公开(公告)号：AU2003250996A1

公开(公告)日：2004-02-23

申请号：AU2003250996

申请日：2003-07-18

Applicant: BASF AG

Inventor： LOBER OLIVER ,  BENISCH CHRISTOPH ,  EBEL KLAUS ,  MELDER JOHANN-PETER

IPC: C07B61/00 ,  C07C213/02 ,  C07C217/58 ,  C07C253/30 ,  C07C255/54

Abstract: The invention relates to a process for preparing 4-[aminoalkoxy]benzylamines of the general formula (I) by catalytically hydrogenating 4-[aminoalkoxy]benzonitriles of the general formula (II) where, in the compounds of the general formulae I and II, R 1 is C 1 -C 8 -alkylene, R 2 and R 3 are each independently C 1 -C 8 -alkyl or are joined to give a ring which may additionally contain a heteroatom, which comprises carrying out the hydrogenation at elevated pressure and elevated temperatures. The invention further relates to a process for preparing the intermediate (II).

公开(公告)号：CA2463068A1

公开(公告)日：2003-05-01

申请号：CA2463068

申请日：2002-10-18

Applicant: BASF AG

Inventor： LUYKEN HERMANN ,  MELDER JOHANN-PETER ,  MAIXNER STEFAN ,  BENISCH CHRISTOPH ,  ANSMANN ANDREAS ,  BASSLER PETER ,  FISCHER ROLF-HARTMUTH

IPC: B01J37/18 ,  B01J23/745 ,  B01J23/889 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: The iron-containing catalyst suitable for use as a catalyst contains a) iron or a mixture containing iron and an iron-based compound. The iron has an average crystallite size ranging from 1-35 nm measured by X-ray diffraction.

公开(公告)号：DE10151559A1

公开(公告)日：2003-04-30

申请号：DE10151559

申请日：2001-10-23

Applicant: BASF AG

Inventor： ANSMANN ANDREAS ,  BENISCH CHRISTOPH ,  BASLER PETER ,  FISCHER ROLF-HARTMUTH ,  MAIXNER STEFAN ,  MELDER JOHANN-PETER ,  LUYKEN HERMANN

IPC: B01J37/18 ,  B01J23/745 ,  B01J23/889 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24 ,  B01J23/76 ,  C07B43/04 ,  C07C255/58

Abstract: The iron-containing catalyst suitable for use as a catalyst contains a) iron or a mixture containing iron and an iron-based compound. The iron has an average crystallite size ranging from 1-35 nm measured by X-ray diffraction.

公开(公告)号：DE10056840A1

公开(公告)日：2002-05-23

申请号：DE10056840

申请日：2000-11-16

Applicant: BASF AG

Inventor： ANSMANN ANDREAS ,  BENISCH CHRISTOPH ,  FUNKE FRANK ,  OHLBACH FRANK ,  MERGER MARTIN

IPC: C07D295/12 ,  C07B43/04 ,  C07B61/00 ,  C07C209/48 ,  C07C211/14 ,  C07C213/02 ,  C07C217/08 ,  C07C249/02 ,  C07C251/20

Abstract: A continuous hydrogenation of nitrites to primary amines, in a liquid phase over a suspended, activated Raney catalyst, involves hydrogenation in absence of ammonia and basic alkali or alkaline earth metal compounds. The Raney catalyst is produced from an aluminum alloy and transition metal(s) selected from a group comprising iron, cobalt, nickel, titanium, zirconium, chromium, and manganese.

公开(公告)号：CA2463068C

公开(公告)日：2010-08-03

申请号：CA2463068

申请日：2002-10-18

Applicant: BASF AG

Inventor： ANSMANN ANDREAS ,  BENISCH CHRISTOPH ,  BASSLER PETER ,  FISCHER ROLF-HARTMUTH ,  MAIXNER STEFAN ,  MELDER JOHANN-PETER ,  LUYKEN HERMANN

IPC: B01J23/745 ,  B01J37/18 ,  B01J23/889 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: The iron-containing catalyst suitable for use as a catalyst contains a) iron or a mixture containing iron and an iron-based compound. The iron has an average crystallite size ranging from 1-35 nm measured by X-ray diffraction.

公开(公告)号：UA79271C2

公开(公告)日：2007-06-11

申请号：UA20041007975

申请日：2003-03-03

Applicant: BASF AG

Inventor： BOEHLING RALF ,  STEINBRENNER ULRICH ,  FUNKE FRANK ,  MUELLER GUENTER ,  GAUS GUENTER ,  BENISCH CHRISTOPH

IPC: C07B61/00 ,  C07C209/60 ,  C07C211/05 ,  C07C211/08

Abstract: The invention relates to a method for producing ethyldimethylamine and triethylamine, comprising the steps of (i) reacting a mixture from diethylamine and dimethylamine with ethylene in the presence of a catalyst from the group of the alkali metal dimethylamides, alkali metal diethylamides and alkali metal hydrides, (ii) removing the catalyst, (iii) separating by distillation the obtained mixture into triethylamine and ethyldimethylamine and optionally diethylamine and dimethylamine, (iv) optionally returning the catalyst and the educt amines to the reaction. The inventive method allows the coupled production of ethyldimethylamine and diethylamine in a simple process.

公开(公告)号：BRPI0410243A

公开(公告)日：2006-05-16

申请号：BRPI0410243

申请日：2004-05-06

Applicant: BASF AG

Inventor： WINTERLING HELMUT ,  DEMETER JUERGEN ,  DEININGER JUERGEN ,  KORY GAD ,  SOETJE OLIVER ,  NEUHAUS RALF ,  KREMPEL KURT ,  BENISCH CHRISTOPH

IPC: C08G69/02 ,  C08G69/14 ,  C08G69/18

Abstract: Polyamide whose main chain contains a chemically bound N-alkyllactam, and processes for preparing such a polyamide and fibers, films and moldings comprising such a polyamide.

公开(公告)号：BRPI0409629A

公开(公告)日：2006-04-25

申请号：BRPI0409629

申请日：2004-05-06

Applicant: BASF AG

Inventor： WINTERLING HELMUT ,  DEMETER JUERGEN ,  DEININGER JUERGEN ,  KORY GAD ,  SOEJE OLIVER ,  WILMS AXEL ,  WEISS ROBERT ,  KREMPEL KURT ,  BENISCH CHRISTOPH

IPC: C08G69/02 ,  C08G69/08 ,  C08G69/14 ,  C08G69/26

Abstract: Polyamide, whose main chain contains a chemically bound amine selected from the group consisting of 2-methyl-1,5-diaminopentane and 1-amino-2-R-cyclopent-1-ene, where R is a functional group capable of combining with an amino group to form an amide group, and processes for preparing such a polyamide and fibers, films and moldings comprising such a polyamide.

公开(公告)号：IN2925CH2004A

公开(公告)日：2006-02-17

申请号：IN2925CH2004

申请日：2004-12-23

Applicant: BASF AG

Inventor： MAIXNER STEFAN ,  BENISCH CHRISTOPH ,  LUYKEN HERMANN ,  BASSLER PETER ,  FISCHER ROLF-HARTMUTH ,  MELDER JOHANN-PETER ,  ANSMANN ANDREAS

IPC: C07C209/84 ,  C07C211/09 ,  C07C211/12 ,  C07C253/34 ,  C07C255/09 ,  C07C255/24

Abstract: A process for reducing the level of an aliphatic monounsaturated amine (IV) in a mixture (V) containing an aminonitrile (I) or a diamine (II) or a dinitrile (III) or mixtures thereof as well as said mine (IV) by a) reacting said mixture (V) with an anionic nucleophile (VI) which contains a nucleophilic atom selected from the group consisting of oxygen, nitrogen and sulfur, which is capable of taking up an H + ion to form an acid having a pK a value in the range from 7 to 11, as measured in water at 25° C., and which has a relative nucleophilicity, as measured in methyl perchlorate/methanol at 25° C., in the range from 3.4 to 4.7 when said nucleophilic atom is oxygen, in the range from 4.5 to 5.8 when said nucleophilic atom is nitrogen, and in the range from 5.5 to 6.8 when said nucleophilic atom is sulfur, in an amount in the range from 0.01 to 10 mol per mole of said amine (IV) in said mixture (V) at a temperature in the range from 50 to 200° C. to obtain a mixture (VII), b) distilling said aminonitrile (I) or said diamine (II) or said dinitrile (III) or mixtures thereof from said mixture (VII) at a temperature in the range from 50 to 200° C. and at a pressure in the range from 0.1 to 100 kPa to obtain a bottom product (VIII), which comprises c) distilling an aminonitrile (I) or diamine (II) or dinitrile (III) or mixtures thereof from said bottom product (VIII) at a temperature which is lower than that chosen in step b).

公开(公告)号：BR0316178A

公开(公告)日：2005-09-27

申请号：BR0316178

申请日：2003-11-11

Applicant: BASF AG

Inventor： FISCHER ROLF-HARTMUTH ,  LUYKEN HERMANN ,  ANSMANN ANDREAS ,  BASSLER PETER ,  BENISCH CHRISTOPH ,  MAIXNER STEFAN ,  MELDER JOHANN-PETER

IPC: C07D201/08 ,  C07D201/16

Abstract: A process for removing high boilers from crude caprolactam which comprises high boilers, caprolactam and in some cases low boilers, and which has been obtained by a) reacting 6-aminocapronitrile with water to give a reaction mixture b) removing ammonia and unconverted water from the reaction mixture to obtain crude caprolactam, which comprises c) feeding the crude caprolactam to a distillation apparatus to obtain a first substream via the top as a product and a second substream via the bottom, by setting the pressure in the distillation in such a way that the bottom temperature does not go below 170° C., and adjusting the second substream in such a way that the caprolactam content of the second substream is not less than 10% by weight, based on the entire second substream.