公开(公告)号：JPH01315701A

公开(公告)日：1989-12-20

申请号：JP412889

申请日：1989-01-11

Applicant: TORAY INDUSTRIES

Inventor： OSHIMA KATSUNORI ,  FUKUDA TADANORI ,  SAKAMOTO SADAYUKI

IPC: G02C7/04 ,  G02B1/04

Abstract: PURPOSE:To provide the base material for plastic lenses which has excellent rigidity and workability and is less colored by mixing a compd. having >=1.3 pieces, in molar average, of CH2=CX- groups in the molecule and a compd. having >=1.1 pieces, in molar average, of -SH groups into the base material at such a ratio at which the specific molar ratio is attained. CONSTITUTION:This base material contains the residual groups having >=1.3 pieces, in molar average, of the unit expressed by a (-CH2-CHX-) unit and (-CH2-CX-) (where X denotes hydrogen or methyl group) as the component of repeating units and the residual group having >=1.1 pieces, in molar average, of (-S-) bonded to the methylene group in the repeating unit component. The molar ratio of this two units has the relation shown by the following A, B: A:0.1

公开(公告)号：JPH01113415A

公开(公告)日：1989-05-02

申请号：JP27103287

申请日：1987-10-26

Applicant: TORAY INDUSTRIES

Inventor： SHIN MIKIO ,  FUKUDA TADANORI ,  OZAKI ITARU

IPC: C08F289/00

Abstract: PURPOSE:To provide the title composition excellent in weather resistance, stain resistance and abrasion resistance, which comprises a graft polymer obtained by polymerizing a (meth)acrylic fluoroalkyl ester, a functional (meth)acrylic alkyl ester and a specific macromonomer, and a curing agent. CONSTITUTION:The title curable composition comprises a graft polymer (A) obtained by polymerizing 3-90wt.% (meth)acrylic fluoroalkyl ester monomer (a), 5-30wt.% functional (meth)acrylic alkyl ester monomer (b) and 5-90wt.% macromonomer (c) having a radical-polymerizable double bond and a molecular weight of 800-10,000, and a curing agent (B) having a functional group reactive with the polymer (A) (e.g., hexamethylene diisocyanate). This composition is quite suitable as a coating agent having stain resistance and weather resistance for buildings, cars, railway vehicles, air planes, ships, electric articles, etc., or as a binder composition for magnetic recording media.

公开(公告)号：JPS63115106A

公开(公告)日：1988-05-19

申请号：JP26072086

申请日：1986-11-04

Applicant: TORAY INDUSTRIES

Inventor： MATSUNAGA TADAYOSHI ,  FUKUDA TADANORI ,  SHIN MIKIO

IPC: G02B6/00 ,  C08F20/22

Abstract: PURPOSE:To obtain optical transmission performance which is excellent in a visible to near IR region by using a polymer or copolymer as a core of a plastic optical fiber having core-cladding structure. CONSTITUTION:Deuterated pentafluorophenyl methacrylate, 0.1mol% azobis tert-butane and 0.1mol% n-butyl mercaptan are mixed in the substantial absence of dust and oxygen and are polymerized for 24hr at 130 deg.C in a hermetic system. After the unreacted monomers are removed under a reduced pressure, the copolymer is melt-extruded simultaneously with a cladding polymer by using a composite mouthpiece, by which the optical fiber is prepd. Spinning is executed at 220 deg.C and a copolymer of hexafluoropropyl methacrylate/MMA is used for the cladding material.

公开(公告)号：JPS636086B2

公开(公告)日：1988-02-08

申请号：JP4781282

申请日：1982-03-25

Applicant: TORAY INDUSTRIES

Inventor： FUKUDA TADANORI ,  SAKAMOTO SADAYUKI

IPC: G02B1/04 ,  C08G59/00 ,  C08G59/18 ,  C08G59/40 ,  C08G59/42 ,  C08G59/48

公开(公告)号：JPS6249289B2

公开(公告)日：1987-10-19

申请号：JP14695079

申请日：1979-11-13

Applicant: TORAY INDUSTRIES

Inventor： FUKUDA TADANORI ,  MORIMOTO HIROSHI

IPC: C08G18/00 ,  C08G18/73 ,  C09D175/00

公开(公告)号：JPS6281601A

公开(公告)日：1987-04-15

申请号：JP22196185

申请日：1985-10-07

Applicant: TORAY INDUSTRIES

Inventor： WADA SUSUMU ,  SAITO MASAMI ,  FUKUDA TADANORI

IPC: G02B1/04 ,  B29C39/02 ,  B29L11/00 ,  C08F18/16 ,  C08F18/24

Abstract: PURPOSE:To obtain a plastic lens having good transparency and color tones and a high refractive index by using a specific crosslinked structure formable org. compd. as an essential component, adding a dye having a complementary color relation with the lens color tone to said compd. and polymerizing the same. CONSTITUTION:The dye having the complementary color relation with the color tone of the high refractive index plastic lens having >=1.50 refractive index nd and essentially consisting of the crosslinked structure formable org. compd. is added to the compsn. for producing said lens and the compsn. is polymerized. A radically polymerizable multifunctional org. vinyl monomer contg. an arom. ring is effective as the compd. having such high refractive index and crosslinked structure characteristic and further such vinyl monomer is more preferable if said monomer contains halogen elements except fluorine. A disperse die is preferable as the dye to be added to the compsn. for the purpose of improving the color tone and is preferably used at about 0.01-100ppm. The color tone of the plastic lens having the particularly high refractive index is thereby improved and the resulted lens has the stable color tone effect even if the lens is left standing under heating or UV rays such as outdoor exposure.

公开(公告)号：JPS60217301A

公开(公告)日：1985-10-30

申请号：JP7262384

申请日：1984-04-13

Applicant: TORAY INDUSTRIES

Inventor： FUKUDA TADANORI ,  SAKAMOTO SADAYUKI ,  WADA SUSUMU

IPC: C08G18/00 ,  G02B1/04

Abstract: PURPOSE:To obtain a resin for plastic lens having high refractive index by polymerizing a specified amt, of a mixture consisting of two specified components having 0.5-2.0 molar ratio of NCO/OH with a specified amt. of a vinyl monomer having 1.55 refractive index. CONSTITUTION:20-100wt% mixture of an isocyanate compd. having >=2 functionality and molar ratio NCO/OH adjusted to 0.5-2.0 with a vinyl monomer having an OH group and expressed by the formula (wherein R is methyl or H), or an addition reaction product thereof is mixed with 0-80wt% vinyl monomer having >=1.55 refractive index of its polymer, and a reaction between the isocyanate group and an OH group is proceeded to completion by the addition of an addition reaction catalyst. Then, the reaction product is poured together with a polymerization initiator into a mold, polymerized by heating to obtain a plastic lens having high refractive index.

公开(公告)号：JPS60174767A

公开(公告)日：1985-09-09

申请号：JP3111284

申请日：1984-02-21

Applicant: TORAY INDUSTRIES

Inventor： YAMAMOTO KEIICHIROU ,  FUKUDA TADANORI

IPC: C07D211/46 ,  C07D211/48 ,  C07D211/52 ,  C07D211/58 ,  C08G18/00 ,  C08G18/78 ,  C08G18/79 ,  C09D175/14

Abstract: NEW MATERIAL:A reaction product of a trifunctional isocyanate compound shown by the formula I (R is 2-3C bifunction hydrocarbon residue) and a hindered amine compound shown by the formula II(R is H, benzyl or benzyl replaced with halogen, etc.; R is H, lower alkyl, phenyl, halogen, benzyl, etc.; Y is OH, amino, monoalkyl, amino, etc.). EXAMPLE:A reaction product of 2,6-diisocyanate caproic acid beta-isocyanate ethyl ester and 1,2,2,6,6-pentamethyl-4-hydroxypiperidine. USE:A monomer for synthesizing polyurethane. Delicately yellow low-viscosity liquid. Sufficient attention is required in its reaction with water in air. Providing a flexible and tough polyurethane having improved heat resistance, solvent resistance to change in color, durability, etc. PREPARATION:A compound shown by the formula I is reacted with a compound shown by the formula II to give a novel substance efficiently.

公开(公告)号：JPS6051706A

公开(公告)日：1985-03-23

申请号：JP15810983

申请日：1983-08-31

Applicant: TORAY INDUSTRIES

Inventor： FUKUDA TADANORI ,  SAKAMOTO SADAYUKI

IPC: C08F299/00 ,  C08F20/26 ,  C08F20/36 ,  C08F290/00 ,  C08F299/06 ,  G02B1/04

Abstract: PURPOSE:A resin for tough plastic lenses having a refractive index >=1.55, comprising a polymer obtained by the vinyl polymerization of a specified urethanized (meth)acryl monomer. CONSTITUTION:A urethanized (meth)acryl monomer is synthesized by reacting the OH groups of a (meth)acryl monomer of the formula (wherein R1 and R2 are each H or methyl, m+n=0-4, and X is Cl, I, or Br) with the NCO groups of a polyisocyanate. This monomer is vinyl-polymerized to obtain the purpose resin. Although the above monomer can be vinyl-polymerized alone to obtain a resin for high-refractive index lenses, the urethanized (meth)acrylic monomer (a first vinyl monomer) may be copolymerized with another vinyl monomer having an aromatic ring in the molecule (a second vinyl monomer).

公开(公告)号：JPS58145724A

公开(公告)日：1983-08-30

申请号：JP2815382

申请日：1982-02-25

Applicant: TORAY INDUSTRIES

Inventor： FUKUDA TADANORI ,  SAKAMOTO SADAYUKI ,  YAMAMOTO KEIICHIROU

IPC: C08F8/00 ,  C08G59/00 ,  C08G59/42 ,  C08L7/00 ,  C08L21/00 ,  C08L63/00

Abstract: PURPOSE:An epoxy resin elastomer excellent in flexibility, electrical properties, water resistance, etc., and suitable as an electrical-insulating material or the like, containing an epoxy resin prepared by reacting a liquid polybutadiene with an epoxy compound and an acid anhydride as a resin component. CONSTITUTION:40-80wt% liquid polybutadiene and (or) its derivative (e.g., polybutadiene glycol, polybutadienedicarboxylic acid) are reacted with 10-40wt% epoxy compound containing at least two oxirane rings in the molecule (e.g., vinylcyclohexene dioxide, neopentyl glycol diglycidyl ether) and 10-40wt% acid anhydride (e.g., phthalic anhydride, maleic anhydride). Then, the purpose epoxy resin elastomer is prepared by mixing the produced epoxy resin as a resin component with, if necessary, a filler, a flame retardant, a colorant, etc.