公开(公告)号：DE69322383D1

公开(公告)日：1999-01-14

申请号：DE69322383

申请日：1993-09-08

Applicant: STANDARD OIL CO OHIO

Inventor： FRIEDRICH MARIA S ,  SEELEY MICHAEL J ,  PAPARIZOS CHRISTOS ,  SURESH DEV D

IPC: B01J23/18 ,  B01J23/22 ,  B01J23/26 ,  B01J23/847 ,  B01J23/889 ,  C01C3/02 ,  C07B61/00 ,  C07C253/26 ,  C07C255/08

Abstract: Disclosed is a method for ammoxidizing C3 to C5 mono-olefins to a,b-mono-unsaturated acyclic nitriles having 3 to 5 carbon atoms and HCN by introducing such mono-olefins molecular oxygen and ammonia into a reaction zone into vapor phase contact with a solid ammoxidation catalyst, wherein the mol ratio of introduced molecular oxygen and ammonia to said introduced mono-olefin is at least 1.5 and 1.0, respectively, wherein said catalyst contains the elements and proportions indicated by the empirical formula: V1SbaMmNnOx where a = 0.5 to 2 M = one or more of: Sn, Ti, Fe, and Ga m = 0.05 to 3, usually at least 0.1 and at most 1 N = one or more of: W, Bi, Mo, Li, Mg, P, Zn, Mn, Te, Ge, Nb, Zr, Cr, Al, Cu, Ce, B n = 0.0 to 0.5, and wherein the preparation of the catalyst includes contacting in an aqueous dispersion a vanadium compound and an antimony compound while said vanadium is in solution.

公开(公告)号：SG47363A1

公开(公告)日：1998-04-17

申请号：SG1995001910

申请日：1995-02-17

Applicant: STANDARD OIL CO OHIO

Inventor： BLUM PATRICIA RAE ,  CIRJAK LARRY MICHAEL ,  LEMANSKI MICHAEL FRANCIS ,  PAPARIZOS CHRISTOS ,  PEPERA MARC ANTHONY ,  SURESH DEVASIRVATHAM DHANARAH

IPC: B01J21/08 ,  B01J23/44 ,  B01J23/52 ,  B01J23/56 ,  B01J23/58 ,  B01J23/60 ,  B01J23/62 ,  B01J23/63 ,  B01J23/644 ,  B01J23/648 ,  B01J23/66 ,  B01J23/68 ,  B01J32/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J37/04 ,  C07B61/00 ,  C07C67/04 ,  C07C67/055 ,  C07C69/15 ,  C07C67/05

Abstract: A process for the preparation of a fluid bed vinyl acetate (VAM) catalyst comprising impregnating a support comprising a mixture of substantially inert microspheroidal particles with a solution comprising a halide-free metal salt of Pd and M, wherein M comprises Ba, Au, La, Nb, Ce, Zn, Pb, Ca, Sr, Sb or mixtures thereof, reducing the metal salts to form a deposit of Pd and M on the support surface and impregnating the support with at least one halide-free alkali metal salt. At least 50% of the particles used for the microspheroidal support have a particle size below 100 microns, preferably below 60 microns. The pore volume of these particles is from 0.2 to 0.7cm /g and the surface area is from 100 to 200 m /g.

公开(公告)号：ES2095406T3

公开(公告)日：1997-02-16

申请号：ES92305436

申请日：1992-06-12

Applicant: STANDARD OIL CO OHIO

Inventor： PAPARIZOS CHRISTOS ,  SHAW WILFRID GARSIDE

IPC: B01J23/88 ,  B01J23/887 ,  B01J27/192 ,  B01J27/199 ,  C07C253/24 ,  C07C253/26 ,  C07C255/08

公开(公告)号：DE69216390D1

公开(公告)日：1997-02-13

申请号：DE69216390

申请日：1992-06-12

Applicant: STANDARD OIL CO OHIO

Inventor： PAPARIZOS CHRISTOS ,  SHAW WILFRID GARSIDE

IPC: B01J23/88 ,  B01J23/887 ,  B01J27/192 ,  B01J27/199 ,  C07C253/24 ,  C07C253/26 ,  C07C255/08

公开(公告)号：ZA951443B

公开(公告)日：1996-08-21

申请号：ZA951443

申请日：1995-02-21

Applicant: STANDARD OIL CO OHIO

Inventor： BENKALOWYCZ NANCY CHRISTOFFERS ,  BLUM PATRICIA RAE ,  LEMANSKI MICHAEL FRANCIS ,  PEPERA MARC ANTHONY ,  CIRJAK LARRY MICHAEL ,  PAPARIZOS CHRISTOS ,  WAGNER DAVID RUDOLPH

IPC: B01J8/24 ,  B01J8/32 ,  B01J8/38 ,  B01J19/00 ,  C07C67/055 ,  C07C

Abstract: A fluid bed process for the manufacture of vinyl acetate from ethylene, acetic acid and oxygen comprising feeding a gaseous mixture comprising ethylene and acetic acid into a fluid bed reactor through a first inlet, introducing the oxygen into the reactor through a second inlet, co-joining the oxygen, ethylene and acetic acid in the reactor in contact with a fluid bed catalyst to produce vinyl acetate. The particle size diameter of the particulate catalyst material has a range of 60% of the particles being below 200 microns (0.1 mm) with no more than 40% of the particles being below 40 microns (0.04 mm).

公开(公告)号：ZA9501441B

公开(公告)日：1996-08-21

申请号：ZA9501441

申请日：1995-02-21

Applicant: STANDARD OIL CO OHIO

Inventor： BLUM PATRICIA RAE ,  LEMANSKI MICHAEL FRANCIS ,  PEPERA MARC ANTHONY ,  CIRJAK LARRY MICHAEL ,  PAPARIZOS CHRISTOS ,  SURESH DEVASIRVATHAM DHANARAH

IPC: B01J21/08 ,  B01J23/44 ,  B01J23/52 ,  B01J23/56 ,  B01J23/58 ,  B01J35/10 ,  B01J37/00 ,  C07C67/055 ,  B01J ,  C07C

CPC classification number: B01J37/0045 ,  B01J21/08 ,  B01J23/44 ,  B01J23/52 ,  B01J23/56 ,  B01J23/58 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  C07C67/055 ,  C07C69/01 ,  C07C69/15

公开(公告)号：FI950819A

公开(公告)日：1995-08-23

申请号：FI950819

申请日：1995-02-22

Applicant: STANDARD OIL CO OHIO

Inventor： BLUM PATRICIA RAE ,  CIRJAK LARRY MICHAEL ,  LEMANSKI MICHAEL FRANCIS ,  PAPARIZOS CHRISTOS ,  PEPERA MARC ANTHONY ,  SURESH DEVASIRVATHAM DHANARAH

IPC: B01J21/08 ,  B01J23/44 ,  B01J23/52 ,  B01J23/56 ,  B01J23/58 ,  B01J23/60 ,  B01J23/62 ,  B01J23/63 ,  B01J23/644 ,  B01J23/648 ,  B01J23/66 ,  B01J23/68 ,  B01J32/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J37/04 ,  C07B61/00 ,  C07C67/04 ,  C07C67/055 ,  C07C69/15 ,  B01J35/08

Abstract: A process for the preparation of a fluid bed vinyl acetate (VAM) catalyst comprising impregnating a support comprising a mixture of substantially inert microspheroidal particles with a solution comprising a halide-free metal salt of Pd and M, wherein M comprises Ba, Au, La, Nb, Ce, Zn, Pb, Ca, Sr, Sb or mixtures thereof, reducing the metal salts to form a deposit of Pd and M on the support surface and impregnating the support with at least one halide-free alkali metal salt. At least 50% of the particles used for the microspheroidal support have a particle size below 100 microns, preferably below 60 microns. The pore volume of these particles is from 0.2 to 0.7cm /g and the surface area is from 100 to 200 m /g.

公开(公告)号：ZA936480B

公开(公告)日：1994-03-25

申请号：ZA936480

申请日：1993-09-02

Applicant: STANDARD OIL CO OHIO

Inventor： SEELY MICHAEL J ,  FRIEDRICH MARIA S ,  PAPARIZOS CHRISTOS ,  SURESH DEV D

IPC: B01J20060101 ,  C07C20060101 ,  B01J ,  C07C

公开(公告)号：MX154145A

公开(公告)日：1987-05-26

申请号：MX18904881

申请日：1981-09-04

Applicant: STANDARD OIL CO OHIO

Inventor： RINZ JAMES EDWARD ,  SMAW WILFRID GARSIDE ,  PAPARIZOS CHRISTOS

IPC: C07C57/05 ,  C07C69/54

公开(公告)号：CA1212836A

公开(公告)日：1986-10-21

申请号：CA418942

申请日：1983-01-05

Applicant: STANDARD OIL CO OHIO

Inventor： VELENYI LOUIS J ,  PESA FREDERICK A ,  PAPARIZOS CHRISTOS

IPC: C01B3/26

Abstract: PRODUCTION OF SYNTHESIS GAS Gas mixtures containing at least hydrogen and carbon monoxide are prepared by reforming hydrocarbons in the presence of a catalyst impregnated on a specially prepared porous catalyst support. In one embodiment of the present invention, methane is reformed in a one-step process to produce a product gas mixture containing about equal portions of carbon monoxide and hydrogen in the presence of a Group VIII metal impregnated on a specially prepared porous catalytic support.