52.
    发明专利
    未知

    公开(公告)号:AT200501T

    公开(公告)日:2001-04-15

    申请号:AT95925768

    申请日:1995-06-27

    Applicant: BASF AG

    Abstract: Biodegradable polyether esters P1 obtainable by reacting a mixture essentially comprising(a1) a mixture essentially comprising20-95 mol % of adipic acid or ester-forming derivatives thereof or mixtures thereof,5-80 mol % of terephthalic acid or ester-forming derivatives thereof or mixtures thereof, and0-5 mol % of a compound containing sulfonate groups,where the total of the individual mole percentages is 100 mol %, and(a2) a mixture of dihydroxy compounds essentially comprising(a21) from 15 to 99.8 mol % of a dihydroxy compound selected from the group consisting of C2-C6-alkanediols and C5-C10-cycloalkanediols,(a22) from 85 to 0.2 mol % of a dihydroxy compound containing ether functionalities of the formula Iwhere n is 2, 3 or 4 and m is an integer from 2 to 250, or mixtures thereof,where the molar ratio of (a1) to (a2) is chosen in the range from 0.4:1 to 1.5:1, with the proviso that the polyether ester P1 has a molecular weight (Mn) in the range from 5000 to 80,000 g/mol, a viscosity number in the range from 30 to 450 g/ml (measured in o-dichlorobenzene/phenol (50/50 ratio by weight) at a concentration of 0.5% by weight of polyether ester P1 at 25° C.) and a melting point in the range from 50 to 200° C., and with the further proviso that from 0.01 to 5 mol %, based on the molar quantity of component (a1) employed, of a compound D with at least three groups capable of ester formation are employed to prepare the polyether ester P1,and further biodegradable polymers and thermoplastic molding compositions, processes for the preparation thereof, the use thereof for producing biodegradable moldings and adhesives, biodegradable moldings, films and blends with starch obtainable from the polymers and molding compositions according to the invention.

    53.
    发明专利
    未知

    公开(公告)号:DE59702906D1

    公开(公告)日:2001-02-15

    申请号:DE59702906

    申请日:1997-10-10

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP97/05605 Sec. 371 Date Apr. 14, 1999 Sec. 102(e) Date Apr. 14, 1999 PCT Filed Oct. 10, 1997 PCT Pub. No. WO98/17719 PCT Pub. Date Apr. 30, 1998Thermoplastic molding compositions comprise A) from 30 to 97% by weight of a polyester, B) from 1 to 30% by weight of melamine cyanurate, C) from 1 to 30% by weight of at least one phosphorus-containing flame retardant which contains phosphorus in the valence state -1, -2 or -3, D) from 0 to 60% by weight of other additives and processing aids, where the total of the percentages by weight of components A) to D) is 100%.

    Method for producing polyamide 6 of a low extract content, high viscosity stability and low remonomerization rate

    公开(公告)号:AU3279800A

    公开(公告)日:2000-08-29

    申请号:AU3279800

    申请日:2000-02-10

    Applicant: BASF AG

    Abstract: The continuous process for producing polyamides by reacting at least one aminonitrile with water comprises the following steps:(10) reacting at least one aminonitrile with water at a temperature of from 200 to 290° C. at a pressure of from 40 to 70 bar in a flow tube containing a Brönsted acid catalyst selected from a beta-zeolite, sheet-silicate or metal oxide catalyst in the form of a fixed bed,(11) diabatically or adiabatically expanding the reaction mixture from step (1) into a first separation zone to a pressure of from 20 to 40 bar, the pressure being at least 10 bar lower than the pressure in step (1), and to a temperature within the range from 220 to 290° C. by flash evaporation and removal of ammonia, water and any aminonitrile monomer and oligomer,(12) further reacting the reaction mixture from step (2) in the presence of water at a temperature of from 200 to 290° C. and a pressure of from 25 to 55 bar and in the presence or absence of a Brönsted acid catalyst selected from a beta-zeolite, sheet-silicate or metal oxide catalyst in the form of a fixed bed,(13) diabatically or adiabatically expanding the reaction mixture from step (3) into a second separation zone to a pressure of from 0.01 to 20 bar, the pressure being at least 20 bar lower than the pressure in step (3), and to a temperature within the range from 220 to 290° C. by flash evaporation and removal of ammonia, water and any aminonitrile monomer and oligomer.

    57.
    发明专利
    未知

    公开(公告)号:DE59605251D1

    公开(公告)日:2000-06-21

    申请号:DE59605251

    申请日:1996-02-03

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP96/00457 Sec. 371 Date Aug. 14, 1997 Sec. 102(e) Date Aug. 14, 1997 PCT Filed Mar. 5, 1996 PCT Pub. No. WO96/25446 PCT Pub. Date Aug. 22, 1996Biodegradable polyesters having a molecular weight (Mn) of from 5000 to 50,000 g/mol (measured by gel permeation chromatography), a viscosity number of from 30 to 350 g/ml (measured in 50:50 by weight of o-dichlorobenzene/phenol at a concentration of 0.5% by weight of polyester at 25 DEG C.), and a melting point of from 50 to 170 DEG C., and having both hydroxyl and carboxyl end groups, the molar ratio of carboxyl end groups to hydroxyl end groups being greater than one, which is obtained by reacting a mixture consisting essentially of a1) a mixture consisting essentially of from 45 to 80 mol % of adipic acid or ester-forming derivatives thereof, or mixtures thereof, from 20 to 55 mol % of terephthalic acid or ester-forming derivatives thereof, or mixtures thereof, and from 0 to 5 mol % of a sulfonate compound, where the sum of the individual mole percentages is 100 mol %, and a2) a dihydroxy compound selected from the group consisting of C2-C6-alkanediols and C5-C10-cycloalkanediols, in the presence of from 0.01 to 5 mol %, per mol of component a1), of a compound D having at least three groups capable of ester formation, the molar ratio of a1) to a2) being from 0.4:1 to 1.5:1, polymers and biodegradable thermoplastic molding compositions, processes for their preparation and their use for producing biodegradable moldings, adhesives, foams and blends with starch obtained from the polymers or molding compositions.

    58.
    发明专利
    未知

    公开(公告)号:DK0792311T3

    公开(公告)日:1999-09-27

    申请号:DK95937865

    申请日:1995-11-04

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/04335 Sec. 371 Date May 12, 1997 Sec. 102(e) Date May 12, 1997 PCT Filed Nov. 4, 1995 PCT Pub. No. WO96/15175 PCT Pub. Date May 23, 1996A biodegradable polyester obtainable by reacting a mixture comprising (a1) from 95 to 99.9% by weight of a polyester P1 obtainable by reacting a mixture essentially comprising (b1) a mixture comprising 35-95 mol % of adipic acid or ester-forming derivatives thereof, 5-65 mol % of terephthalic acid or ester-forming derivatives thereof, and 0-5 mol % of a compound containing sulfonate groups, and (b2) a dihydroxy compound selected from the group consisting of C2-C6-alkanediols and C5-C10-cycloalkanediols, with the proviso that a compound D with at least three groups capable of ester formation is employed to prepare the polyester P1, (a2) from 0.1 to 5% by weight of a divinyl ether C1 and (a3) from 0 to 5 mol %, based on component (b1) from the preparation of P1, of compound D, and other biodegradable polymers and thermoplastic molding compositions, processes for the preparation thereof, the use thereof for producing biodegradable moldings and adhesives.

    60.
    发明专利
    未知

    公开(公告)号:DK0802942T3

    公开(公告)日:1998-11-16

    申请号:DK96900928

    申请日:1996-01-08

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP96/00067 Sec. 371 Date Jul. 3, 1997 Sec. 102(e) Date Jul. 3, 1997 PCT Filed Jan. 8, 1996 PCT Pub. No. WO96/21692 PCT Pub. Date Jul. 18, 1996Biodegradable polyesteramides as defined in the specification obtained by reacting a mixture consisting essentially of (a1) from 95 to 99.9% by weight of a polyesteramide, (a2) from 0.1 to 5% by weight of a divinyl ether, and (a3) from 0 to 5 mol % of compound D as defined in the specification, and other biodegradable polymers and thermoplastic molding compositions, processes for the preparation thereof, the use thereof for producing biodegradable moldings, and adhesives, biodegradable moldings obtained from the polymers and molding compositions according to the invention.

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