45.
    发明专利
    未知

    公开(公告)号:AT488511T

    公开(公告)日:2010-12-15

    申请号:AT04731925

    申请日:2004-05-10

    Applicant: BASF SE

    Abstract: A method for the production of propylene oxide (PO) by reacting propene with a hydroperoxide in a nitrile-containing solvent in presence of a porous oxide-containing catalyst, involves using a zeolite catalyst with an X-ray crystal structure of the MWW type. An independent claim is also included for formed catalyst bodies containing the above type of zeolite.

    A PROCESS FOR PREPARING PROPYLENE OXIDE

    公开(公告)号:ZA201601117B

    公开(公告)日:2019-07-31

    申请号:ZA201601117

    申请日:2016-02-18

    Abstract: A continuous process for the preparation of propylene oxide, comprising (i) providing a liquid feed stream comprising propene, hydrogen peroxide, acetonitrile, water, optionally propane, and at least one dissolved potassium salt of a phosphorus oxyacid wherein the molar ratio of potassium relative to phosphorus in the at least one potassium salt of a phosphorus oxyacid is in the range of from 0.6 to 1.4; (ii) passing the liquid feed stream provided in (i) into an epoxidation reactor comprising a catalyst comprising a titanium zeolite of structure type MWW comprising zinc, and subjecting the liquid feed stream to epoxidation reaction conditions in the epoxidation reactor, obtaining a reaction mixture comprising propylene oxide, acetonitrile, water, the at least one dissolved potassium salt of a phosphorus oxyacid, optionally propene, and optionally propane; (iii) removing an effluent stream from the epoxidation reactor, the effluent stream comprising propylene oxide, acetonitrile, water, at least a portion of the at least one dissolved potassium salt of a phosphorus oxyacid, optionally propene, and optionally propane.

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