公开(公告)号：KR101451306B1

公开(公告)日：2014-10-17

申请号：KR1020130037569

申请日：2013-04-05

Applicant: 한국화학연구원

Inventor： 장광석 ,  이미혜 ,  가재원 ,  김윤호 ,  김진수 ,  윤준영

IPC: H01L51/05 ,  H01L51/40 ,  H01L29/786

Abstract: 본 발명은 유기절연체와 유기반도체 사이에 형성된 비정질의 금속산화물 층간-박막을 이용한 유기 박막 트랜지스터, 이의 제조방법 및 이를 이용한 유기 박막 트랜지스터의 전기적 특성 향상 방법에 관한 것으로, 구체적으로 유기절연체와 유기반도체 사이에 비정질의 금속산화물, 예를 들어 비정질의 알루미나 층간-박막을 형성시킴으로써 유기절연체의 절연특성은 저하시키지 않으면서 유기반도체의 분자정렬을 향상시킬 뿐만 아니라, 비정질 금속산화물 층간-박막을 형성시키기 위한 잔여 전구체 물질에 의해 전하이동이 향상시킴으로써, 유기 박막 트랜지스터의 전기적 특성을 향상시켜, 최종적으로 소자의 성능을 향상시키는 효과가 있다.
또한, 본 발명에 따른 유기절연체와 유기반도체 사이에 비정질의 금속산화물 층간-박막은 용액공정에 의한 코팅 및 저온의 열처리에 의해 형성될 수 있으므로, 투명-고분자 기판에도 적용이 가능할 뿐만 아니라 비용적으로 경제적이고 공정이 간소하므로 차세대 플렉서블 유기 박막트랜지스터의 제조에 유용하게 사용될 수 있다.

公开(公告)号：KR1020130132036A

公开(公告)日：2013-12-04

申请号：KR1020120056098

申请日：2012-05-25

Applicant: 한국화학연구원

Inventor： 가재원 ,  이미혜 ,  김진수 ,  김윤호 ,  장광석 ,  김희주 ,  박정신

IPC: C07D405/14 ,  C07D407/10 ,  C07D409/14 ,  G02F1/1337

Abstract: The present invention relates to photo-initiator free polymerizable mesogen and a polymerizable liquid crystal composition containing the same. More specifically, the polymerizable mesogen uses furyl acrylate as a photosensitive group to be photocrosslinked without using a photo-initiator, to be polymerized at relatively low energy, to have excellent solubility with the host liquid crystal by having an asymmetric structure, and to have an effect of increasing the stability of linear gradient after photocrosslinking using the polymerizable mesogen for the polymerizable liquid crystal composition, especially the polymerizable liquid crystal composition for a polymer stabilization oriented liquid display. [Reference numerals] (AA) Photocurable degree (%);(BB) Example 6;(CC) Comparative example 1;(DD) Irradiation energy (J/cm^2)

Abstract translation: 本发明涉及无引发剂的可聚合介晶和含有它的可聚合液晶组合物。 更具体地，可聚合的介晶使用丙烯酸呋喃酯作为光敏基团而不使用光引发剂，以相对低的能量聚合，通过具有不对称结构与主体液晶具有优异的溶解性，并且具有 使用可聚合液晶组合物的可聚合介晶，特别是用于聚合物稳定化液晶显示器的可聚合液晶组合物，在光致交联后增加线性梯度的稳定性的效果。 （AA）光固化度（％）;（BB）实施例6;（CC）比较例1（DD）照射能（J / cm ^ 2）

公开(公告)号：KR101302418B1

公开(公告)日：2013-08-30

申请号：KR1020120036246

申请日：2012-04-06

Applicant: 한국화학연구원

Inventor： 가재원 ,  이미혜 ,  김희선 ,  서민혜 ,  장광석 ,  김진수

IPC: C08G61/12 ,  C08L65/00 ,  H01B3/30 ,  H01L51/00

CPC classification number: C08G61/12 ,  C08G61/123 ,  C08G73/22 ,  C08G2261/3245 ,  C08G2261/92 ,  C08L65/00 ,  C09D179/04 ,  H01B3/30 ,  H01B3/307 ,  H01L51/052

Abstract: PURPOSE: A polymer compound is provided to have excellent chemical resistance, especially base resistance, excellent insulating performance, and heat resistance by a solution process. CONSTITUTION: A polymer compound is represented by chemical formula 1. A polymer compound having a repeating unit represented by chemical formula 1 can be dissolved into dimethylacetamide, dimethylformamide, N-methyl-2-pyrrolidone, acetone, and ethylacetate. A thin film transistor includes a glass or plastic substrate (1), a gate electrode (2), an organic insulating film (3), an organic semiconductor layer or an inorganic semiconductor layer (4), a source electrode (5), and a drain electrode (6). The organic insulating film includes the polymer compound.

Abstract translation: 目的：提供高分子化合物以具有优异的耐化学性，特别是耐碱性，优异的绝缘性能和通过溶液方法的耐热性。 构成：高分子化合物由化学式1表示。具有化学式1表示的重复单元的高分子化合物可以溶解在二甲基乙酰胺，二甲基甲酰胺，N-甲基-2-吡咯烷酮，丙酮，乙酸乙酯中。 薄膜晶体管包括玻璃或塑料基板（1），栅电极（2），有机绝缘膜（3），有机半导体层或无机半导体层（4），源电极（5）和 漏电极（6）。 有机绝缘膜包括高分子化合物。

公开(公告)号：KR1020120115606A

公开(公告)日：2012-10-19

申请号：KR1020110016412

申请日：2011-02-24

Applicant: 한국화학연구원

Inventor： 가재원 ,  이미혜 ,  정혜인 ,  박정신 ,  김진수 ,  이계형

IPC: C07C237/20 ,  C07C233/88 ,  C09K19/32 ,  G02F1/1335

CPC classification number: C09K19/32 ,  C09K2019/328 ,  G02F1/13363 ,  G02F2001/133633

Abstract: PURPOSE: An acetylene-containing triphenylene-based reactive mesogen compound is provided to manufacture a thin film from a reinforcing film because of high double reflectivity. CONSTITUTION: An acetylene-containing triphenylene-based reactive mesogen compound is indicated in chemical formula 1. In chemical formula 1, X is selected from O, NH and S, L is selected from R, C(=O)R, C(=O)ArOR and -C(=O)ArNHR, Y is selected from CH2, Ar, ArO, ArS, ArNH, C(=O), C(=O)O, C(=O)NH, C(=O)Ar, C(=O)ArO, C(=O)ArS, C(=O)ArNH, ArC(=O), ArC(=O)O, ArC(=O)S and ArC(=O)NH, Z is selected from -OC(O)CH=CH2, -OC(O)C(CH3)=CH2, a functional group indicated in chemical formula a, a functional group indicated in chemical formula b, -NHC(O)CH=CH2, -NHC(O)C(CH3)=CH2, a functional group in chemical formula c, a functional group indicated in chemical formula d, A is selected from -R', C(=O)R', and -R'-Z, R is C1-20 alkylene, Ar is C6-30 arylene, and R' is C1-20 alkyl.

Abstract translation: 目的：提供含乙炔的三亚苯基反应性液晶元素化合物，由于双重反射率的高度，从加强膜制造薄膜。 化学式1中，X选自O，NH和S，L选自R，C（= O）R，C（= O）ArOR和-C（= O）ArNHR，Y选自CH 2，Ar，ArO，ArS，ArNH，C（= O），C（= O）O，C（= O）NH，C（= O ）Ar，C（= O）ArO，C（= O）ArS，C（= O）ArNH，ArC（= O），ArC（= O）O，ArC（= O） ，Z选自-OC（O）CH = CH 2，-OC（O）C（CH 3）= CH 2，化学式a表示的官能团，化学式b表示的官能团，-NHC（O）CH = CH 2，-NHC（O）C（CH 3）= CH 2，化学式c中的官能团，化学式d表示的官能团，A选自-R'，C（= O）R' R'-Z，R为C 1-20亚烷基，Ar为C 6-30亚芳基，R'为C 1-20烷基。

公开(公告)号：KR1020120063704A

公开(公告)日：2012-06-18

申请号：KR1020100124795

申请日：2010-12-08

Applicant: 한국화학연구원

Inventor： 김진수 ,  이미혜 ,  가재원 ,  박지민 ,  이계형

IPC: C09K19/32 ,  C09K19/34 ,  C08J5/18

Abstract: PURPOSE: A polymerizable liquid crystal compound is provided to enhance isotropic phase transition temperature, optical anisotropy, polymerization, and compatibility. CONSTITUTION: A polymerizable liquid crystal compound is represented by chemical formula 1. Here, X is independently selected from hydrogen and C1-12 straight-chain or side chain alkyl, L is -(C=O) -, - (C=O) -O-, - (C=O) -CH=CH-, - (C=O) -C≡C-, or - (C=O) -NR^1-, Ar is C6-12 monoaryl group, biaryl group, or C5-10 heteroaryl group, R is independently selected from hydrogen and C1-12 straight-chain or side chain alkyl, and P is -OCOCH=CH2, - OCOC (CH3) =CH2, - OCH 2, -OCOCH=CH-Ph, functional group of chemical formula 1a, -O-CH=CH2, -OCH2CH=CH2, functional group of chemical formula 1b, or functional group of chemical formula 1c.

Abstract translation: 目的：提供可聚合液晶化合物，以提高各向同性相转变温度，光学各向异性，聚合和相容性。 构成：可聚合的液晶化合物由化学式1表示。这里，X独立地选自氢和C 1-12直链或侧链烷基，L是 - （C = O） - ， - （C = O） -O - ， - （C = O）-CH = CH-， - （C = O）-C≡C-或 - （C = O）-NR 1 - ，Ar为C 6-12单芳基， 基团或C5-10杂芳基，R独立地选自氢和C1-12直链或侧链烷基，P是-OCOCH = CH 2，-OCOC（CH 3）= CH 2，-OCH 2，-OCOCH = CH-Ph，化学式1a的官能团，-O-CH = CH 2，-OCH 2 CH = CH 2，化学式1b的官能团或化学式1c的官能团。

公开(公告)号：KR1020110026460A

公开(公告)日：2011-03-15

申请号：KR1020110017361

申请日：2011-02-25

Applicant: 한국화학연구원

Inventor： 안택 ,  이미혜 ,  김지영

IPC: C08G73/10 ,  C08G61/12 ,  H01L29/786

CPC classification number: C08G73/10 ,  C08G61/12 ,  H01L51/052

Abstract: PURPOSE: A low temperature-processable and photo-crosslinkable organic insulator is provided to reduce a hardening temperature of an organic insulator and to improve an insulation property by reacting a polyimide organic insulator showing thermal stability and excellent chemical resistance with photo-crosslinkable group. CONSTITUTION: An organic thin film transistor includes a gate electrode, an organic insulating film, an organic semiconductor layer, a source electrode and a drain electrode on a glass and plastic substrate. The organic insulating film is formed by applying a coating solution containing a polyimide-based organic polymer having a unit represented by chemical formula 1 on a substrate in which a gate electrode is formed and photo-curing the substrate.

Abstract translation: 目的：提供低温加工和光交联的有机绝缘体，以降低有机绝缘体的硬化温度，并通过使具有热稳定性和优异耐化学性的聚酰亚胺有机绝缘体与光交联性基团反应来提高绝缘性能。 构成：有机薄膜晶体管包括在玻璃和塑料衬底上的栅电极，有机绝缘膜，有机半导体层，源电极和漏电极。 有机绝缘膜通过在其上形成有栅电极的基板上涂布含有由化学式1表示的单元的聚酰亚胺类有机聚合物的涂布溶液形成，并使基板光固化。

公开(公告)号：KR1020110018668A

公开(公告)日：2011-02-24

申请号：KR1020090076251

申请日：2009-08-18

Applicant: 한국화학연구원

Inventor： 안택 ,  이미혜 ,  이진희 ,  김지영

IPC: C08L79/08 ,  H01L29/786 ,  H01B3/18

CPC classification number: C08L79/08 ,  H01B3/18 ,  H01L51/052

Abstract: PURPOSE: A composition for forming an organic insulator is provided to enable application to organic thin film transistors as driving switching devices in a next generation flexible display and photocuring by a low-temperature process and photopolymerization process. CONSTITUTION: A composition for forming an organic insulator comprises a polyimide derivative having a hydroxy group of chemical formula 1 and an epoxy compound of chemical formula 2 or an epoxy compound of chemical formula 3, and further at least one of photoinitiators or organic solvents. An organic thin film transistor successively includes glass or plastic substrate, gate electrode, organic insulating film, oragnic semiconductor layer, source electrode and drain electrode.

Abstract translation: 目的：提供一种用于形成有机绝缘体的组合物，可用于下一代柔性显示器中的驱动开关器件和通过低温工艺和光聚合工艺进行光固化的有机薄膜晶体管。 构成：用于形成有机绝缘体的组合物包括具有化学式1的羟基的聚酰亚胺衍生物和化学式2的环氧化合物或化学式3的环氧化合物，以及光引发剂或有机溶剂中的至少一种。 有机薄膜晶体管依次包括玻璃或塑料基板，栅电极，有机绝缘膜，磁性半导体层，源电极和漏电极。

公开(公告)号：KR1020100114280A

公开(公告)日：2010-10-25

申请号：KR1020090032733

申请日：2009-04-15

Applicant: 한국화학연구원

Inventor： 안택 ,  이미혜 ,  김진수 ,  석혜정

IPC: H01L51/30 ,  H01L29/786

CPC classification number: C08G73/10 ,  C08L79/08 ,  H01L51/052

Abstract: PURPOSE: A photo-curable diamine monomer and polyimide, and organic thin film transistor using the same as an insulator are provided to improve the packing density and insulating property of an organic insulator thin film as well as to improve the chemical resistance of the thin film. CONSTITUTION: In a photo-curable diamine monomer and polyimide, and organic thin film transistor using the same as insulator, the molecular weight of polyimide is within 5,000-1,000,000 g/mol. The intrinsic viscosity of the polyimide is within 0.1-1.5dL/g. The polyimide has an insulating film formation temperature of 100-300300°C.

Abstract translation: 目的：提供光固化二胺单体和聚酰亚胺以及使用其作为绝缘体的有机薄膜晶体管，以提高有机绝缘体薄膜的堆积密度和绝缘性，以及提高薄膜的耐化学性 。 构成：在光固化二胺单体和聚酰亚胺以及与绝缘子相同的有机薄膜晶体管中，聚酰亚胺的分子量在5,000-1,000,000g / mol以内。 聚酰亚胺的特性粘度在0.1-1.5dL / g之内。 聚酰亚胺的绝缘膜形成温度为100-300300℃。

公开(公告)号：KR1020100045696A

公开(公告)日：2010-05-04

申请号：KR1020080104762

申请日：2008-10-24

Applicant: 한국화학연구원

Inventor： 정현민 ,  원종찬 ,  이미혜 ,  김용석 ,  임재필

IPC: B01J31/02 ,  C07C215/08

CPC classification number: B01J31/0202 ,  C07C215/08

Abstract: PURPOSE: A catalyst consisting to amino alcohol compounds for imidation and a manufacturing method of polyimide using the same are provided to promote imidation reaction at a low temperature, and to manufacture polyimide of high purity. CONSTITUTION: A catalyst for imidation is an amino alcohol compound indicated as a chemical formula 1. In the chemical formula 1, R1, R2, R3, and R4 are hydrogen atoms. N is 0 ~ 4 integer. A manufacturing method of polyimide includes a step for reacting polyamic acid under the amino alcohol compound circumference. The imidation reaction is performed in a temperature of 100 ~ 400 °C.

Abstract translation: 目的：提供由用于酰亚胺化的氨基醇化合物构成的催化剂和使用其的聚酰亚胺的制造方法，以促进低温下的酰亚胺化反应，制造高纯度的聚酰亚胺。 构成：用于酰亚胺化的催化剂是以化学式1表示的氨基醇化合物。在化学式1中，R 1，R 2，R 3和R 4是氢原子。 N为0〜4整数。 聚酰亚胺的制造方法包括在氨基醇化合物周长下使聚酰胺酸反应的工序。 酰亚胺化反应在100〜400℃的温度下进行。

公开(公告)号：KR1020080109387A

公开(公告)日：2008-12-17

申请号：KR1020070057623

申请日：2007-06-13

Applicant: 한국화학연구원

Inventor： 이미혜 ,  안택 ,  양윤철

IPC: C08G73/10 ,  C08J5/22 ,  G02F1/1337

CPC classification number: C08G73/10 ,  C08G73/1039 ,  C08G73/1064 ,  C08G73/1078 ,  C09D179/08 ,  G02F1/133723 ,  G02F1/133788

Abstract: A soluble polyimide photo-alignment layer is provided to ensure excellent heat resistance, surface hardness and transparency and to realize processability at a low-temperature. An alicyclic soluble polyimide resin for a low-temperature process comprises a unit of the chemical formula 1. In the chemical formula 1, m is a natural number of 1 - 500; R1 - R4 are independently hydrogen, C1~C30 linear or branched saturated or unsaturated alkyl group, C6~C12 aryl, C6~C30 aryl group substituted with C1~C30 alkoxy group or C6~C30 heteroaryl group. The aryl group can be substituted with C1~C30 linear or branched saturated or unsaturated alkyl, ester, carbonyl, halogen or amino group.

Abstract translation: 提供可溶性聚酰亚胺光取向层以确保优异的耐热性，表面硬度和透明度，并在低温下实现加工性能。 用于低温方法的脂环族可溶性聚酰亚胺树脂包括化学式1的单元。在化学式1中，m是1〜500的自然数; R1-R4独立地为氢，C1〜C30直链或支链饱和或不饱和的烷基，C6〜C12芳基，被C1〜C30烷氧基或C6〜C30杂芳基取代的C6〜C30芳基。 芳基可以被C1〜C30直链或支链饱和或不饱和的烷基，酯，羰基，卤素或氨基取代。