公开(公告)号：BR9713951A

公开(公告)日：2000-03-21

申请号：BR9713951

申请日：1997-12-04

Applicant: BASF AG

Inventor： VOGELBACHER UWE JOSEF ,  KEIL MICHAEL ,  KLINTZ RALF ,  WAHL JOSEPH ,  WINGERT HORST ,  NIG HARTMANN K ,  RACK MICHAEL ,  TZ ROLAND G ,  TELES JOAQUIM HENRIQUE

IPC: C07D231/20 ,  C07D231/22

Abstract: PCT No. PCT/EP97/06780 Sec. 371 Date Jun. 14, 1999 Sec. 102(e) Date Jun. 14, 1999 PCT Filed Dec. 4, 1997 PCT Pub. No. WO98/27062 PCT Pub. Date Jun. 25, 1998A process is described for preparing N-substituted 3-hydroxypyrazoles of the formula I where R1 is unsubstituted or substituted alkyl, alkenyl, alkynyl, cycloalkyl, aryl or heteroaryl and R2, R3 are hydrogen, cyano, halogen and unsubstituted or substituted alkyl, alkenyl, alkynyl, cycloalkyl, aryl or heteroaryl, by oxidizing a corresponding pyrazolidin-3-one.

公开(公告)号：DE59507712D1

公开(公告)日：2000-03-02

申请号：DE59507712

申请日：1995-11-14

Applicant: BASF AG

Inventor： ISAK HEINZ ,  KEIL MICHAEL ,  WOLF BERND ,  WINGERT HORST ,  WETTLING THOMAS

IPC: C07B61/00 ,  C07C253/14 ,  C07C255/40

Abstract: PCT No. PCT/EP95/04463 Sec. 371 Date May 6, 1997 Sec. 102(e) Date May 6, 1997 PCT Filed Nov. 14, 1995 PCT Pub. No. WO96/16023 PCT Pub. Date May 30, 1996Halomethylbenzoyl cyanides I PH-CO-CN (I) where Ph is phenyl which is substituted by chloromethyl or bromomethyl and may cary 1-4 other rradicals, are prepared from halomethylbenzoyl chlorides II PH-CO-Cl (II), by reacting II with a cyanide-donating compound in the presence of a Lewis acid, if required in an inert organic solvent or diluent, and then isolating the product. The halomethylbenzoyl cyanides I are important intermediates for synthesizing crop protection agents.

公开(公告)号：GR3031313T3

公开(公告)日：1999-12-31

申请号：GR990402413

申请日：1999-09-22

Applicant: BASF AG

Inventor： BAYER HERBERT ,  ISAK HEINZ ,  WINGERT HORST ,  SAUTER HUBERT ,  KEIL MICHAEL ,  NETT MARKUS ,  BENOIT REMY ,  MUELLER RUTH

IPC: C07C67/22 ,  C07C69/716 ,  C07C69/738 ,  C07C235/78 ,  C07C249/08 ,  C07C249/12 ,  C07C251/48 ,  C07C251/60 ,  C07C255/41 ,  C07C255/62 ,  C07D249/12 ,  C07D521/00

Abstract: A process and intermediates for preparing alpha -methoxyiminocarboxylic acid methylamides (I) by Pinner reaction of a cyanoketone (II) with an alcohol and subsequent reaction of the resulting ester (IV) with hydroxylamine to give the oxime (V), methylation of (V) to give the oxime ether (VI) and subsequent reaction of (VI) with methylamine: +TR X = nitro, trifluoromethyl, halogen, alkyl or alkoxy; n = 0, 1, 2, 3 or 4; Y = a C-organic radical.

公开(公告)号：AU3930599A

公开(公告)日：1999-11-29

申请号：AU3930599

申请日：1999-05-04

Applicant: BASF AG

Inventor： RHEINHEIMER JOACHIM ,  DEYN WOLFGANG VON ,  GEBHARDT JOACHIM ,  RACK MICHAEL ,  LOCHTMAN RENE ,  GOTZ NORBERT ,  KEIL MICHAEL ,  WITSCHEL MATTHIAS ,  HAGEN HELMUT ,  MISSLITZ ULF ,  BAUMANN ERNST

IPC: C07C20060101 ,  C07C201/12 ,  C07C205/44 ,  C07C249/06 ,  C07C251/48 ,  C07C251/52 ,  C07C253/00 ,  C07C255/50 ,  C07C317/32 ,  C07C319/14 ,  C07C323/09 ,  C07D20060101 ,  C07D261/02 ,  C07D261/04 ,  C07D261/08 ,  C07D413/02 ,  C07D413/10 ,  C07C251/40

公开(公告)号：CA2652071A1

公开(公告)日：1999-11-18

申请号：CA2652071

申请日：1999-05-04

Applicant: BASF AG

Inventor： BAUMANN ERNST ,  KEIL MICHAEL ,  WITSCHEL MATTHIAS ,  GOETZ NORBERT ,  LOCHTMAN RENE ,  RACK MICHAEL ,  MISSLITZ ULF ,  VON DEYN WOLFGANG ,  GEBHARDT JOACHIM ,  HAGEN HELMUT ,  RHEINHEIMER JOACHIM

IPC: C07C251/48 ,  C07C20060101 ,  C07C201/12 ,  C07C205/44 ,  C07C249/06 ,  C07C251/52 ,  C07C253/00 ,  C07C255/50 ,  C07C315/04 ,  C07C317/32 ,  C07C317/36 ,  C07C319/14 ,  C07C319/20 ,  C07C321/28 ,  C07C323/09 ,  C07D20060101 ,  C07D261/02 ,  C07D261/04 ,  C07D261/08 ,  C07D413/02 ,  C07D413/10

Abstract: The invention relates to a method for producing isoxazolene of the formula (I): (See formula I) where the substituents have the following meanings: R1 is hydrogen, C1-C6 alkyl, R2 is C1-C6 alkyl, R3, R4, R5 are hydrogen, C1-C6 alkyl or R4 and R5 togethe r form a linkage, R6 is a heterocyclic ring, and n is 0, 1 or 2. Said method comprises the production of an intermediate compound of the formula (VI): (See formula VI) where R1, R3, R4 and R5 have the meanings given above. This step is followed by halogenation, thiomethylation, oxidation and acylation to yield compounds of formula (I). The invention also relates to new intermediate products for producing compounds of formula (I) and new methods for producing the intermediate products.

公开(公告)号：ES2135741T3

公开(公告)日：1999-11-01

申请号：ES95921761

申请日：1995-05-26

Applicant: BASF AG

Inventor： BAYER HERBERT ,  ISAK HEINZ ,  WINGERT HORST ,  SAUTER HUBERT ,  KEIL MICHAEL ,  NETT MARKUS

IPC: C07C67/22 ,  C07C69/716 ,  C07C69/738 ,  C07C235/78 ,  C07C249/08 ,  C07C249/12 ,  C07C251/48 ,  C07C251/60 ,  C07C255/41 ,  C07C255/62 ,  C07D249/12 ,  C07D521/00

Abstract: A process and intermediates for preparing alpha -methoxyiminocarboxylic acid methylamides (I) by Pinner reaction of a cyanoketone (II) with an alcohol and subsequent reaction of the resulting ester (IV) with hydroxylamine to give the oxime (V), methylation of (V) to give the oxime ether (VI) and subsequent reaction of (VI) with methylamine: +TR X = nitro, trifluoromethyl, halogen, alkyl or alkoxy; n = 0, 1, 2, 3 or 4; Y = a C-organic radical.

公开(公告)号：PL177244B1

公开(公告)日：1999-10-29

申请号：PL30293994

申请日：1994-04-07

Applicant: BASF AG

Inventor： ISAK HEINZ ,  WETTLING THOMAS ,  KEIL MICHAEL

IPC: C07C253/14 ,  C07C255/32 ,  C07C255/40

Abstract: A process for preparing halomethylbenzoyl cyanides I Ph-CO-CNI (Ph=phenyl radical substituted by chloromethyl or bromomethyl which, if desired, can additionally carry 1-4 further radicals) by reacting halomethylbenzoyl chlorides II Ph-CO-ClII with an alkali metal cyanide or transition metal cyanide, if appropriate in an organic diluent, and novel halomethylbenzoyl cyanides I' I' (X=halogen, C1-C4-alkyl, C1-C4-alkoxy, CF3, C1-C5-alkyl-(C1-C5-alkyl)hydroxyimino or C1-C5-alkyl-(C2-C5-alkenyl)hydroxyimino; m=0 to 4 and Y=chloromethyl or bromomethyl) are described. The halomethylbenzoyl cyanides I are important intermediates for the synthesis of plant protection agents.

公开(公告)号：CZ9902147A3

公开(公告)日：1999-09-15

申请号：CZ214799

申请日：1997-12-04

Applicant: BASF AG

Inventor： VOGELBACHER UWE JOSEF ,  KEIL MICHAEL ,  KLINTZ RALF ,  WAHL JOSEPH ,  WINGERT HORST ,  KONIG HARTMANN ,  RACK MICHAEL ,  GOTZ ROLAND ,  TELES JOAQUIM HENRIQUE

IPC: C07D231/20 ,  C07D231/22

CPC classification number: C07D231/22 ,  C07D231/20

公开(公告)号：DE59505986D1

公开(公告)日：1999-06-24

申请号：DE59505986

申请日：1995-11-21

Applicant: BASF AG

Inventor： WINGERT HORST ,  KEIL MICHAEL

IPC: C07C249/04 ,  C07C249/12 ,  C07C251/48

Abstract: PCT No. PCT/EP95/04580 Sec. 371 Date May 20, 1997 Sec. 102(e) Date May 20, 1997 PCT Filed Nov. 21, 1995 PCT Pub. No. WO96/16932 PCT Pub. Date Jun. 6, 1996A process for preparing oxime ethers of the general formula I I where R1 is a C-organic radical, R2 is hydrogen, alkoxy, cyano, nitro, SOR4, SO2R4, CO2-alkyl, P(O)(OR4)2 or a C-organic radical, and R3 and R4 are unsubstituted or substituted C1-C6-alkyl, entails converting an oxime of the general formula II II where the substituents R1 and R2 have the abovementioned meanings, in the presence or absence of an organic diluent, with a base into the corresponding salt, and reacting the latter with a dialkyl carbonate of the general formula III III where R3 has the abovementioned meanings.

公开(公告)号：HU215951B

公开(公告)日：1999-03-29

申请号：HU9701988

申请日：1995-11-21

Applicant: BASF AG

Inventor： KEIL MICHAEL ,  WINGERT HORST

IPC: C07C249/04 ,  C07C249/12 ,  C07C251/48

Abstract: PCT No. PCT/EP95/04580 Sec. 371 Date May 20, 1997 Sec. 102(e) Date May 20, 1997 PCT Filed Nov. 21, 1995 PCT Pub. No. WO96/16932 PCT Pub. Date Jun. 6, 1996A process for preparing oxime ethers of the general formula I I where R1 is a C-organic radical, R2 is hydrogen, alkoxy, cyano, nitro, SOR4, SO2R4, CO2-alkyl, P(O)(OR4)2 or a C-organic radical, and R3 and R4 are unsubstituted or substituted C1-C6-alkyl, entails converting an oxime of the general formula II II where the substituents R1 and R2 have the abovementioned meanings, in the presence or absence of an organic diluent, with a base into the corresponding salt, and reacting the latter with a dialkyl carbonate of the general formula III III where R3 has the abovementioned meanings.