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公开(公告)号:AU2004308652A1
公开(公告)日:2005-07-14
申请号:AU2004308652
申请日:2004-12-23
Applicant: BASF AG
Inventor: JOHANN THORSTEN , HARTH KLAUS , OLBERT GERHARD , WEBER MARKUS , FIENE MARTIN , STROFER ECKHARD , SIEGERT MARKUS , LANG NEVEN
Abstract: A process for preparing formaldehyde by gas-phase oxidation of methanol vapor by means of a gas stream comprising molecular oxygen in the presence of a fixed-bed catalyst comprising iron and molybdenum, wherein the process is carried out in a reactor ( 1 ) having heat-exchange plates ( 2 ) which are arranged in the longitudinal direction of the reactor ( 1 ) and have a spacing between them and through which a heat transfer medium flows, inlet and outlet facilities ( 3, 4 ) for the heat transfer medium to the heat-exchange plates ( 2 ) and also gaps ( 5 ) between heat-exchange plates ( 2 ) in which the fixed-bed catalyst is present and into which the methanol vapor and the gas stream comprising molecular oxygen are passed, is described.
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公开(公告)号:DE10316418A1
公开(公告)日:2004-10-21
申请号:DE10316418
申请日:2003-04-10
Applicant: BASF AG
Inventor: OLBERT GERHARD , MATTKE TORSTEN , FIENE MARTIN , HUTTENLOCH OLIVER , HAMMON ULRICH
Abstract: The use of an ionic liquid as heat transfer medium for the indirect introduction or removal of heat into or from a reactor is described.
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43.
公开(公告)号:AU2003285303A8
公开(公告)日:2004-05-13
申请号:AU2003285303
申请日:2003-10-27
Applicant: BASF AG
Inventor: WALSDORFF CHRISTIAN , HARTH KLAUS , KUHRS CHRISTIAN , FIENE MARTIN , STROFER ECKHARD
IPC: C01B7/04 , C01B7/07 , C07C263/10
Abstract: Process for preparing chlorine from hydrochloric acid, which comprises the steps: a) providing a hydrochloric acid feed stream I; b) providing a hydrochloric acid recycle stream II; c) separating off a hydrogen chloride stream IV from the hydrochloric acid feed stream I and the hydrochloric acid recycle stream II in a distillation step; d) feeding the hydrogen chloride stream IV, an oxygen-containing steam V and, if desired, an oxygen-containing recycle stream Va into an oxidation zone and oxidizing hydrogen chloride to chlorine in the presence of a catalyst to give a product gas stream VI comprising chlorine, unreacted oxygen, unreacted hydrogen chloride and water vapor; e) separating off hydrogen chloride and water from the product gas stream VI in an absorption step to give a gas stream VII and the hydrochloric acid recycle stream II; f) if desired, drying the gas stream VII; g) separating off an oxygen-containing stream from the gas stream VII and, if desired, recirculating at least part of this as oxygen-containing recycle stream Va to the oxidation zone, leaving a chlorine-containing product stream VIII; h) if desired, further purifying the chlorine-containing product stream VIII.
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公开(公告)号:AU2003282140A1
公开(公告)日:2004-02-25
申请号:AU2003282140
申请日:2003-07-30
Applicant: BASF AG
Inventor: STROEFER ECKHARD , HARTH KLAUS , JACOBS JAN D , DEBERDT FILIP , WALSDORFF CHRISTIAN , FIENE MARTIN
IPC: B01J23/46 , C01B7/04 , C07C263/10 , C07C263/20 , C25B1/26
Abstract: Process for preparing organic isocyanates, which comprises the steps (a) making available a first partial amount of chlorine, with the chlorine of this first partial amount having a content of free and bound bromine and iodine of
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公开(公告)号:DE10235476A1
公开(公告)日:2004-02-12
申请号:DE10235476
申请日:2002-08-02
Applicant: BASF AG
Inventor: WALSDORFF CHRISTIAN , FIENE MARTIN , STROEFER ECKHARD , HARTH KLAUS , JACOBS JAN D , DEBERDT FILIP
Abstract: Process for preparing organic isocyanates, which comprises the steps (a) making available a first partial amount of chlorine, with the chlorine of this first partial amount having a content of free and bound bromine and iodine of
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公开(公告)号:AU2003232761A1
公开(公告)日:2003-12-02
申请号:AU2003232761
申请日:2003-05-13
Applicant: BASF AG
Inventor: FIENE MARTIN , WEBER MARKUS , STROFER ECKHARD , HARTH KLAUS , WALSDORFF CHRISTIAN
Abstract: The present invention relates to a process for the continuous preparation of chlorine by reaction of hydrogen chloride with oxygen in the presence of a heterogeneous catalyst, in which the conversion of hydrogen chloride in a single pass through the reactor is restricted to from 15 to 90%.
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