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    53.
    发明专利
    未知

    公开(公告)号：DE59108983D1

    公开(公告)日：1998-06-18

    申请号：DE59108983

    申请日：1991-06-15

    Applicant: BASF AG

    Inventor： REHMER GERD DR ,  BARWICH JUERGEN DR ,  AUCHTER GERHARD DR

    IPC: C08F2/00 ,  C08F2/04 ,  C08F2/06 ,  C08F220/10 ,  C08F220/18 ,  C08L33/04 ,  C08L33/08 ,  C09J133/04 ,  C09J133/08

    Abstract: Polymers of olefinically unsaturated monomers and solutions of polymers of olefinically unsaturated monomers obtainable by polymerising the olefinically unsaturated monomers in the presence of free radical-forming initiators in solution under otherwise prespecified polymerisation conditions in a process in which a solvent and/or a liquid part of one or more reaction components of the polymerisation batch is initially introduced and heated to the polymerisation temperature, and, while maintaining or initiating the polymerisation, some or all of the monomers to be polymerised are fed continuously, via at least one feed, to the initially introduced part of the polymerisation batch (which is kept in motion), in such a manner that the exit opening of the at least one feed is above the surface of the initially introduced liquid part of the polymerisation batch.

    56.
    发明专利
    未知

    公开(公告)号：AT145926T

    公开(公告)日：1996-12-15

    申请号：AT91107745

    申请日：1991-05-14

    Applicant: BASF AG

    Inventor： REHMER GERD DR ,  AUCHTER GERHARD DR ,  JAEGER HELMUT

    IPC: C08F20/12 ,  C08F2/50 ,  C08F8/00 ,  C08F8/14 ,  C08F8/30 ,  C08F8/32 ,  C08F20/34 ,  C08F20/36 ,  C08F20/52 ,  C08F20/58 ,  C08F220/10 ,  C08F220/12 ,  C09J4/00 ,  C09J4/02

    Abstract: Synthetic resins are obtainable by chemically bonding one or more compounds of the general formula I (* CHEMICAL STRUCTURE *) (I) where R1 is -OH, -NH2, (* CHEMICAL STRUCTURE *) -NHR3 or (* CHEMICAL STRUCTURE *) R2 is -H, -CH3 or -C2H5, R3 is -CmH2m+1, where m is from 1 to 6, R4 is -H or -CH3 and n is from 1 to 12, via the oxygen or nitrogen atom of R1 to one or more polymers A which consist of a) from 50 to 100% by weight of one or more esters of acrylic or methacrylic acid with monohydric alcohols of 1 to 18 carbon atoms or a mixture of these esters (monomers a) and b) from 0 to 50% by weight of other copolymerizable monomers (monomers b) in polymerized form, in amounts such that the synthetic resin contains from 0.01 to 1 mole of double bonds per kg of polymer A. After exposure to ultraviolet light or to electrons, these synthetic resins are suitable as contact adhesives.

    Material for adhesion to solid surfaces
    57.
    发明专利
    Material for adhesion to solid surfaces 未知

    公开(公告)号：DE4442684A1

    公开(公告)日：1996-06-05

    申请号：DE4442684

    申请日：1994-11-30

    Applicant: BASF AG

    Inventor： REHMER GERD DR ,  AUCHTER GERHARD DR ,  JAEGER HELMUT ,  BARWICH JUERGEN DR

    IPC: C09D133/06 ,  C09J133/06 ,  C08L33/06 ,  C08F218/04 ,  C08F220/18 ,  C08L31/02 ,  C09D4/00 ,  C09D131/02 ,  C09J11/06 ,  C09J131/02

    Abstract: A material for adhesion to solid surfaces contains (A) copolymer(s) of (a) 65-99.9 wt.% cpds. of formula CH2=CR -CO-OR (I). R = H or 1-4C alkyl; R = 1-18C alkyl; and/or vinyl esters of formula R -CO-O-CH=CH2 (II). R = 1-12C alkyl; (b) 0-6 wt.% alpha,beta-unsatd. 3-8C mono- and/or dicarboxylic acids and/or anhydrides of 3-8C diacids, (c) 0.1-4 wt.% (meth)acrylamido-glycolic acid and (d) 0-34.9 wt.% other unsatd. comonomers, pref. with 2-10 C atoms; (B) 0.05-5 wt.% (w.r.t. A) of a metal chelate, pref. a Zr chelate, and/or an opt. polymerised metal acid ester of formula RnT(OR )z (III) or (IV): T = di- to tetra-valent metal atom, pref. a Gp. II, III, IV or V metal, esp. pref. Ti; R = 1-8C alkyl or 6-16C aryl; R , R = 1-4C alkoxy or 1-18C aliphatic residue; R = as for R /R , or 1-4C alkylamino; n = 0 or a whole no.; z = at least 1, pref. at least 2; n + z = valency of T; (C) 10-900 wt.% (w.r.t. A) organic solvent or a mixt. thereof with water; and (D) opt. fillers, tackifying resins and/or stabilisers.

    58.
    发明专利
    未知

    公开(公告)号：ES2054981T3

    公开(公告)日：1994-08-16

    申请号：ES89119552

    申请日：1989-10-21

    Applicant: BASF AG

    Inventor： REHMER GERD DR ,  BOETTCHER ANDREAS DR ,  PFOEHLER PETER DR ,  AYDIN ORAL DR ,  NESTLER GERHARD DR

    IPC: C08J5/18 ,  C08F220/18 ,  C08L23/00 ,  C08L33/04 ,  C08L33/06 ,  C09J133/06

    Abstract: Compositions which can be crosslinked under an atmospheric oxygen atmosphere by means of ultraviolet irradiation and are based on (meth)acrylate copolymers having a K value of from 10 to 100, obtained by free-radical polymerisation in solid phase or solution of a) 5 to 97.4% by weight of i-amyl acrylate and/or i-amyl methacrylate and b) 0 to 89.9% by weight of (meth)acrylates whose hompolymers have a glass transition temperature of below -30 DEG C, c) 2.5 to 30% by weight of alpha , beta -monoolefinically unsaturated compounds whose homopolymers have a glass transition temperature of above - 30 DEG C, d) 0 to 10% by weight of monoolefinically unsaturated acids and/or anhydrides thereof, e) 0 to 20% by weight of further olefinically unsaturated monomers containing at least one of the following functional groups: hydroxyl, amide, epoxide, ether, ester, urethane, urea, primary, secondary or tertiary amine and ether, and f) 0.1 to 5% by weight of a copolymerisable benzophenone or acetophenone derivative, the sum of the percentages by weight x = a + b + c + d + f in each case being 100.

    60.
    发明专利
    未知

    公开(公告)号：DE58906988D1

    公开(公告)日：1994-03-24

    申请号：DE58906988

    申请日：1989-11-06

    Applicant: BASF AG

    Inventor： HORN PETER DR ,  REHMER GERD DR ,  LUTTER HEINZ-DIETER DR ,  RAMLOW GERHARD DR

    IPC: C08F216/14 ,  C08F218/10 ,  C08F220/28 ,  C08F220/58 ,  C08F222/20 ,  C08F226/00 ,  C08F226/06 ,  C08F290/06 ,  C08F299/02 ,  C08G18/40 ,  C08G18/62 ,  C08L75/04 ,  C09K23/52

    Abstract: The novel copolymers having K values of from 5 to 80 are prepared by free-radical polymerisation of A) 20 to 80% by weight, based on the total weight of (A) and (B), of at least one olefinically unsaturated polyoxyalkylene alcohol or polyester alcohol adduct, (B) 80 to 20% by weight, based on the total weight of (A) and (B), of at least one vinyl monomer from the group comprising N-vinylformamide, -2-pyrrolidone, -2-piperidone, -2-caprolactam, -imidazole, -2-ethyleneurea and -2-propyleneurea, C) 0 to 40 parts by weight of glycidyl acrylate and/or glycidyl methacrylate, D) 0 to 10 parts by weight of at least one alpha , beta -monoolefinically unsaturated acid and E) 0 to 30 parts by weight of at least one olefinically unsaturated carboxamide and/or carboxylate and/or styrene, the parts by weight of (C), (D) and (E) in each case being based on 100 parts by weight of the monomers (A) and (B). The copolymers are used as assistants and/or additives, for example as dispersion and/or emulsification assistants, or as additives for improving the mechanical properties, in formulations for the preparation of polyisocyanate polyaddition products.

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