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    41.
    发明专利
    未知

    公开(公告)号：DE19913604A1

    公开(公告)日：2000-09-28

    申请号：DE19913604

    申请日：1999-03-25

    Applicant: BASF AG

    Inventor： MEYER FRANK ,  SCHUHMACHER PETER ,  PRECHTL FRANK

    IPC: C07D493/04 ,  A61K8/00 ,  A61K8/02 ,  A61K8/37 ,  A61K8/49 ,  A61Q5/00 ,  A61Q17/04 ,  C09K3/00 ,  C09K19/00 ,  C09K19/04 ,  C09K19/20 ,  C09K19/58 ,  C09K19/34

    Abstract: New chiral doping agents (I) comprise dianhydrohexitol derivatives containing at least one polymerizable group. Chiral doping agents of formula (I) are new. Z1-Y1-(A1)m-Y2-M-Y3-X-Y4-(A2)n-Y5-Z 2 (I) A1, A2 = spacers having a chain length of 1-30C; Y1-Y5 = direct bond, O, S, C(O), C(O)O, OC(O), CH=CHC(O)O, OC(O)O, C(O)N(R), N(R)C(O), CH2O, CH=N, N=CH or N=N; M = mesogenic group; R = H or 1-4C alkyl; Z1, Z2 = H, 1-4C alkyl, polymerizable group (PG) or residue carrying a PG, provided that at least one is a PG or residue carrying a PG; X = dianhydrosorbitol, dianhydromannitol or dianhydroiditol residue; m, n = 0 or 1. An Independent claim is included for cholesteric liquid crystal compositions (A) (which preferably reflect left-circular polarized light in the UV region), comprising at least one chiral liquid crystalline monomer (I) which provides a cholesteric liquid crystalline phase having a pitch of less than 450 nm, optionally mixed with at least one achiral liquid crystalline monomer of formula (II). Z1-Y1-(A1)m-Y2-M-Y4-(A2)n-Y5-Z2 (II)

    46.
    发明专利
    未知

    公开(公告)号：DE19824972A1

    公开(公告)日：1999-12-09

    申请号：DE19824972

    申请日：1998-06-04

    Applicant: BASF AG

    Inventor： SCHUHMACHER PETER ,  SCHNEIDER NORBERT ,  WESTENFELDER HORST ,  HAREMZA SYLKE ,  HABECK THORSTEN ,  MEYER FRANK

    IPC: A61K8/00 ,  A61K8/02 ,  A61K8/23 ,  A61K8/25 ,  A61K8/29 ,  A61K8/31 ,  A61K8/33 ,  A61K8/34 ,  A61K8/36 ,  A61K8/37 ,  A61K8/41 ,  A61K8/46 ,  A61K8/49 ,  A61K8/73 ,  A61K8/86 ,  A61K8/89 ,  A61K8/97 ,  A61K8/98 ,  A61K31/255 ,  A61K31/34 ,  A61P17/16 ,  A61Q1/00 ,  A61Q1/04 ,  A61Q1/10 ,  A61Q5/00 ,  A61Q17/04 ,  A61Q19/00 ,  C09B67/20 ,  C09C3/08 ,  C09K3/00 ,  A61K7/42 ,  A61K7/48

    Abstract: Liquid crystal compositions forming a cholesteric phase with a pitch of less than 450 nm, comprising either at least one polymerizable chiral liquid crystal monomer or a mixture of at least one polymerizable achiral liquid crystal monomer and at least one chiral additive, are used as ultraviolet filters for protecting skin or hair against solar radiation. Liquid crystal compositions forming a cholesteric phase with a pitch of less than 450 nm, comprising either: (a) at least one polymerizable chiral liquid crystal monomer of formula (I); or (b) a mixture of at least one polymerizable achiral liquid crystal monomer of formula (II) and at least one chiral additive, are used as ultraviolet (UV) filters in cosmetic and pharmaceutical compositions for protecting human skin or hair against solar radiation: A -A = spacers with a chain length of 1-30C; Y -Y = bonds, O, S, C(O)O, OC(O), CH=CHC(O)O, OC(O)O, C(O)N(R), N(R)C(O), CH2O, OCH2, CH=N, N=CH or N=N; M , M = mesogenic groups; R = H or 1-4C alkyl; Z = H, 1-4C alkyl or a polymerizable group, at least one being a polymerizable group; Z , Z = H, 1-4C alkyl or polymerizable groups, at least one being a polymerizable group; X = an n-valent chiral group; m, o, p = 0 or 1; n = 1-6. Independent claims are also included: (1) use of the liquid crystal compositions as photostable UV reflectors; (2) use of the liquid crystal compositions as UV stabilizers in cosmetic and pharmaceutical formulations; (3) pigments containing the polymerized liquid crystal compositions.

    48.
    发明专利
    未知

    公开(公告)号：BR9510303A

    公开(公告)日：1997-11-11

    申请号：BR9510303

    申请日：1995-11-21

    Applicant: BASF AG

    Inventor： BECK ERICH ,  MEYER FRANK ,  POTH ULRICH ,  SIEMENSMEYER KARL ,  SIERAKOWSKI CLAUDIA ,  GREIF NORBERT ,  OSTERTAG WERNER ,  ZIRNSTEIN MICHAEL ,  LEYRER REINHOLD ,  JAHNS EKKEHARD ,  ETZBACH KARL-HEINZ ,  SCHUHMACHER PETER

    IPC: C09K19/38 ,  C08F20/28 ,  C09B67/00 ,  C09D4/00 ,  C09D4/06 ,  C09D5/29 ,  C09D5/36 ,  C09D11/02 ,  C09D11/10 ,  C09D11/16 ,  C09K19/00 ,  C09K19/54 ,  C09K19/58

    Abstract: PCT No. PCT/EP95/04576 Sec. 371 Date May 23, 1997 Sec. 102(e) Date May 23, 1997 PCT Filed Nov. 21, 1995 PCT Pub. No. WO96/02597 PCT Pub. Date Feb. 1, 1996A process for coating or printing substrates with a coating or printing composition comprises applying a polymerizable material containing liquid-crystalline, polymerizable monomers which carry at least two polymerizable groups for coating and at least one polymerizable group for printing, to the substrate, and subsequently carrying out the polymerization, where the coating composition or the printing composition comprises a1) a chiral liquid-crystalline monomer and b) a polymeric binder and/or monomeric compounds which can be converted into the polymeric binder by polymerization, or, in the case of emulsion coatings and printing inks, a dispersion auxiliary d), or the coating composition or the printing composition comprises a2) an achiral liquid-crystalline monomer, b) a polymeric binder and/or monomeric compounds which can be converted into the polymeric binder by polymerization, or, in the case of emulsion coatings and printing inks, a dispersion auxiliary d), and c) a non-liquid-crystalline chiral compound.

    MEZCLAS DE SUBSTANCIAS FLUIDOCRISTALINAS.
    49.
    发明专利
    MEZCLAS DE SUBSTANCIAS FLUIDOCRISTALINAS. 未知

    公开(公告)号：ES2220401T3

    公开(公告)日：2004-12-16

    申请号：ES00905026

    申请日：2000-02-05

    Applicant: BASF AG

    Inventor： MEYER FRANK ,  ISHIDA HIROKI ,  SCHUHMACHER PETER ,  NEUMANN HORST

    IPC: G02F1/13 ,  B41M5/52 ,  B41M7/00 ,  C09D4/00 ,  C09D5/36 ,  C09D11/50 ,  C09K19/00 ,  C09K19/20 ,  C09K19/38 ,  C09K19/54

    Abstract: Mezclas de substancias fluidocristalinas que contienen como componentes A) una mezcla fluidocristalina, que contiene A1) un 40 a un 99, 5 % en peso, referido a la cantidad total de componente A, al menos de un compuesto de la **fórmula** Z1-Y1-A1-Y3-M-Y4-A2-Y2-Z2 y al menos un compuesto de la **fórmula** Z3-Y5-A3-Y7-M2-P en la que las variables, independientemente entre sí, tienen el siguiente significado: P hidrógeno, alquilo con 1 a 15 átomos de carbono, que puede estar substituido por uno o varios grupos metilo, flúor, cloro o bromo, y en el que grupos CH2 no adyacentes pueden estar substituidos por oxígeno, azufre, -CO-, -O-CO-, -CO-O- o -O-CO-O-, o una agrupación -Y8-A4-Y6- Z4, donde las variables tienen el significado descrito anteriormente, Z1 a Z2 agrupaciones polimerizables, Y1 a Y8 un enlace químico sencillo, oxígeno, azufre, -O-CO-, -CO-O-, -O-CO-O-, -CO-NR-, -NR-CO-, -O-CO-NR-, -NR-CO-O o -NR-CO-NR, Z1-Y1-, Z2-Y2-, Z3-Y5-, y en el caso dado Z4-Y6-, un grupo seleccionado a partir del grupo de metacriloiloxi, acriloiloxi y viniloxi, R hidrógeno o alquilo con 1 a 4 átomos de carbono.

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