公开(公告)号：ES2083656T3

公开(公告)日：1996-04-16

申请号：ES92119402

申请日：1992-11-13

Applicant: BASF AG

Inventor： GEHRER EUGEN DR ,  HARDER WOLFGANG DR

IPC: B01J23/88 ,  C07B61/00 ,  C07C29/136 ,  C07C29/60 ,  C07C31/20

Abstract: Process for the preparation of 1,2-propylene glycol by reacting dihydroxyacetone hydrogenolytically in one step by means of a catalyst to give 1,2-propylene glycol.

公开(公告)号：DE4431093A1

公开(公告)日：1996-03-07

申请号：DE4431093

申请日：1994-09-01

Applicant: BASF AG

Inventor： DINGERDISSEN UWE DR ,  LAUTH GUENTER DR ,  HENNE ANDREAS DR ,  STOPS PETER ,  ELLER KARSTEN DR ,  GEHRER EUGEN DR

IPC: B01J27/18 ,  B01J27/182 ,  B01J27/185 ,  B01J27/188 ,  C07B61/00 ,  C07C209/60 ,  C07C211/03 ,  C07C211/05 ,  C07C211/06 ,  C07C211/07 ,  C07C211/08 ,  C07C211/35 ,  B01J21/08 ,  B01J21/12

Abstract: Preparation of amines of formula (I) comprises reaction of olefins of formula (II) with ammonia or prim. or sec. amines of formula (III) in the presence of a microporous, X-ray amorphous catalyst of formula (IV) having a specific BET surface area of 200-1000 sq.m/g, at 200-400 degrees C and 1-700 bar pressure. Catalyst has the compsn. aMO2.bQ2O3.cP2O5 (IV). R1-R5 = H, 1-20C alkyl or cycloalkyl, 4-20C alkyl-cycloalkyl, 4-20C cycloalkyl-alkyl, aryl, 7-20C alkylaryl, 7-20C aralkyl or heterocyclic; Q = Al, B, Cr, Fe or Ga; M = Si, Ti or Ge; a, b = 0.5:1 to 1,000-1; and c = 0 to 2:1.

公开(公告)号：DE59201646D1

公开(公告)日：1995-04-20

申请号：DE59201646

申请日：1992-07-01

Applicant: BASF AG

Inventor： GEHRER EUGEN DR ,  HARDER WOLFGANG DR ,  KNUTH BERNHARD DR ,  VOGEL HERBERT DR

IPC: B01J31/02 ,  C07B61/00 ,  C07C45/00 ,  C07C45/75 ,  C07C49/17 ,  C07D277/22 ,  C07D277/34

公开(公告)号：DE4023255A1

公开(公告)日：1992-01-23

申请号：DE4023255

申请日：1990-07-21

Applicant: BASF AG

Inventor： GEHRER EUGEN DR ,  HARDER WOLFGANG DR

IPC: B01J23/46 ,  B01J23/70 ,  B01J25/02 ,  B01J27/18 ,  C07B61/00 ,  C07C29/00 ,  C07C29/38 ,  C07C31/20

公开(公告)号：DE19734176A1

公开(公告)日：1999-02-11

申请号：DE19734176

申请日：1997-08-07

Applicant: BASF AG

Inventor： SIGWART CHRISTOPH DR ,  NARBESHUBER THOMAS DR ,  ARNOLD HEIKO DR ,  BARL MANFRED DR ,  FISCHER ROLF DR ,  GEHRER EUGEN DR

IPC: C08F4/22 ,  C08F4/78 ,  C08F10/10

Abstract: A process is disclosed for preparing halogen-free, reactive polyisobutylene with a content of terminal double bonds of more than 50 % by moles and an average molecular weight Mn of 500 to 5000 daltons by cationic polymerisation of isobutylene or isobutylene-containing hydrocarbon mixtures in the liquid phase. Polymerisation is carried out at a temperature of between -40 and +10 DEG C in the presence of a molybdate or wolframate heteropolyacid.

公开(公告)号：DE59601030D1

公开(公告)日：1999-02-04

申请号：DE59601030

申请日：1996-04-26

Applicant: BASF AG

Inventor： GEHRER EUGEN DR ,  MASSONNE KLEMENS DR ,  GAUSEPOHL HERMANN DR ,  FISCHER MARTIN DR ,  RIEKER CHRISTOPHER WILLIAM DR ,  SIGGEL LORENZ DR

IPC: B01J29/18 ,  B01J29/70 ,  C07B61/00 ,  C07C2/66 ,  C07C15/16

Abstract: The prodn. of diaryl-ethanes of formula (I), in which all R gps. = H or 1-8C alkyl, comprises reacting aromatics of formula (II) with styrenes of formula (III) at -20 to +300 degrees C and 1-100 bar in presence of beta-zeolites or mordenite as heterogenous catalyst.

公开(公告)号：DE19715203A1

公开(公告)日：1998-10-15

申请号：DE19715203

申请日：1997-04-11

Applicant: BASF AG

Inventor： NARBESHUBER THOMAS FRANZ DR ,  GROSCH GEORG HEINRICH DR ,  TREFZER MICHAEL ,  GEHRER EUGEN DR ,  BAIER MICHAEL DR

IPC: B01J23/04 ,  B01J23/00 ,  B01J23/02 ,  B01J23/78 ,  B01J23/80 ,  B01J23/835 ,  B01J23/86 ,  B01J27/045 ,  B01J27/051 ,  B01J27/08 ,  C07B61/00 ,  C07C2/24 ,  C07C2/54 ,  C07C2/66 ,  C07C2/72 ,  C07C5/25 ,  C07C15/02 ,  C07C2/58 ,  C07C2/08 ,  C07C5/22

Abstract: A catalyst containing an alkali metal on a spinel or an inverse spinel as a carrier, which can be doped with an alkali/alkaline earth compound, the weight ratio of alkali metal:carrier being 0.01 : 5; is produced by applying an alkali metal on to the carrier by (i) impregnating the molten alkali metal; or (ii) impregnating the carrier with solutions of alkali metal azide, drying the carrier and decomposing the alkali metal on the carrier; or (iii) impregnating the carrier with ammoniacal solutions of alkali metal and removing the ammonia; the carrier optionally being doped before impregnating with an alkali/alkaline earth metal compound, drying and then calcining.

公开(公告)号：CZ21397A3

公开(公告)日：1998-04-15

申请号：CZ21397

申请日：1997-01-23

Applicant: BASF AG

Inventor： ELLER KARSTEN DR ,  KUMMER RUDOLF DR ,  GEHRER EUGEN DR

IPC: B01J29/08 ,  C07B43/04 ,  C07B61/00 ,  C07C209/60 ,  C07C211/03 ,  C07C211/07

公开(公告)号：ES2111110T3

公开(公告)日：1998-03-01

申请号：ES93114033

申请日：1993-09-02

Applicant: BASF AG

Inventor： TELES JOAQUIM HENRIQUE DR ,  MELDER JOHANN-PETER DR ,  GEHRER EUGEN DR ,  HARDER WOLFGANG DR ,  EBEL KLAUS DR ,  GROENING CARSTEN DR

IPC: B01J31/02 ,  C07B61/00 ,  C07C45/75 ,  C07C47/19 ,  C07C49/17 ,  C07D249/08 ,  C07D249/10 ,  C07D249/12 ,  C07D249/14 ,  C07D257/04 ,  C07D471/04 ,  C07D487/04

公开(公告)号：DE59307979D1

公开(公告)日：1998-02-19

申请号：DE59307979

申请日：1993-09-02

Applicant: BASF AG

Inventor： TELES JOAQUIM HENRIQUE DR ,  MELDER JOHANN-PETER DR ,  GEHRER EUGEN DR ,  HARDER WOLFGANG DR ,  EBEL KLAUS DR ,  GROENING CARSTEN DR ,  MEYER REGINA DR

IPC: B01J31/02 ,  C07B61/00 ,  C07C45/75 ,  C07C47/19 ,  C07C49/17 ,  C07D249/08 ,  C07D249/10 ,  C07D249/12 ,  C07D249/14 ,  C07D257/04 ,  C07D471/04 ,  C07D487/04