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公开(公告)号:CA2403878C
公开(公告)日:2010-02-16
申请号:CA2403878
申请日:2001-03-27
Applicant: BASF AG
Inventor: KRONER MATTHIAS , PERNER JOHANNES , BUCHNER KARL-HEINZ , WILD JOCHEN , PFISTER JURGEN
Abstract: The invention relates to a method for modifying acid group containing polymers by reacting, at temperatures of up to 250 °C, a) polymers that contain polymerized into them at least 5 wt.- % of a monomer that contain monoethylenically unsaturated acid groups, that have a molecular weight ranging between 200 to 100.000 and that are obtainable by radical polymerization of monoethylenically unsaturated acids, optionally in the presence of another monoethylenically unsaturated monomer in an aqueous solution in the presence of at least 4 wt.- %, based on the monomers used for the polymerization, of a water-soluble sulfur composition in which the sulfur has the oxidation number +4, with b) unilaterally end-group terminated polyalkylene glycols, alkylpolyalkyene glycolamines or the mixtures thereof. The invention also relates to the mixtures of at least one of said compounds with up to 30 wt.-- %, based on the mixtures, of ammonia, amines, alcohols, hydroxycarboxylic acids or aminocarboxylic acids.
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公开(公告)号:AU2001254743B2
公开(公告)日:2005-10-20
申请号:AU2001254743
申请日:2001-03-27
Applicant: BASF AG
Inventor: KRONER MATTHIAS , BUCHNER KARL-HEINZ , PERNER JOHANNES , PFISTER JURGEN , WILD JOCHEN
IPC: C08G81/02 , C04B24/26 , C08F8/14 , C08F8/30 , C08F008/30 , C08F008/14
Abstract: Polymers containing acid groups are modified by reaction of(a) polymers which comprise at least 5% by weight of a copolymerized monoethylenically unsaturated monomer containing acid groups, have molar masses of from 200 to 100,000 and are obtainable by free-radical polymerization of monoethylenically unsaturated acids in aqueous solution in the presence or absence of other monoethylenically unsaturated monomers and in the presence of at least 4% by weight, based on the monomers used in the polymerization, of a water-soluble sulfur compound in which the sulfur is in the oxidation state +4,with(b) polyalkylene glycols which are end-capped at one end, alkylpolyalkylene glycol amines or mixtures thereof, or mixtures of at least one of the two compounds specified with up to 30% by weight, based on the mixtures, of ammonia, amines, alcohols, hydroxycarboxylic acids or aminocarboxylic acidsat up to 250° C.
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公开(公告)号:BR0015848A
公开(公告)日:2002-07-16
申请号:BR0015848
申请日:2000-11-16
Applicant: BASF AG
Inventor: KRONER MATTHIAS , CHNER KARL-HEINZ B , PERNER JOHANNES , RAUBENHEIMER HANS-J RGEN , FAUL DIETER
IPC: C08F2/06 , C08F8/44 , C08F220/28 , C08F290/06 , C08F290/14 , C08G65/332 , C08L71/02
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公开(公告)号:AU5474301A
公开(公告)日:2001-10-08
申请号:AU5474301
申请日:2001-03-27
Applicant: BASF AG
Inventor: KRONER MATTHIAS , PERNER JOHANNES , BUCHNER KARL-HEINZ , WILD JOCHEN , PFISTER JURGEN
Abstract: Polymers containing acid groups are modified by reaction of(a) polymers which comprise at least 5% by weight of a copolymerized monoethylenically unsaturated monomer containing acid groups, have molar masses of from 200 to 100,000 and are obtainable by free-radical polymerization of monoethylenically unsaturated acids in aqueous solution in the presence or absence of other monoethylenically unsaturated monomers and in the presence of at least 4% by weight, based on the monomers used in the polymerization, of a water-soluble sulfur compound in which the sulfur is in the oxidation state +4,with(b) polyalkylene glycols which are end-capped at one end, alkylpolyalkylene glycol amines or mixtures thereof, or mixtures of at least one of the two compounds specified with up to 30% by weight, based on the mixtures, of ammonia, amines, alcohols, hydroxycarboxylic acids or aminocarboxylic acidsat up to 250° C.
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公开(公告)号:DE19957177A1
公开(公告)日:2001-08-02
申请号:DE19957177
申请日:1999-11-27
Applicant: BASF AG
Inventor: KRONER MATTHIAS , BUECHNER KARL-HEINZ , PERNER JOHANNES , RAUBENHEIMER HANS-JUERGEN , FAUL DIETER
IPC: C08F2/06 , C08F8/44 , C08F220/28 , C08F290/06 , C08F290/14 , C08G65/332 , C08L71/02 , C08F220/26 , C08F8/14
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公开(公告)号:PH29930A
公开(公告)日:1996-09-16
申请号:PH47287
申请日:1993-11-18
Applicant: BASF AG
Inventor: PERNER JOHANNES , DIESSEL PAUL , GUEMBEL HELMUT , DENZINGER WALTER , HARTMANN HEINRICH , KRONER MATTHIAS
IPC: C02F5/10 , C08L33/02 , H04L27/20 , C08L35/00 , C08L51/02 , C08L77/04 , C11D3/37 , H04B7/00 , H04J3/16 , H04J3/22 , H04J3/24 , H04J11/00 , H04J13/00 , H04J13/18 , H04L20060101 , H04L1/00 , H04L1/08 , H04L12/00 , H04L27/30 , H04L29/06 , H04Q7/38
Abstract: PCT No. PCT/EP93/03159 Sec. 371 Date May 22, 1995 Sec. 102(e) Date May 22, 1995 PCT Filed Nov. 11, 1993 PCT Pub. No. WO94/12571 PCT Pub. Date Jun. 9, 1994Mixtures of (I) polymers of monoethylenically unsaturated dicarboxylic acids having a molecular weight of from 200 to 5,000 and (II) (1) copolymers having a molecular weight of from 10,000 to 150,000 and comprising (a) from 10 to 70% by weight of monoethylenically unsaturated C4-C8-dicarboxylic acids or the salts thereof and (b) from 30 to 90% by weight of monoethylenically unsaturated C3-C10-monocarboxylic acids and/or the salts thereof, (2) graft polymers having a molecular weight of from 5,000 to 150,000, which are obtainable by free radical graft polymerization of (A) monoethylenically unsaturated C3-C10-carboxylic acids or the anhydrides and/or the salts thereof in the presence of (B) mono-, oligo- or polysaccharides and the derivatives thereof in a weight ratio (A) : (B) of (95 to 20) : (5 to 80), and/or (3) polyaminocarboxylic acids and/or polymers containing aminocarboxylic acid groups contain the components (I) and (II) in a weight ratio of from 10 : 0.5 to 0.5 : 10 and are used as additives for phosphate-free or low-phosphate textile detergents or as dispersants or coating inhibitors in cleaners for hard surfaces.
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公开(公告)号:AU2674195A
公开(公告)日:1996-01-15
申请号:AU2674195
申请日:1995-06-03
Applicant: BASF AG
Inventor: DETERING JURGEN , SCHADE CHRISTIAN , PERNER JOHANNES , JAGER HANS-ULRICH
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公开(公告)号:AT127150T
公开(公告)日:1995-09-15
申请号:AT92904485
申请日:1992-02-11
Applicant: BASF AG
Inventor: STOECKIGT DIETER , BAUR RICHARD , TRAPP HORST , PERNER JOHANNES
Abstract: PCT No. PCT/EP92/00289 Sec. 371 Date Aug. 23, 1993 Sec. 102(e) Date Aug. 23, 1993 PCT Filed Feb. 11, 1992 PCT Pub. No. WO92/14808 PCT Pub. Date Sep. 3, 1992.A mixture suitable for use as a foam-suppressing surfactant additament in cleaning compositions for mechanized cleaning processes comprises at least two mixtures of alkoxylated alcohols I R-O-(C2H4O)x-(C3H6O)y-H (I) where x is an average degree of ethoxylation between 1 and 12, y is an average degree of propoxylation between 1 and 15, one alkoxylated alcohol mixture carries straight-chain or branched C8-C18-alkyl groups as the radical R and one other alkoxylated alcohol mixture carries straight-chain or branched C10-C20-alkyl groups as the radical R, subject to the proviso that the two radicals R differ by at least 0.5 in the average number of carbon atoms, and the two alkoxylated alcohol mixtures present in a ratio of from 10:90 to 90:10.
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公开(公告)号:AU5465194A
公开(公告)日:1994-06-22
申请号:AU5465194
申请日:1993-11-11
Applicant: BASF AG
Inventor: PERNER JOHANNES , DIESSEL PAUL , GUEMBEL HELMUT , DENZINGER WALTER , HARTMANN HEINRICH , KRONER MATTHIAS
IPC: H04L27/20 , C02F5/10 , C08L33/02 , C08L35/00 , C08L51/02 , C08L77/04 , C11D3/37 , H04B7/00 , H04J3/16 , H04J3/22 , H04J3/24 , H04J11/00 , H04J13/00 , H04J13/18 , H04L20060101 , H04L1/00 , H04L1/08 , H04L12/00 , H04L27/30 , H04L29/06 , H04Q7/38
Abstract: PCT No. PCT/EP93/03159 Sec. 371 Date May 22, 1995 Sec. 102(e) Date May 22, 1995 PCT Filed Nov. 11, 1993 PCT Pub. No. WO94/12571 PCT Pub. Date Jun. 9, 1994Mixtures of (I) polymers of monoethylenically unsaturated dicarboxylic acids having a molecular weight of from 200 to 5,000 and (II) (1) copolymers having a molecular weight of from 10,000 to 150,000 and comprising (a) from 10 to 70% by weight of monoethylenically unsaturated C4-C8-dicarboxylic acids or the salts thereof and (b) from 30 to 90% by weight of monoethylenically unsaturated C3-C10-monocarboxylic acids and/or the salts thereof, (2) graft polymers having a molecular weight of from 5,000 to 150,000, which are obtainable by free radical graft polymerization of (A) monoethylenically unsaturated C3-C10-carboxylic acids or the anhydrides and/or the salts thereof in the presence of (B) mono-, oligo- or polysaccharides and the derivatives thereof in a weight ratio (A) : (B) of (95 to 20) : (5 to 80), and/or (3) polyaminocarboxylic acids and/or polymers containing aminocarboxylic acid groups contain the components (I) and (II) in a weight ratio of from 10 : 0.5 to 0.5 : 10 and are used as additives for phosphate-free or low-phosphate textile detergents or as dispersants or coating inhibitors in cleaners for hard surfaces.
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公开(公告)号:CA2149746A1
公开(公告)日:1994-06-09
申请号:CA2149746
申请日:1993-11-11
Applicant: BASF AG
Inventor: PERNER JOHANNES , DIESSEL PAUL , GUEMBEL HELMUT , DENZINGER WALTER , HARTMANN HEINRICH , KRONER MATTHIAS
IPC: H04L27/20 , C02F5/10 , C08L33/02 , C08L35/00 , C08L51/02 , C08L77/04 , C11D3/37 , H04B7/00 , H04J3/16 , H04J3/22 , H04J3/24 , H04J11/00 , H04J13/00 , H04J13/18 , H04L20060101 , H04L1/00 , H04L1/08 , H04L12/00 , H04L27/30 , H04L29/06 , H04Q7/38
Abstract: Mixtures of (I) polymers of monoethylenically unsaturated dicarboxylic acids having a molecular weight of from 200 to 5,000 and (II) (1) copolymers having a molecular weight of from 10,000 to 150,000 and comprising (a) from 10 to 70% by weight of monoethylenically unsaturated C4-C8-dicarboxylic acids or the salts thereof and (b) from 30 to 90% by weight of monoethylenically unsaturated C3-C10-monocarboxylic acids and/or the salts thereof, (2) homo- and copolymers, each having a molecular weight of from 1,000 to 500,000 and obtained from monoethylenically unsaturated C3-C10-monocarboxylic acids, (3) graft polymers having a molecular weight of from 5,000 to 150,000, which are obtainable by free radical graft polymerization of (A) monoethylenically unsaturated C3-C10-carboxylic acids or the anhydrides and/or the salts thereof in the presence of (B) mono-, oligo- or polysaccharides and the derivatives thereof in a weight ratio (A) (B) of (95 to 20) (5 to 80), and/or (4) polyaminocarboxylic acids and/or polymers containing aminocarboxylic acid groups contain the components (I) and (II) in a weight ratio of from 10 : 0.5 to 0.5 : 10 and are used as additives for phosphate-free or low-phosphate textile detergents or as dispersants or coating inhibitors in cleaners for hard surfaces.
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