61.
    发明专利
    未知

    公开(公告)号:DE4126479A1

    公开(公告)日:1993-02-11

    申请号:DE4126479

    申请日:1991-08-09

    Applicant: BASF AG

    Abstract: Cyclohexenone oximethers have the formula (I), in which n is 0 to 5; m is 0 to 2; R stands for C1-C6 alkyl; R stands for C1-C4 alkyl or benzyl; A stands for C1-C6 alkylene, C3-C6 alkenylene, C3-C6 alkinylene, C3-C6 alkylene or C4-C6 alkenylene chains, all these elements being optionally substituted. In each of them a methylene group may be substituted by O, S, SO, SO2 or -N(R )-; R stands for H, C1-C4 alkyl, C3-C6 alkenyl, C3-C6 alkinyl; Z stands for phenyl, 5-membered heteroaromate or 6-membered heteroaromate with 1 to 4 N atoms; X stands for NO2, CN, halogen, C1-C4 alkyl, C1-C4 halogenalkyl, C1-C4 alkoxy, C1-C4 alkylthio, C1-C4 halogenalkoxy, COOH, C1-C4 alkoxycarbonyl, optionally substituted benzyloxycarbonyl, optionally substituted phenyl, optionally substituted pyridyl, -NR R ,; R stands for H, C1-C4 alkyl, C3-C6 alkenyl, C3-C6 alkinyl, R stands for H, C1-C4 alkyl, C3-C6 alkenyl, C3-C6 alkinyl C1-C6 acyl, optionally substituted benzoyl. The compounds having the formula (I), as well as their salts and esters of C1-C10 carboxylic and anorganic acids useful in agriculture, are suitable as herbicides.

    63.
    发明专利
    未知

    公开(公告)号:DE4105518A1

    公开(公告)日:1992-08-27

    申请号:DE4105518

    申请日:1991-02-22

    Applicant: BASF AG

    Abstract: The invention concerns sulfonyl urea derivatives of formula (I), wherein R stands for optionally substituted alkyl or phenyl; alkenyl or propargyl; alkylamino or dialkylamino; R stands for hydrogen, halogen, optionally halogen-substituted methyl, methoxy or ethoxy, an alklylsulfonyl group, nitro or cyano; R stands for difluoromethoxy, trifluoromethoxy, bromodifluoromethoxy, chlorodifluoromethoxy or fluorine; R stands for halogen, optionally halogen-substituted methyl, ethyl, methoxy or ethoxy or the methylamino or dimethylamino group; R stands for hydrogen, alkyl, alkenyl or an alkinyl; Z stands for CH or N, provided that a) if R stands for the difluoromethoxy group, R does not stand for a di(alkyl)amino group, R does not stand for an alkylsulfonyl group, and R does not stand for a methyl or methoxy group, b) if R stands for a fluorine atom and Z stands for nitrogen, R does not stand for an alkylamino group. The invention also concerns their salts. The sulfonyl urea derivatives can be used as herbicides.

    65.
    发明专利
    未知

    公开(公告)号:DE58901159D1

    公开(公告)日:1992-05-21

    申请号:DE58901159

    申请日:1989-08-31

    Applicant: BASF AG

    Abstract: 5-(N-3,4,5,6-Tetrahydrophthalimido)-cinnamic acid derivatives of the formula Ib Ib where the substituents have the following meanings: Y is chlorine, bromine or C1-C4-alkyl; R1 is hydrogen, C1-C8-alkyl, substituted or unsubstituted C2-C4alkyl, C3-C6-alkenyl, C3-C6-alkynyl, or substituted or unsubstituted phenyl or benzyl, R2 is C5-C8-alkyl, substituted or unsubstituted C2-C4-alkyl, C1-C6-alkoxy, C3-C6-alkenyl, C3-C6-alkenyloxy, C3-C6-alkynyl, C3-C6-alkynyloxy, or substituted or unsubstituted phenyl, phenoxy, benzyl or benzyloxy, R3 C1-C6-alkyl, or substituted or unsubstituted C2-C6-alkyl, methods of manufacturing these compounds, and their use as herbicides.

    New 1-oxo-3-hydroxy-2-cyclohexene-2-yl ketoxime ether(s)

    公开(公告)号:DE4033193A1

    公开(公告)日:1992-04-23

    申请号:DE4033193

    申请日:1990-10-19

    Applicant: BASF AG

    Abstract: 1-Oxo-3-hydroxy-2-cyclohexenyl ketoxime ethers of formula (I) are new. In (I) Q is H, 2-7 alkanoyl, benzoyl, alkali(ne earth) metal, opt. substd. ammonium, phosphonium, sulphonium, sulphoxonium or transition metal; W is CC or CH=CH; R1 is (a) alkoxyalkyl or alkylthioalkyl, (b) cycloalkyl, cycloalkenyl or 6-membered heterocyclyl contg. 1-2 nonadjacent O and/or S atoms, opt. substd. by 1-3 of OH, halogen, alkyl, haloalkyl, alkoxy or alkylthio, (c) 5-membered satd. heterocyclyl contg. 1-2 O and/or S atoms, opt. substd. by 1-3 of alkyl, haloalkyl, alkoxy or alkylthio, (d) 5-membered heteroaryl contg. 1-2 N atoms and/or an O or S atom, opt. substd. by 1-3 of CN, halogen, alkyl, haloalkyl, alkenyl, haloalkenyl, alkoxy, alkylthio, alkenyloxy or alkoxyalkyl, (e) phenyl or pyridyl opt. substd. by 1-3 of NO2, CN, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkoxyalkyl, alkylthioalkyl, alkenyloxy, alkynyloxy or NR8R9, or (f) R7X-substd. alkyl, where X is O, S, SO, or SO2 and R7 is alkyl, or phenyl or 5- or 6- membered heteroaryl opt. substd. as in (e); R8 is H, alkyl, alkenyl or alkynyl; R9 is H, alkyl, alkenyl, alkynyl, alkanoyl, or benzoyl opt. substd. by 1-3 of NO2, CN, halogen, alkyl, haloalkyl, alkoxy or alkylthio; R2 is alkyl; R3 is H or alkyl; R4 is H, halogen or alkyl; R5 is H or alkyl; or R3+R4, R3+R5 or R4+R5 are each alkylene or alkenylene; R6 is (a) H, alkyl, haloalkyl, phenylhaloalkyl, alkenyl, alkoxyalkyl or alkylthioalkyl, (b) cycloalkyl or cycloalkenyl, opt. substd. by 1-3 of OH, alkyl, haloalkyl, alkoxy, alkoxyalkyl or alkylthioalkyl or (c) phenyl or pyridyl opt. substd. by 1-3 of NO2, CN, OH, halogen, alkyl, haloalkyl, alkoxy, alkylthio, alkoxyalkyl or alkylthioalkyl. (B) Intermediates of formula (IIa) and (IIIa) are also new.

    68.
    发明专利
    未知

    公开(公告)号:DE3931786A1

    公开(公告)日:1991-04-04

    申请号:DE3931786

    申请日:1989-09-23

    Applicant: BASF AG

    Abstract: Pyrazole-3-carboxamides of the general formula I in which the substituents have the following meanings: R represents hydrogen or optionally substituted C3-C8-cycloalkyl or C1-C4-alkyl, R represents hydroxyl; amino; C1-C4-alkylamino; di-C1-C4-alkylamino, aminocarbonyl-C1-C6-alkyl, optionally substituted C1-C4-alkoxy, C3-C6-alkenyl, C3-C6-alkynyl, phenyl or naphthyl, optionally substituted 5- to 6-membered heterocycle; one of the groups mentioned under R or R and R together form a 4- to 7-membered chain which can contain as ring member one of the following groups in addition to methylene groups: oxygen, sulphur, N-methyl or carbonyl; R represents optionally substituted 5- to 6-membered heterocycle, optionally substituted C3-C6-alkenyl, C3-C6-alkynyl, 5,6,7,8-tetrahydronaphthyl or phenyl, or one of the groups mentioned under R ; R represents nitro; cyano; carboxyl; halogen; optionally substituted C1-C4-alkoxy or C1-C4-alkylthio, or one of the groups mentioned under R ; R represents 4,5-dihydrooxazol-2-yl or a group COYR ; Y represents oxygen or sulphur; R represents hydrogen; C3-C8-cycloalkyl, optionally substituted C1-C6-alkyl, C3-C6-alkenyl, C3-C6-alkynyl, C5-C7-cycloalkenyl or phenyl, optionally substituted 5- to 6-membered heterocycle; phthalimido; tetrahydrophthalimido; succinimido; maleimido; benzotriazolyl or a group -N=CR R where R is hydrogen or C1-C6-alkyl and R is C3-C6-cycloalkyl, phenyl, furyl or a radical R , or R and R together form a 4- to 7-membered alkylene chain, and their agriculturally useful salts, where Y is not oxygen and R is not hydrogen when R is hydrogen and R is nitro, trifluoromethyl, halogen or C1-C4-alkoxy, and -YR is not ethoxy when R is hydrogen, R is methyl and R is phenyl or substituted phenyl.

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