65.
    发明专利
    未知

    公开(公告)号:DE3785235D1

    公开(公告)日:1993-05-13

    申请号:DE3785235

    申请日:1987-01-15

    Applicant: BASF AG

    Abstract: The copolyethers (I) are prepd. by 1) polycondensing A1) bisphenol A, bis(4-hydroxyphenyl) sulphone, 2,4'-dihydroxydiphenyl sulphone, or 4,4'-dihydroxydiphenyl with A2) bis(4-chloro or 4-fluoro-phenyl) sulphone in presence of alkali metal carbonate in N-methylpyrrolidone (II) as solvent to give polyethersulphone blocks A, of no. average mol. wt. 1500-30,000 2) polymerising, onto ends of blocks A, polyether-ketone blocks B by reacting B1) hydroquinone with B2) 4,4'-difluorobenzophenone (III) or bis(4-fluorobenzoyl)benzene, molar ratio A2:B2 being 90:10-40:60. Pref. (I) are transparent and molar ratio A2:B2 is 90:10-65:35.

    Poly:aryl-ether-sulphone solns., esp. for bonding polyether-sulphones - contain polysulphone from mixed bisphenol units, in mixt. of DMA AND-or tetra:chloroethane and di:chloromethane

    公开(公告)号:DE3931650A1

    公开(公告)日:1991-04-11

    申请号:DE3931650

    申请日:1989-09-22

    Applicant: BASF AG

    Abstract: A polymer soln. (I) claimed, contg. at least 5 wt.% of a polymer made up of (A) 15-95 mol.% units of formula (II), (B) 5-85 mol.% units of formula (III) and (C) 0-60 mol.% units of formula (IV) in a solvent system comprising 50-100 wt.% dimethylacetamide (DMA) and/or 1,1,2,2-tetrachloroethane (TCE) and 0-50 wt.% CH2Cl2; R1-R6 = alkyl or alkoxy, aryl, Cl or F; x = direct bond, O, S, SO2 (only if a or b is not =0), CO or CR7R8 (with R7, R8 = H, 1-6C alkyl or alkoxy, or aryl; R7, R8 = Me only if a or b is not = 0); Q, W = CO or SO2; Z = O or direct bond; p, q, r = 0 or 1; a, b, c, d, e, f = 0, 1, 2, 3 or 4. USE/ADVANTAGE - Soln. (I) is useful for bonding or coating (claimed). The soln. has a good shelf life and the solvent does not evaporate too quickly when the soln. is applied (contrast prior-art polyarylether-sulphone adhesive solns.); the soln. gives strong joints and is useful esp. for bonding chemically similar thermoplastics.

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