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公开(公告)号:DE50108088D1
公开(公告)日:2005-12-22
申请号:DE50108088
申请日:2001-05-10
Applicant: BASF AG
Inventor: BOEHME PETER , PCOLINSKI MICHAEL , ROTERMUND UDO , HABICHER WOLF-DIETER , ZIEMER ANTJE
Abstract: The invention relates to high-functionality polyether polyols of the general formula where each R' 1 is an unsubstituted or substituted aliphatic or aromatic radical and each R' 2 is an unsubstituted or substituted aliphatic or aromatic radical, H, OH, polyalkyl ether chain or halogen, each X is a polyalkyl ether chain or H, where at least one X is a polyalkyl ether chain, and m is an integer from 0 to 20, where Xm is H when m is 0, and n is an integer from 4 to 12, to processes for preparing such high-functionality polyether polyols and also to the use thereof for preparing polyurethanes and nonionic surfactants.
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公开(公告)号:DE10309798A1
公开(公告)日:2004-09-16
申请号:DE10309798
申请日:2003-03-05
Applicant: BASF AG
Inventor: ROTERMUND UDO , HEMPEL RENATE , RUDLOFF JAN , HENNIG INGOLF , MOEHWALD HELMUT , RAHNER DIETMAR , TROMMER KRISTIN
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公开(公告)号:DE10304344A1
公开(公告)日:2004-08-12
申请号:DE10304344
申请日:2003-02-03
Applicant: BASF AG
Inventor: BLEUEL ELKE , LEHMANN PIT , ROTERMUND UDO , SEITZ CHRISTIAN , BOEHME PETER
Abstract: Substituted bis[tetrakis(hydroxymethyl)phosphonium] salts are new. Substituted bis[tetrakis(hydroxymethyl)phosphonium] salts (I) of formula (1) are new. [Image] A : -CH2 or CH2-CH-E; E : 1-8(1-4)C alkylene; R : an organic group which in polyurethane comprises the corresponding isocyanate or its reaction products or in a prepolymer is the group of the added isocyanate; w, x, y, z : 1-20. Independent claims are included for: (1) a process for the production of salts (I) by reaction of tetrakis(hydroxymethyl)phosphonium salts of formula (10) with alkylene oxides; (2) polyurethanes, preferably rigid polyurethane foams having at least one structure of formula (2) - (9) in its matrix; (3) an isocyanate or hydroxyl group containing prepolymer containing at least one structure of formula (2) - (9) and; (4) a process for the production of flame retardant polyurethanes by reaction of polyisocyanates with isocyanate-reactive compounds having at least 2 reactive hydrogen atoms in the presence of a compound of formula (1) or (10). [Image] [Image] D : -CH2 or -CH2-CH-E; B : anion; a : whole number ensuring electroneutrality.
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公开(公告)号:AU2002351961A1
公开(公告)日:2003-05-26
申请号:AU2002351961
申请日:2002-11-12
Applicant: BASF AG
Inventor: SCHLEGEL KARL , ROTERMUND UDO , FALKE PETER , VOELKEL RUDIGER , HEMPEL RENATE
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公开(公告)号:DE10142262A1
公开(公告)日:2003-03-20
申请号:DE10142262
申请日:2001-08-29
Applicant: BASF AG
Inventor: BOEHME PETER , SLANY MICHAEL , ROTERMUND UDO , HEINZ MARION , OEHME GUENTHER , HABICHER WOLF-DIETER , PAETZOLD ECKHARD
IPC: B01J31/02 , B01J31/06 , B01J31/24 , C07B37/04 , C07B53/00 , C07C45/50 , C07C51/14 , C07C231/18 , C07C233/11 , C07B37/00 , C07B37/02 , C07B41/06 , C07B61/00 , C07C43/20 , C07C217/08
Abstract: A catalytically active composition comprises at least one Group 8 metal and at least one cyclic polyether polyol. A catalytically active composition (I) comprises at least one Group 8 metal and at least one cyclic polyether polyol of formula (1). R = H, alkyl, cycloalkyl, aryl or heteroaryl; R = H, alkyl, cycloalkyl, aryl, heteroaryl, WOR , WCOOR , WSO3R , WNE E , (CHR CH2O)xR or W-halogen; W = a single bond or a 1-20 divalent bridging group; R , E , E = H, alkyl, cycloalkyl or aryl; R = H, methyl or ethyl; x = 1-20; X , X = H, polyalkylene oxide or polyalkyleneimine having 1-20 alkylene oxide or alkylene imine units provided that at least one of X and X is a polyalkylene oxide or polyalkyleneimine; n = 4-12. An Independent claim is also included for the production of carbon-carbon and/or carbon-hydrogen (coupled) products using the composition (I).
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公开(公告)号:ES2175980T3
公开(公告)日:2002-11-16
申请号:ES99923570
申请日:1999-05-10
Applicant: BASF AG
Inventor: REICHELT MICHAEL , ROTERMUND UDO , HEMPEL RENATE , FALKE PETER , VON MALOTKI PETER , SEIFERT HOLGER
Abstract: Prepolymers which contain isocyanate groups, have an NCO content of at least 30.0% by weight and can be prepared by reacting an isocyanate mixture consisting predominantly of diphenylmethane diisocyanates and polyphenylpolymethylene polyisocyanates and having a proportion of two-ring isomers of not more than 74% by weight with at least 4-functional polyols or a mixture of polyols having a mean functionality of at least 4, where the polyols or polyol mixtures have a hydroxyl number of from 200 to 1650 mg KOH/g and a number average molecular weight of less than 1100 g/mol. The present invention also provides a process for preparing these prepolymers containing isocyanate groups, provides for their use for producing polyurethanes and provides a process for producing polyurethanes by reacting at least one novel prepolymer containing isocyanate groups, if desired in admixture with further organic and/or modified organic isocyanates (a), with compounds having at least two reactive hydrogen atoms (b) in the presence of, if desired, blowing agents (c), catalysts (d) and, if desired, further auxiliaries and/or additives (e).
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公开(公告)号:DE10046612A1
公开(公告)日:2002-03-28
申请号:DE10046612
申请日:2000-09-20
Applicant: BASF AG
Inventor: REICHELT MICHAEL , ROTERMUND UDO , BOEHME PETER
Abstract: Production of a purification agent comprises introducing a phosphoric acid and an isocyanate and/or polyisocyanate into a solvent such that, through time, a homogeneous solution is obtained. Independent claims are also included for (i) separation of metallic compounds from organic fluids by contacting with the purification agent and then separation off of the purified fluid; and (ii) a purification apparatus having a coating of the agent.
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公开(公告)号:MX199574B
公开(公告)日:2000-11-16
申请号:MX9707293
申请日:1997-09-24
Applicant: BASF AG
Inventor: ROTERMUND UDO , HEMPEL RENATE , SEIFERT HOLGER , WIEGMANN WERNER
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公开(公告)号:DE59800060D1
公开(公告)日:2000-01-13
申请号:DE59800060
申请日:1998-06-10
Applicant: BASF AG
Inventor: GLUECK GUISCARD , HAHN KLAUS , ROTERMUND UDO , VOLKERT OTTO
Abstract: In the production of rigid polyurethane (PUR) foam with low thermal conductivity by reacting (a) organic and/or modified organic polyisocyanates with (b) compounds containing NOTLESS 2 reactive hydrogen atoms in the presence of (c) blowing agent, (d) catalyst and optionally (e) ancillaries and/or additives, the novelty is that graphite is added to (a) and/or (b). Also claimed is rigid PUR foam produced in this way.
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公开(公告)号:DE19824134A1
公开(公告)日:1999-12-02
申请号:DE19824134
申请日:1998-05-29
Applicant: BASF AG
Inventor: GUETTES BERND , HINZ WERNER , HEMPEL RENATE , ROTERMUND UDO , WETTERLING MONIKA
Abstract: Reaction of acidified saccharide with an alkaline reagent and an alkylene oxide results in surface etherification or partial alkoxylation of the saccharide, whereby cleavage and side reactions are avoided. Combination of the alkoxylation product with sugar-based polyetherpolyol gives foamed polyurethane of increased heat resistance and profile stability on storage and decreased shrinkage. Compact or cellular oligo- and/or polysaccharide containing polyurethane is prepared by reaction of (a) high molecular compounds having at least two reactive H with (b) organic and/or inorganic modified organic di- and/or polyisocyanates; (c) a chain lengthening- and/or crosslinking agent; (d) a propellant; (e) catalysts; and (f) adjuvants. The high molecular compound (a) comprises (wt.%): (a1) saccharide containing compounds (1-100) and (a2) at least one polyol (0-99), relative to the total weight of (a). The saccharide containing compound (a1) comprises (wt.%): (a11) an alkoxylation component (1-99) and (a12) a polyoxyalkylenepolyol (1-99) of an oligo- and/or polysaccharide, relative to the total weight of alkoxylation component (a11), defined and prepared as below. Independent claims are included for: (1) An oligo- and/or polysaccharide alkoxylation component obtained by reaction of (wt.%): (a111) at least one oligo- and/or polysaccharide product (5-70) of pH 3.5-6 with (a112) an alkylene oxide (20-94.9), (a113) an alkali (0.1-10), relative to the total weight of alkoxylation component; (2) an oligo- and/or polysaccharide containing polyurethane prepared as above; a (3) shaped polyurethane parts obtained as above;
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