-
公开(公告)号：IN123CH2000A
公开(公告)日：2005-07-22
申请号：IN123CH2000
申请日：2000-06-16
Applicant: BASF AG
Inventor： BRUNNER MELANIE , BOTTCHER ARND , BREITSCHEIDEL BORIS , HALBRITTER KLAUS , HENKELMANN JOCHEM , THIL LUCIEN , PINKOS ROLF
Abstract: The hydrogenation of esters of benzene-dicarboxylic acids is carried out on supported catalysts containing a Sub-Group VIIII metal on a macroporous support. A process for the hydrogenation of benzene-dicarboxylic acid ester(s) with hydrogen in presence of a supported catalyst containing Sub-Group VIII metal(s) on a macroporous support. If the ester is dimethyl terephthalate, this excludes hydrogenation on a catalyst containing ruthenium, with or without Sub-Group I, VII or VIII metal(s), on a support with an average pore diameter (APD) of at least 50 nm and a BET surface of not more than 30 m /g, with an active metal content of 0.01-30 wt.% and a ratio of (active metal surface):(support surface) of less than 0.05, and/or on a catalyst containing 0.01-30 wt.% active metal(s) as above on a support in which 10-50 vol.% of the pores consist of macropores with a diameter of 50-10,000 nm and 50-90 vol.% consist of mesopores with a diameter of 2-50 nm.
-
公开(公告)号：DE50006006D1
公开(公告)日：2004-05-13
申请号：DE50006006
申请日：2000-08-23
Applicant: BASF AG
Inventor： STAMM ARMIN , KNEUPER HEINZ-JOSEF , THIL LUCIEN , HENKELMANN JOCHEM
IPC: C07C263/10 , C07C265/08 , C07C265/10 , C07C265/12
Abstract: The present invention relates to a process for the preparation of aliphatic, cycloaliphatic, araliphatic and aromatic mono- and oligoisocyanates by phosgenation of the corresponding primary amines at atmospheric pressure, which comprisesa) introducing a catalytic amount of a monoisocyanate (isocyanate a) into an inert solvent together with phosgene;b) adding the primary amine, andc) reacting the resulting reaction mixture with phosgene.
-
公开(公告)号：DE59908919D1
公开(公告)日：2004-04-22
申请号：DE59908919
申请日：1999-11-26
Applicant: BASF AG
Inventor： THIL LUCIEN , BREITSCHEIDEL BORIS , DISTELDORF WALTER , ZELLER EDGAR , WALTER MARC , MORSBACH BERND , DORNIK KNUT
IPC: C07B61/00 , C07C29/14 , C07C31/125 , C07C67/08 , C07C69/44 , C07C69/80 , C08K5/05 , C08K5/10 , C08K5/11 , C08K5/12 , C08L27/06
Abstract: The mixture described is a mixture of isomeric nonanol diesters of a dicarboxylic acid, selected from the class consisting of a mixture of diesters of adipic acid in the 1H NMR spectrum of which, observed in CDCl3, the ratio of the area under the resonance signals at chemical shifts in the range from 1.0 to 2.0 ppm with respect to TMS to the area under the resonance signals at chemical shifts in the range from 0.5 to 1.0 ppm with respect to TMS is from 1.20 to 5.00 and a mixture of diesters of phthalic acid, in the 1H NMR spectrum of which, observed in CDCl3, the ratio of the area under the resonance signals at chemical shifts in the range from 1.1 to 3.0 ppm with respect to TMS to the area under the resonance signals at chemical shifts in the range from 0.5 to 1.1 ppm with respect to TMS is from 1.00 to 4.00.The diesters of adipic and phthalic acid are suitable as plasticizers for PVC-based molding compositions and have high compatibility, a low cold crack temperature, low torsional rigidity and/or high thermal stability.
-
公开(公告)号：AT263752T
公开(公告)日：2004-04-15
申请号：AT00951530
申请日：2000-08-23
Applicant: BASF AG
Inventor： STAMM ARMIN , KNEUPER HEINZ-JOSEF , THIL LUCIEN , HENKELMANN JOCHEM
IPC: C07C263/10 , C07C265/08 , C07C265/10 , C07C265/12
Abstract: The present invention relates to a process for the preparation of aliphatic, cycloaliphatic, araliphatic and aromatic mono- and oligoisocyanates by phosgenation of the corresponding primary amines at atmospheric pressure, which comprisesa) introducing a catalytic amount of a monoisocyanate (isocyanate a) into an inert solvent together with phosgene;b) adding the primary amine, andc) reacting the resulting reaction mixture with phosgene.
-
公开(公告)号：MX218972B
公开(公告)日：2004-02-04
申请号：MXPA00005882
申请日：2000-06-15
Applicant: BASF AG
Inventor： PINKOS ROLF , THIL LUCIEN , HALBRITTER KLAUS , HENKELMANN JOCHEM , BREITSCHEIDEL BORIS , BOTTCHER ARND , BRUNNER MELANIE
-
Patent Agency Ranking
公开(公告)号：NO20016148L
公开(公告)日：2002-01-16
申请号：NO20016148
申请日：2001-12-17
Applicant: BASF AG
Inventor： MAAS-BRUNNER MELANIE , THIL LUCIEN , BREITSCHEIDEL BORIS , OTTER RAINER
Abstract: The invention relates to the use of a cyclohexane polycarboxylic acid or of one of its derivatives, or of a mixture of one or more of said acids as plasticizers in the production of plastics which are rated toxicologically favourable. In animal experiments, using rodents, to which a daily oral dose of 1000 mg/kg body weight of the corresponding cyclohexane polycarboxylic acid, or a derivative thereof, or a mixture of two or more of said acids is administered by oesophageal tube over a period of at least 14 days, said dose, in comparison to untreated control animals, leads neither to a significant increase in the weight of the liver after treatment, nor to a doubling of the specific cyanide-insensitive palmitoyl-CoA oxidase activity, measured in the liver homogenisate.
-
公开(公告)号：ID30388A
公开(公告)日：2001-11-29
申请号：ID20001182
申请日：1998-12-18
Applicant: BASF AG
Inventor： BRUNNER MELANIE , BOTTCHER ARND , BREITSCHEIDEL BORIS , HALBRITTER KLAUS , HENKELMANN JOCHEM , THIL LUCIEN
Abstract: The hydrogenation of esters of benzene-dicarboxylic acids is carried out on supported catalysts containing a Sub-Group VIIII metal on a macroporous support. A process for the hydrogenation of benzene-dicarboxylic acid ester(s) with hydrogen in presence of a supported catalyst containing Sub-Group VIII metal(s) on a macroporous support. If the ester is dimethyl terephthalate, this excludes hydrogenation on a catalyst containing ruthenium, with or without Sub-Group I, VII or VIII metal(s), on a support with an average pore diameter (APD) of at least 50 nm and a BET surface of not more than 30 m /g, with an active metal content of 0.01-30 wt.% and a ratio of (active metal surface):(support surface) of less than 0.05, and/or on a catalyst containing 0.01-30 wt.% active metal(s) as above on a support in which 10-50 vol.% of the pores consist of macropores with a diameter of 50-10,000 nm and 50-90 vol.% consist of mesopores with a diameter of 2-50 nm.
-
公开(公告)号：AU5974600A
公开(公告)日：2001-01-09
申请号：AU5974600
申请日：2000-06-16
Applicant: BASF AG
Inventor： BRUNNER MELANIE , THIL LUCIEN , BREITSCHEIDEL BORIS , OTTER RAINER
Abstract: The invention relates to the use of a cyclohexane polycarboxylic acid or of one of its derivatives, or of a mixture of one or more of said acids as plasticizers in the production of plastics which are rated toxicologically favourable. In animal experiments, using rodents, to which a daily oral dose of 1000 mg/kg body weight of the corresponding cyclohexane polycarboxylic acid, or a derivative thereof, or a mixture of two or more of said acids is administered by oesophageal tube over a period of at least 14 days, said dose, in comparison to untreated control animals, leads neither to a significant increase in the weight of the liver after treatment, nor to a doubling of the specific cyanide-insensitive palmitoyl-CoA oxidase activity, measured in the liver homogenisate.
-
公开(公告)号：DE19924339A1
公开(公告)日：2000-11-30
申请号：DE19924339
申请日：1999-05-27
Applicant: BASF AG
Inventor： THIL LUCIEN , BREITSCHEIDEL BORIS , DISTELDORF WALTER , DORNIK KNUT , MORSBACH BERND
Abstract: New mixtures (I) of dicarboxylic acid diesters with isomeric nonanols consist of adipate or phthalate diester mixtures having 1H-NMR spectra (obtained in CDCl3) with specific ratios of surface areas below the resonance signals for particular chemical shifts towards TMS. The ratio of the surface area for shifts of 1.0-2.0 ppm to that for shifts of 0.5-1.0 ppm is 1.20-5.00 for the adipate diesters; and the ratio of the surface area for shifts of 1.1-3.0 ppm to that for shifts of 0.5-1.1 ppm is 1.00-4.00 for the phthalate diesters; An Independent claim is included for mixtures (II) of isomeric nonanols which either: (i) form (I) as defined above on esterification with adipic or phthalic acid; or (ii) are obtained by hydroformylation of a mixture of isomeric octenes in presence of a cobalt catalyst and hydrogenation of the product, where the isomeric octene mixture is obtained by contacting a hydrocarbon mixture containing butenes with a heterogeneous catalyst containing a nickel oxide.
-
公开(公告)号：DE19918051A1
公开(公告)日：2000-10-26
申请号：DE19918051
申请日：1999-04-21
Applicant: BASF AG
Inventor： THIL LUCIEN , BREITSCHEIDEL BORIS , DISTELDORF WALTER , ZELLER EDGAR , WALTER MARC , MORSBACH BERND
Abstract: New mixtures (I) of dicarboxylic acid diesters with isomeric nonanols consist of adipate or phthalate diester mixtures having 1H-NMR spectra (obtained in CDCl3) with specific ratios of surface areas below the resonance signals for particular chemical shifts towards TMS. The ratio of the surface area for shifts of 1.0-2.0 ppm to that for shifts of 0.5-1.0 ppm is 1.20-5.00 for the adipate diesters; and the ratio of the surface area for shifts of 1.1-3.0 ppm to that for shifts of 0.5-1.1 ppm is 1.00-4.00 for the phthalate diesters; An Independent claim is included for mixtures (II) of isomeric nonanols which either: (i) form (I) as defined above on esterification with adipic or phthalic acid; or (ii) are obtained by hydroformylation of a mixture of isomeric octenes in presence of a cobalt catalyst and hydrogenation of the product, where the isomeric octene mixture is obtained by contacting a hydrocarbon mixture containing butenes with a heterogeneous catalyst containing a nickel oxide.
-
-
-
-
-
-
-
-
-
Search Results
51
records
(took 0.025 seconds)
