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公开(公告)号:ES2265061T3
公开(公告)日:2007-02-01
申请号:ES02790296
申请日:2002-10-18
Applicant: BASF AG
Inventor: GERST MATTHIAS , LAUBENDER MATTHIAS , RECK BERND
IPC: C08L101/00 , C09D151/00 , C08F257/02 , C08F265/04 , C08F291/00 , C08G59/42 , C08K5/15 , C08K5/1515 , C08K5/17 , C08L33/02 , C08L35/00 , C08L51/00 , C08L63/00 , D04H1/64 , D06M13/11 , D06M15/263
Abstract: Agentes aglutinantes termoendurecibles, a base de una dispersión polímera acuosa, que contiene - un polímero en emulsión (en abreviatura EP), - un polímero, que está constituido al menos por un 5% en peso de un ácido carboxílico, un ácido dicarboxílico o un anhídrido de ácido dicarboxílico monoetilénicamente insaturado (en abreviatura polímero ácido - compuestos epóxido monofuncionales o multifuncionales como endurecedores y, como endurecedores, además, un poliol o una alcanolamina con al menos dos grupos hidroxilo.
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公开(公告)号:DE50207584D1
公开(公告)日:2006-09-07
申请号:DE50207584
申请日:2002-01-16
Applicant: BASF AG
Inventor: KRONER MATTHIAS , GERST MATTHIAS , RECK BERNHARD
Abstract: The present invention relates to the use of compositions comprising reaction products of low molecular mass dicarboxylic or tricarboxylic acids with ammonia to produce moldings comprising finely divided materials.
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公开(公告)号:AT334158T
公开(公告)日:2006-08-15
申请号:AT02001203
申请日:2002-01-16
Applicant: BASF AG
Inventor: KRONER MATTHIAS , GERST MATTHIAS , RECK BERNHARD
Abstract: The present invention relates to the use of compositions comprising reaction products of low molecular mass dicarboxylic or tricarboxylic acids with ammonia to produce moldings comprising finely divided materials.
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公开(公告)号:CA2575167A1
公开(公告)日:2006-03-02
申请号:CA2575167
申请日:2005-08-04
Applicant: BASF AG
Inventor: GERST MATTHIAS , MICHL KATHRIN , FAUL DIETER , WITTELER HELMUT , KLIPPEL FRANK , DIETSCHE FRANK , GOTHLICH ALEXANDER
IPC: C08F220/04 , C08F222/02 , C09D133/02
Abstract: Partially neutralized carboxylate-rich copolymers, processes for their preparation and methods of using the same are disclosed, the copolymers comprising: monomers (A), (B), and (C); wherein monomer (A) comprises at least one monoethylenically unsaturated monocarboxylic acid, and is present in an amount of 30% to 79.99% by weight; wherein monomer (B) comprises at least one monoethylenically unsaturated dicarboxylic acid selected from the group consisting of acids corresponding to general formula I, acids corresponding to general formula II, anhydrides thereof, and other hydrolyzable derivatives thereof, and is present in an amount of 20.01% to 70% by weight: (HOOC)R1C-CR2(COOH) (I) R1R2C-C(-(CH2)n-COOH)(COOH) (II) wherein R1 and R2 each independently represent H or a straight-chain or branched, optionally substituted alkyl radical having 1 to 20 carbon atoms, or, in the case of (I), R1 and R2 together being an optionally substituted alkylene radical having 3 to 20 carbon atoms, and n represents an integer from 0 to 5; wherein monomer (C) comprises at least one additional ethylenically unsaturated comonomer, and is present in an amount of 0% to 40% by weight; wherein the carboxylate-rich copolymer is partially neutralized with at least one amine and the carboxylate-rich copolymer has a degree of neutralization of 2 to 18 mol %, based on the total amount of all COOH groups of the monocarboxylic and dicarboxylic acids; and wherein the carboxylate-rich copolymer has an average molecular weight Mw of at least 3000 g/mol.
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公开(公告)号:CA2536754A1
公开(公告)日:2005-03-24
申请号:CA2536754
申请日:2004-09-09
Applicant: BASF AG
Inventor: MICHL KATHRIN , GERST MATTHIAS
IPC: D06M15/263 , C03C25/26 , C03C25/30 , C08F222/02 , C08J5/24 , C09D4/02 , D04H1/4209 , D04H1/4218 , D04H1/587 , D04H1/64 , D04H1/645 , D06N5/00 , E04F15/16
Abstract: The invention relates to the use of an aqueous binding agent devoid of formaldehyde for substrates, having a large molecular weight distribution. Said binding agent contains (A) 0 - 100 wt. % of an ethylenically unsaturate d acid anhydride or an ethylenically unsaturated dicarboxylic acid, whereby th e carboxylic acid groups thereof can form an anhydride group, or mixtures thereof, (B) 100 - 0 wt.- % of an ethylenically unsaturated compound, (C) at least one polyfunctional cross-linking agent or mixtures thereof. The polyme rs made from A) and B), obtained by radical polymerisation, classified in a coodination system according to the average molecular weight thereof Mw and the polydispersity value thereof, are arranged on a surface above a straight line which is defined by the straight equation y = 1.25x + 20000 and is displaced in direction y in a parallel manner by at least + 3000. The x axis characterises the average weight of the molecule and the y axis characterise s the polydispersity multiplied by 10000.
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公开(公告)号:DE10304958A1
公开(公告)日:2004-08-19
申请号:DE10304958
申请日:2003-02-06
Applicant: BASF AG
Inventor: LAUBENDER MATTHIAS , GERST MATTHIAS , RECK BERND , WEBER MANFRED
IPC: B24D3/28 , B24D11/00 , C08F220/02 , C08F265/02 , C08F267/04 , C08J5/14 , C08K5/17 , C08L25/14 , C08L51/00 , C09J133/02 , C09D5/12 , B24D11/02 , C09D5/02
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公开(公告)号:DE10253498A1
公开(公告)日:2003-07-03
申请号:DE10253498
申请日:2002-11-16
Applicant: BASF AG
Inventor: FUESL RUEDIGER , MEYER-ROSCHER BERND , GERST MATTHIAS , SMINK EDUARD
IPC: C08F265/02 , C09D133/00 , C09J133/00 , C09J151/00 , C09D5/12 , C09J133/02
Abstract: Aqueous polymer dispersions for use as binders in wood glue contain polymers obtained by radical polymerisation of monomers in presence of copolymers of unsaturated mono- or di-carboxylic acids and esters of unsaturated acids with hydroxy-amines. The use of an aqueous polymer dispersion (D) containing dispersed particles of polymer(s) (A1) obtained by radical polymerisation in presence of a polymer (A2), as a binder in structural glues for wood. Polymer (A2) is derived from 50-99.5 wt% unsaturated mono- and/or di-carboxylic acid, 0.5-50 wt% unsaturated compound(s) selected from esters of unsaturated monocarboxylic acids and half-esters and di-esters of unsaturated dicarboxylic acids with hydroxy-amine(s) and up to 20 wt% other comonomer(s). An Independent claim is also included for the use as a wood glue binder of an aqueous solution (S) containing (A) a polymer obtained by radical polymerisation, comprising 5-100 wt% unsaturated acid anhydride or unsaturated dicarboxylic acid capable of forming an anhydride and (B) an alkanolamine with at least 2 hydroxyl groups.
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公开(公告)号:AU2002363088A1
公开(公告)日:2003-05-06
申请号:AU2002363088
申请日:2002-10-18
Applicant: BASF AG
Inventor: RECK BERND , GERST MATTHIAS , LAUBENDER MATTHIAS
IPC: C08L101/00 , C08F257/02 , C08F265/04 , C08F291/00 , C08G59/42 , C08K5/1515 , C08K5/17 , C08L33/02 , C08L35/00 , C08L51/00 , C08L63/00 , C09D151/00 , D04H1/64 , D06M13/11 , D06M15/263
Abstract: A heat-curable binder based on an aqueous polymer dispersion comprising an emulsion polymer (EP), a polymer composed of at least 5% by weight of an ethylenically unsaturated monocarboxylic acid, dicarboxylic acid or dicarboxylic anhydride (acid polymer SP for short), and monofunctional or polyfunctional epoxide compounds as curatives. The monofunctional or polyfunctional epoxide compound is stirred, preferably in the liquid state, into the aqueous polymer dispersion. Besides the epoxide compound, the heat-curable binder may further comprise a polyol or an alkanolamine as hardener.
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公开(公告)号:DE10125139A1
公开(公告)日:2002-12-05
申请号:DE10125139
申请日:2001-05-22
Applicant: BASF AG
Inventor: GERST MATTHIAS , LAUBENDER MATTHIAS , RECK BERND
IPC: C08L33/02 , C08F2/16 , C08F2/22 , C08F2/26 , C08F2/44 , C08F220/18 , C08F265/02 , C08K5/5415 , C08L35/00 , D04H1/58 , C08L57/00 , C09D5/02 , C09D5/12 , C09D183/10
Abstract: Aqueous polymer dispersions comprising an emulsion polymer, an acid polymer comprising at least 5 wt.% ethylenically unsaturated monocarboxylic acids, dicarboxylic acids or dicarboxylic acid anhydrides and an alkoxysilane are prepared by emulsion polymerization in the presence of at least a portion of the alkoxysilane. Aqueous polymer dispersions (I) comprising an emulsion polymer, an acid polymer comprising at least 5 wt.% ethylenically unsaturated monocarboxylic acids, dicarboxylic acids or dicarboxylic acid anhydrides and an alkoxysilane of formula SiR R R R (I) are prepared by emulsion polymerization in the presence of at least a portion of the alkoxysilane: R -R = an organic group of which at least one is an alkoxy group.
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