公开(公告)日：1983-04-28
申请号：DE3139958
申请日：1981-10-08
Applicant: BASF AG
Inventor： HAMBRECHT JUERGEN DIPL CHEM DR , MUENCH VOLKER DIPL CHEM DR , NAARMANN HERBERT DIPL CHEM DR , BRANDSTETTER FRANZ DIPL CHEM D , BOEHLKE KLAUS DIPL CHEM DR
Abstract: Self-extinguishing thermoplastic moulding compositions based on styrene polymers, polyphenylene ethers and polymeric organophosphorus compounds containing phosphorus in the polymer chain in an oxidation state of +3 and having a number average molecular weight Mn of
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公开(公告)号：DE3140566A1
公开(公告)日：1983-04-21
申请号：DE3140566
申请日：1981-10-13
Applicant: BASF AG
Inventor： HAMBRECHT JUERGEN DIPL CHEM DR , BRANDSTETTER FRANZ DIPL CHEM D , MC KEE GRAHAM EDMUND DIPL CHEM , ECHTE ADOLF DIPL CHEM DR
Abstract: The invention relates to a thermoplastic moulding composition comprising a copolymer A and a graft copolymer B. The copolymer A makes up from 50 to 95% by weight of the moulding composition and is built up from a monovinylaromatic monomer and an unsaturated dicarboxylic anhydride as further monomer. The graft copolymer makes up from 5 to 50% by weight of the moulding composition and comprises from 20 to 80% by weight of an elastomeric graft base and from 20 to 80% by weight of a graft shell. The graft shell contains from 80 to 99% by weight of a monovinylaromatic monomer and from 1 to 20% by weight of an ethylenically unsaturated monomer containing at least one reactive terminal group from the series consisting of -OH, -SH and -NHR, where R is H, alkyl having 1 to 18 carbon atoms, aralkyl or aryl. The moulding composition may contain conventional additives and is obtained from a melt of component A with the graft copolymer B by reaction at temperatures of >/=200 DEG C. It is used to produce mouldings.
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Patent Agency Ranking
公开(公告)号：DE3138505A1
公开(公告)日：1983-04-07
申请号：DE3138505
申请日：1981-09-28
Applicant: BASF AG
Inventor： HAMBRECHT JUERGEN DIPL CHEM DR , MUENCH VOLKER DIPL CHEM DR , BRANDSTETTER FRANZ DIPL CHEM D , NAARMANN HERBERT DIPL CHEM DR , BOEHLKE KLAUS DIPL CHEM DR
Abstract: Self-extinguishing moulding compositions based on styrene polymers, polyphenylene ethers and organic phosphorus compounds containing sulphonamide groups bonded to the phosphorus.
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公开(公告)号：DE3137823A1
公开(公告)日：1983-03-31
申请号：DE3137823
申请日：1981-09-23
Applicant: BASF AG
Inventor： HAMBRECHT JUERGEN DIPL CHEM DR , MUENCH VOLKER DIPL CHEM DR , PENZIEN KLAUS DIPL CHEM DR , NAARMANN HERBERT DIPL CHEM DR , BRANDSTETTER FRANZ DIPL CHEM D , BOEHLKE KLAUS DIPL CHEM DR
IPC: C08L25/00 , C08K5/49 , C08K5/53 , C08K5/5313 , C08L7/00 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L71/00 , C08L71/12 , C08L101/00 , C08L71/04
Abstract: Self-extinguishing thermoplastic moulding compositions based on styrene polymers, polyphenylene ethers and organic, substituted phosphinic acids and/or anhydrides thereof.
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公开(公告)号：DE3135251A1
公开(公告)日：1983-03-17
申请号：DE3135251
申请日：1981-09-05
Applicant: BASF AG
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公开(公告)号：DE3114090A1
公开(公告)日：1982-10-28
申请号：DE3114090
申请日：1981-04-08
Applicant: BASF AG
Inventor： BRANDSTETTER FRANZ DIPL CHEM D , HAMBRECHT JUERGEN DIPL CHEM DR , HILDENBRAND PETER DIPL CHEM DR , ECHTE ADOLF DIPL CHEM DR
IPC: C08F20/18 , C08F265/06
Abstract: The invention relates to a discontinuous (batch) process for the preparation of latices of polymers based on esters of acrylic acid with saturated aliphatic alcohols having 2 to 8 carbon atoms, by polymerisation of the monomers in emulsion under conventional pressure and temperature conditions, where first a mixture of water, emulsifier and an aliphatic alcohol (having 10-30 carbon atoms) is heated with stirring to temperatures above the melting point of the aliphatic alcohol, and the mixture is subsequently, if necessary, adjusted to the polymerisation temperature, and the polymerisation is carried out directly after the preparation of the mixture (preemulsion) by a) introducing all the initiator or b) introducing all the monomer, optionally with some of the initiator, or c) introducing some of the monomer and at least some of the initiator into the preemulsified mixture of water, emulsifier and alcohol, and metering in (feeding) the respective total or remaining amounts of monomer or initiator during the polymerisation.
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公开(公告)号：DE3112428A1
公开(公告)日：1982-10-07
申请号：DE3112428
申请日：1981-03-28
Applicant: BASF AG
Inventor： BRANDSTETTER FRANZ DIPL CHEM D , HAMBRECHT JUERGEN DIPL CHEM DR , SCHARF BERNHARD DIPL CHEM DR , JUNG RUDOLF DIPL CHEM DR , LINDENSCHMIDT GERHARD DIPL CHE , SCHWAAB JOSEF DIPL CHEM DR
Abstract: Thermoplastic molding masses based on the copolymerization of styrene and/or alpha -methylstyrene and acrylonitrile, which may be modified to be impact resistant with rubberlike polymers, are made antistatic by adding 0.01 to 1.5 percent by weight of a graft polyol which is a polyhydroxy-polyalkylene polyether modified with styrene-acrylonitrile copolymers.
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