公开(公告)号：SI1572613T1

公开(公告)日：2006-10-31

申请号：SI200330423

申请日：2003-12-01

Applicant: BASF AG

Inventor： MAYWALD VOLKER ,  HOFFMANN NICO ,  KEIL MICHAEL ,  VOGELBACHER UWE JOSEF ,  WEVERS JAN HENDRIK

IPC: C07C45/00 ,  C07C49/00 ,  C07C51/00

公开(公告)号：DE50304687D1

公开(公告)日：2006-09-28

申请号：DE50304687

申请日：2003-12-01

Applicant: BASF AG

Inventor： MAYWALD VOLKER ,  HOFFMANN NICO ,  KEIL MICHAEL ,  VOGELBACHER JOSEF ,  WEVERS HENDRIK

IPC: C07C45/46 ,  C07C45/81 ,  C07C49/84 ,  C07C51/363 ,  C07C51/60

Abstract: A process for preparing benzophenones of the formula I, where X may be chlorine, hydroxyl, methoxy or C 1 -C 6 -alkylcarbonyloxy, and Y may be chlorine or bromine, by reacting an acid chloride of the formula II where X and Y are as defined above with 3,4,5-trimethoxytoluene, which comprises carrying out the reaction in the presence of a) an aromatic hydrocarbon as a diluent and b) from 0.01 to 0.2 mol % of an iron catalyst, based on the acid chloride, c) at a temperature between 60° C. and the boiling point of the particular diluent.

公开(公告)号：CA2422075A1

公开(公告)日：2003-03-12

申请号：CA2422075

申请日：2001-09-12

Applicant: BASF AG

Inventor： ZIEGLER HANS ,  KROHL THOMAS ,  MAYWALD VOLKER ,  KOBER REINER ,  BERGHAUS RAINER

IPC: A01N25/04 ,  A01N25/30 ,  A01N43/18

Abstract: The invention relates to oil suspension concentrates based on 2-{1-[2-(4- chlorophenoxy)-propoxyimino]-butyl}-3-hydroxy-5-(tetrahydrothiopyran-3-yl)- cyclohex-2-enone lithium salt and certain formulation auxiliary agents, in addition to the use of said oil suspension concentrates as plant protecting agents, especially rice herbicides. Preferred formulation auxiliary agents a re monocarboxylic and/or dicarboxylic acid esters, e.g. liquid fatty acid ester s; anionic surfactants such as sulfonates, e.g. alkyl and alkylaryl sulfonates and sulfosuccinates; and non-ionic surfactants such as optionally ethoxylate d carboxylic acids and esters of monofunctional or polyfunctional alcohols, e. g. ethoxylated fatty acids and polyoxyethylene sorbitan fatty acid esters. The aforementioned oil suspension concentrates are stable in storage and have excellent properties of use.

公开(公告)号：PL348751A1

公开(公告)日：2002-06-03

申请号：PL34875199

申请日：1999-11-06

Applicant: BASF AG

Inventor： MAYWALD VOLKER ,  STEINMETZ ADRIAN ,  RACK MICHAEL ,  GOETZ NORBERT ,  GOETZ ROLAND ,  HENKELMANN JOCHEM ,  BECKER HEIKE ,  AISCAR BAYETO JUAN JOSE

IPC: C07D231/20

Abstract: The invention relates to a process for preparing 1-substituted 5- and/or 3-hydroxypyrazoles of the formulae I and IIin which R1 is C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl or C1-C4-alkoxy, where these groups may be substituted by halogen, C1-C4-alkoxy, phenoxy, C1-C6-alkoxycarbonyl, C1-C6-alkylthiocarbonyl or by a cyclic ring system having 3-14 ring atoms, which comprises reactingan alkyl 3-alkoxyacrylate of the formula IIIin which R2, R3 independently of one another are C1-C6-alkyl or C3-C6-cycloalkyl with a hydrazine of the formula IVin which R1 is as defined abovea) at a pH of 6-11 to give 5-hydroxypyrazoles of the formula I orb) at a pH of 11-14 to give 3-hydroxypyrazoles of the formula II.

公开(公告)号：BG105538A

公开(公告)日：2002-04-30

申请号：BG10553801

申请日：2001-05-22

Applicant: BASF AG

Inventor： MAYWALD VOLKER ,  STEINMETZ ADRIAN ,  RACK MICHAEL ,  GOETZ NORBERT ,  GOETZ ROLAND ,  HENKELMANN JOCHEM ,  BECKER HEIKE ,  AISCAR BAYETO JUAN J

IPC: C07D231/20

Abstract: The invention relates to a method for producing 1-substituted 5- and/or 3-hydroxypyrazoles of formulae wherein R1 represents C1-C6-alkyl,C2-C6-alkenyl, C2-C6-alkinyl, C3-C6-cycloalkyl or C1-C4-alkoxy, whereby these groups can be substituted by halogen, C1-C4-alkoxy, phenoxy, C1-C6-alkoxycarbonyl, or a cyclic ring system with 3-14 ring atoms, by reacting a 3-alkoxyacrylic acid alkyl ester for formula wherein R2, R3 independently means C1-C6-alkyl or C3-C6 cycloalkyl, with a hydrazine or formula wherein R1 has the above cited meaning, a) at a pH value of 6-11 to form 5-hydroxypyrazoles of formula or b) at a pH value of 11-14 to form 3-hydroxypyrazoles of formula (II). 13 claims

公开(公告)号：AU8594901A

公开(公告)日：2002-03-26

申请号：AU8594901

申请日：2001-09-12

Applicant: BASF AG

Inventor： KOBER REINER ,  BERGHAUS RAINER ,  KROHL THOMAS ,  ZIEGLER HANS ,  MAYWALD VOLKER

IPC: A01N25/04 ,  A01N25/30 ,  A01N43/18

Abstract: The present invention relates to oil suspension concentrates based on 2-{1-[2-(4-chlorophenoxy)propoxyimino]butyl}-3-hydroxy-5-(tetrahydrothiopyran-3-yl)cyclohex-2-enone lithium salt and certain formulation auxiliaries and to the use of the oil suspension concentrates as crop protection compositions and in particular as rice herbicides. Preferred formulation auxiliaries are mono- and/or dicarboxylic esters, for example fluid fatty acid esters, anionic surfactants of the sulfonate type, for example alkyl- and alkylarylsulfonates and also sulfosuccinates, and nonionic surfactants of the type of the nonethoxylated or ethoxylated carboxylic acids and esters of mono- or polyfunctional alcohols, for example ethoxylated fatty acids and polyoxyethylene sorbitan fatty acid esters.The oil suspension concentrates described herein are storage-stable and have excellent use properties.

公开(公告)号：AT214383T

公开(公告)日：2002-03-15

申请号：AT98962407

申请日：1998-12-02

Applicant: BASF AG

Inventor： MAYWALD VOLKER ,  GOETZ NORBERT ,  KUEKENHOEHNER THOMAS ,  BORCHERS DIRK ,  KOENIG HARTMANN ,  HARTMANN HORST ,  WAGNER RUPERT

IPC: C07D307/32 ,  C07D307/33 ,  C07D407/04

Abstract: A process for removing impurities from 3-(2'-acetoxyethyl)-dihydro-2(3H)-furanone (I), which comprises initially preparing the 3-(2'-acetoxyethyl)-dihydro-2(3H)-furanone containing the undesirable impurities in a manner known per se by acetylating 3-(2'-hydroxylethyl)-dihydro-2(3H)-furanone, subsequently treating it with strong mineral acids and finally removing the decomposition products of the undesirable impurities from I.

公开(公告)号：TR200101404T2

公开(公告)日：2002-01-21

申请号：TR200101404

申请日：1999-11-06

Applicant: BASF AG

Inventor： MAYWALD VOLKER ,  STEINMETZ ADRIAN ,  RACK MICHAEL ,  GOETZ NORBERT ,  GOETZ ROLAND ,  HENKELMANN JOCHEM ,  BECKER HEIKE ,  BAYETO JUAN JOSE AISCAR

IPC: C07D231/20

Abstract: The invention relates to a process for preparing 1-substituted 5- and/or 3-hydroxypyrazoles of the formulae I and IIin which R1 is C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl or C1-C4-alkoxy, where these groups may be substituted by halogen, C1-C4-alkoxy, phenoxy, C1-C6-alkoxycarbonyl, C1-C6-alkylthiocarbonyl or by a cyclic ring system having 3-14 ring atoms, which comprises reactingan alkyl 3-alkoxyacrylate of the formula IIIin which R2, R3 independently of one another are C1-C6-alkyl or C3-C6-cycloalkyl with a hydrazine of the formula IVin which R1 is as defined abovea) at a pH of 6-11 to give 5-hydroxypyrazoles of the formula I orb) at a pH of 11-14 to give 3-hydroxypyrazoles of the formula II.

公开(公告)号：CZ20002026A3

公开(公告)日：2000-09-13

申请号：CZ20002026

申请日：1998-12-02

Applicant: BASF AG

Inventor： MAYWALD VOLKER ,  GOETZ NORBERT ,  KUEKENHOEHNER THOMAS ,  BORCHERS DIRK ,  KOENIG HARTMANN ,  HARTMANN HORST ,  WAGNER RUPERT

IPC: C07D307/33

公开(公告)号：AU1380900A

公开(公告)日：2000-06-13

申请号：AU1380900

申请日：1999-11-06

Applicant: BASF AG

Inventor： MAYWALD VOLKER ,  STEINMETZ ADRIAN ,  RACK MICHAEL ,  GOTZ NORBERT ,  GOTZ ROLAND ,  HENKELMANN JOCHEM ,  BECKER HEIKE ,  BAYETO JUAN JOSE AISCAR

IPC: C07D231/20

Abstract: The invention relates to a process for preparing 1-substituted 5- and/or 3-hydroxypyrazoles of the formulae I and IIin which R1 is C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl or C1-C4-alkoxy, where these groups may be substituted by halogen, C1-C4-alkoxy, phenoxy, C1-C6-alkoxycarbonyl, C1-C6-alkylthiocarbonyl or by a cyclic ring system having 3-14 ring atoms, which comprises reactingan alkyl 3-alkoxyacrylate of the formula IIIin which R2, R3 independently of one another are C1-C6-alkyl or C3-C6-cycloalkyl with a hydrazine of the formula IVin which R1 is as defined abovea) at a pH of 6-11 to give 5-hydroxypyrazoles of the formula I orb) at a pH of 11-14 to give 3-hydroxypyrazoles of the formula II.