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公开(公告)号:ES2290352T3
公开(公告)日:2008-02-16
申请号:ES02792876
申请日:2002-12-04
Applicant: BASF AG
Inventor: HAESE FRANK , EBEL KLAUS , BURKART KIRSTEN , UNVERRICHT SIGNE , MUNSTER PETER
Abstract: Procedimiento para la isomerización de alcoholes alílicos reactantes de la fórmula general (I) para dar alcoholes alílicos como producto de la fórmula general (II) significando R1 hasta R5 hidrógeno o un resto alquilo con 1 a 12 átomos de carbono saturado o una o varias veces insaturado, que, en caso dado, puede estar substituido, caracterizado porque se somete a una transposición al menos a un alcohol alílico reactante o a una mezcla de los mismos, según una forma de trabajo semicontinua, para dar el correspondiente alcohol alílico como producto, dosificándose a un reactor adecuado, que contiene catalizador, al menos un alcohol alílico reactante o una mezcla de los mismos.
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公开(公告)号:SK285932B6
公开(公告)日:2007-11-02
申请号:SK1922003
申请日:2001-08-16
Applicant: BASF AG
Inventor: ISAK HEINZ , SENDHOFF NORBERT , SCHUTZ FRANZ , THERRE JORG , DROGEMULLER MICHAEL , FRANKE DIRK , MUNZINGER MANFRED , WECK ALEXANDER , BURKART KIRSTEN
IPC: C07D285/00 , A01N25/00 , A01N25/12 , A01N43/00 , A01N43/88 , C07D285/34
Abstract: Described is a process for the preparation of a particulate tetrahydro-3,5-dimethyl-1,3,5-thiadiazine-2-thione product by combining a first aqueous solution comprising methylammonium N-methyldithiocarbamate with a second aqueous solution comprising formaldehyde, followed by separation and drying of the resulting solid, which comprises combining the first and the second aqueous solutions in such a way that the ratio between the concentrations of dithiocarbamate functions and of formaldehyde is essentially constant in the reaction mixture over time during the duration of the reaction, and separating the solid form the resulting suspension.
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公开(公告)号:AT373632T
公开(公告)日:2007-10-15
申请号:AT02792876
申请日:2002-12-04
Applicant: BASF AG
Inventor: HAESE FRANK , EBEL KLAUS , BURKART KIRSTEN , UNVERRICHT SIGNE , MUENSTER PETER
Abstract: The present invention relates to a process for isomerizing reactant allyl alcohols to product allyl alcohols in the presence of a catalyst, wherein the reactant allyl alcohol is rearranged to product allyl alcohol in semicontinuous or continuous mode in a catalyst-containing suitable reactor. In particular, the process according to the invention is used to prepare linalool from Geraniol and/or nerol.
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公开(公告)号:DE50203555D1
公开(公告)日:2005-08-11
申请号:DE50203555
申请日:2002-12-03
Applicant: BASF AG
Inventor: FUNKE DR , GERLACH DR , EBEL DR , UNVERRICHT DR , HAESE DR , BURKART KIRSTEN , GOEBBEL DR
IPC: C07B61/00 , C07C29/17 , C07C31/125
Abstract: Tetrahydrogeraniol is obtained by direct catalytic hydrogenation of the product mixture or distillation residue from the synthesis of linalool, citronellal, citronellol or geraniol/nerol.
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公开(公告)号:AT287877T
公开(公告)日:2005-02-15
申请号:AT02016604
申请日:2002-07-25
Applicant: BASF AG
Inventor: RUST HARALD , BURKART KIRSTEN , FAUST TILLMANN DR , HENKELMANN JOCHEM DR , KINDLER ALOIS DR , KNOLL CHRISTIAN DR , BECKER MICHAEL DR
IPC: C07D213/67 , C07D263/42
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公开(公告)号:EA005202B1
公开(公告)日:2004-12-30
申请号:EA200300221
申请日:2001-08-16
Applicant: BASF AG
Inventor: ISAK HEINZ , SENDHOFF NORBERT , SCHUTZ FRANZ , THERRE JORG , DROGEMULLER MICHAEL , FRANKE DIRK , MUNZINGER MANFRED , WECK ALEXANDER , BURKART KIRSTEN
IPC: A01N25/12 , A01N43/88 , C07D285/34
Abstract: Визобретенииописываетсяспособполученияпорошковойкомпозициитетрагидро-3,5-диметил-1,3,5-тиадиазин-2-тиона, осуществляемыйпутемобъединениядвухводныхрастворов, одинизкоторыхсодержит N-метилдитиокарбаматметиламмония, адругойсодержитформальдегид, споследующимвыделениемобразовавшегосятвердогопродуктаи егосушкой. Такойспособотличаетсятем, чтопервыйи второйводныерастворыобъединяюттакимобразом, чтобысоотношениеконцентрацийфункциональныхгруппдитиокарбаматаи формальдегидав реакционнойсмесинапротяжениивсейреакцииоставалосьпрактическипостоянным.
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公开(公告)号:DE10304343A1
公开(公告)日:2004-08-12
申请号:DE10304343
申请日:2003-02-03
Applicant: BASF AG
Inventor: ARNDT JAN-DIRK , HENKELMANN JOCHEM , BURKART KIRSTEN , HEIMANN FRANK , RUST HARALD , BECKER MICHAEL
IPC: C07D213/67 , C07D263/42
Abstract: Production of 5-alkoxyoxazoles (I) comprises heating an alpha -isocyano alkanoate ester (II) at a temperature above 80 [deg] C in the presence of an tertiary amine with a molecular weight above 185. Production of 5-alkoxyoxazoles of formula (I) comprises heating an alpha -isocyano alkanoate ester of formula (II) at a temperature above 80 [deg] C in the presence of an amine of formula NR5R6R7 with a molecular weight above 185. [Image] R1optionally substituted 1-6C alkyl; R2H or optionally substituted 1-6C alkyl; R5-R7optionally substituted 1-9C alkyl or 5-7C cycloalkyl; or two of R5-R7optionally substituted (un)saturated heterocycle. An independent claim is also included for production of pyridoxine derivatives of formula (IX) by: (1) esterifying an amino acid of formula (III); (2) converting the ester to a N-formyl derivative of formula (V); (3) converting this to (II) and thence to (I) as above; (4) reacting (I) with a protected diol of formula (VI) to form a Diels-Alder adduct of formula (VII); and (5) converting this to (IX) by acid treatment and deprotection. [Image] R3, R4protecting groups.
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公开(公告)号:DE50101522D1
公开(公告)日:2004-03-25
申请号:DE50101522
申请日:2001-08-16
Applicant: BASF AG
Inventor: ISAK HEINZ , SENDHOFF NORBERT , SCHUETZ FRANZ , THERRE JOERG , DROEGEMUELLER MICHAEL , FRANKE DIRK , MUNZINGER MANFRED , WECK ALEXANDER , BURKART KIRSTEN
IPC: A01N25/12 , A01N43/88 , C07D285/34
Abstract: Described is a process for the preparation of a particulate tetrahydro-3,5-dimethyl-1,3,5-thiadiazine-2-thione product by combining a first aqueous solution comprising methylammonium N-methyldithiocarbamate with a second aqueous solution comprising formaldehyde, followed by separation and drying of the resulting solid, which comprises combining the first and the second aqueous solutions in such a way that the ratio between the concentrations of dithiocarbamate functions and of formaldehyde is essentially constant in the reaction mixture over time during the duration of the reaction.
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公开(公告)号:ZA200302068B
公开(公告)日:2004-03-15
申请号:ZA200302068
申请日:2003-03-14
Applicant: BASF AG
Inventor: BURKART KIRSTEN , DROEGEMUELLER MICHAEL , FRANKE DIRK , ISAK HEINZ , MUNZINGER MANFRED , SCHUETZ FRANZ , SENDHOFF NORBERT , THERRE JOERG , WECK ALEXANDER
IPC: A01N25/12 , A01N43/88 , C07D285/34 , C07D , A01N
Abstract: Described is a process for the preparation of a particulate tetrahydro-3,5-dimethyl-1,3,5-thiadiazine-2-thione product by combining a first aqueous solution comprising methylammonium N-methyldithiocarbamate with a second aqueous solution comprising formaldehyde, followed by separation and drying of the resulting solid, which comprises combining the first and the second aqueous solutions in such a way that the ratio between the concentrations of dithiocarbamate functions and of formaldehyde is essentially constant in the reaction mixture over time during the duration of the reaction.
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公开(公告)号:HU0300766A2
公开(公告)日:2003-09-29
申请号:HU0300766
申请日:2001-08-16
Applicant: BASF AG
Inventor: BURKART KIRSTEN , DROEGEMUELLER MICHAEL , FRANKE DIRK , ISAK HEINZ , MUNZINGER MANFRED , SCHUETZ FRANZ , SENDHOFF NORBERT , THERRE JOERG , WECK ALEXANDER
IPC: A01N25/12 , A01N43/88 , C07D285/34
Abstract: Described is a process for the preparation of a particulate tetrahydro-3,5-dimethyl-1,3,5-thiadiazine-2-thione product by combining a first aqueous solution comprising methylammonium N-methyldithiocarbamate with a second aqueous solution comprising formaldehyde, followed by separation and drying of the resulting solid, which comprises combining the first and the second aqueous solutions in such a way that the ratio between the concentrations of dithiocarbamate functions and of formaldehyde is essentially constant in the reaction mixture over time during the duration of the reaction.
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