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公开(公告)号：KR1020020061434A
公开(公告)日：2002-07-24
申请号：KR1020010002734
申请日：2001-01-17
Applicant: 한국화학연구원
IPC: B01J23/755 , B01J21/04 , B01J21/06
CPC classification number: B01J23/755 , B01J23/83 , B01J23/835 , B01J37/0201 , B01J37/0205 , B01J37/035 , C07C5/05
Abstract: PURPOSE: The modified nickel-alumina catalyst for selective hydrogenation of diolefins of the present invention is manufactured by surface modifying gamma-alumina support with one element selected from zirconium, lanthanum and tin, and then it is further supported by nickel. CONSTITUTION: In a modified nickel-alumina catalyst for selective hydrogenation of diolefins that is manufactured by surface modifying gamma-alumina support with one element selected from zirconium, lanthanum and tin, and then it is further supported by nickel, the present invention is characterized in that gamma-alumina support is supported by one element selected from zirconium, lanthanum and tin in an amount of 0.2 to 10 wt.% and nickel in an amount of 0.5 to 10 wt.%, based on the weight of the gamma-alumina support. Before the modified nickel-alumina catalyst is used to convert diolefins to corresponding mono olefins through selective hydrogenation reaction, the modified nickel-alumina catalyst should undergo reduction stage at 400-500deg.C and pretreatment at 300-450deg.C in H2S gas atmosphere.
Abstract translation: 目的：本发明二烯烃选择性氢化的改性镍 - 氧化铝催化剂是通过用选自锆，镧和锡的一种元素表面改性γ-氧化铝载体，然后进一步由镍负载制备的。 构成：在通过用选自锆，镧和锡的一种元素表面改性γ-氧化铝载体制备的二烯烃选择性氢化的改性镍 - 氧化铝催化剂中，然后进一步由镍负载，本发明的特征在于 该γ-氧化铝载体由选自锆，镧和锡的一种元素以0.2至10重量％的量负载，镍的量为0.5至10重量％，基于γ-氧化铝载体的重量 。 在通过选择性氢化反应将改性镍 - 氧化铝催化剂用于将二烯烃转化为相应的单烯烃之前，改性镍 - 氧化铝催化剂应在400-500℃下进行还原阶段，并在H 2 S气体气氛中在300-450℃下进行预处理。
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公开(公告)号：KR1020020060002A
公开(公告)日：2002-07-16
申请号：KR1020010001198
申请日：2001-01-09
Applicant: 한국화학연구원 , 주식회사 불이화이버
CPC classification number: B01J27/053 , B01J29/126 , B01J29/146 , B01J29/48
Abstract: PURPOSE: Provided is a multifunctional oxidation catalysts, which can remove chlorinated volatile organic compounds at low temperatures of 20 to 220°C as well as minimize generation of another forms of chlorinated volatile organic compounds after reaction. CONSTITUTION: The present invention is characterized in that sulfated metal oxide support is impregnated with (i) as active species, 0.5-2.0 wt.% of one novel metal selected from Pt, Pd, Ir and Rh; (ii) as subsidiary active species, Cu 2.0-10.0 wt.%, Ni 0.1-1.0 wt.%. The sulfated metal oxide support is selected from zirconia, titania and ceria containing SO4 in an amount of 0.3 to 2.3 wt.%. And a porous molecular sieve material is used as support, together with the sulfated metal oxide support within the range of less than 50%. The porous molecular sieve material, such as protonic zeolite or ammonium zeolite, is selected from BEA, MFI, MOR and FAU zeolite with a Si/Al ratio within the range of 10 to 100.
Abstract translation: 目的：提供一种多功能氧化催化剂，可在20〜220℃的低温下除去氯化挥发性有机化合物，并使反应后产生其他形式的氯化挥发性有机化合物最小化。 构成：本发明的特征在于硫酸化金属氧化物载体浸渍有（i）作为活性物质，选自Pt，Pd，Ir和Rh的一种新型金属为0.5-2.0重量％ （ii）作为辅助活性物质，Cu 2.0-10.0重量％，Ni 0.1-1.0重量％。 硫酸化金属氧化物载体选自氧化锆，二氧化钛和含有SO 3的二氧化铈，其量为0.3至2.3重量％。 使用多孔分子筛材料作为载体，硫酸化金属氧化物载体在小于50％的范围内。 多孔分子筛材料，例如质子沸石或铵沸石，选自BEA，MFI，MOR和FAU沸石，Si / Al比在10至100的范围内。
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公开(公告)号：KR100336967B1
公开(公告)日：2002-05-17
申请号：KR1019990045621
申请日：1999-10-20
Applicant: 한국화학연구원
IPC: B01J23/44
Abstract: 본발명은휘발성유기화합물제거용하니컴형일체식촉매의제조방법에관한것으로서, 더욱상세하게는팔라듐이온(Pd)과전이금속이온을함유한금속염을제올라이트와같은다공성담체에담지시켜서만들어진촉매분말을소정의바인더와배합하여슬러리형태로제조한후, 이를하니컴형담체표면에습윤코팅하여제조한것으로화학산업의생산과정에서발생하는배가스중의휘발성유기화합물을저온완전연소시켜제거하는데유용한하니컴형일체식촉매의제조방법에관한것이다.
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公开(公告)号：KR100336963B1
公开(公告)日：2002-05-17
申请号：KR1020010003268
申请日：2001-01-19
Applicant: 한국화학연구원
Abstract: 본발명은휘발성유기화합물제거용하니컴형일체식촉매에관한것으로서, 더욱상세하게는팔라듐이온(Pd)과전이금속이온을함유한금속염을제올라이트와같은다공성담체에담지시켜서만들어진촉매분말을소정의바인더와배합하여슬러리형태로제조한후, 이를하니컴형담체표면에습윤코팅하여제조한것으로화학산업의생산과정에서발생하는배가스중의휘발성유기화합물을저온완전연소시켜제거하는데유용한하니컴형일체식촉매에관한것이다.
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公开(公告)号：KR1020000001930A
公开(公告)日：2000-01-15
申请号：KR1019980022415
申请日：1998-06-15
Applicant: 한국화학연구원
Abstract: PURPOSE: Title compounds are directly prepared by hydrogen and oxygen, not using perhydroxide in the presence of binary catalyst. CONSTITUTION: Title compounds are prepared by hydrogen and oxygen at -10- 60°C, atmospheric pressure in the presence of binary catalyst comprising zeolite catalyst including VIII-B transition metals and alkyl anthraquinone derivatives and zeolite catalyst containing the transition metal having tetrahedron coordinated structures. Thus, 15 ml benzene and 15 ml acetic acid are mixed in the velocity of 16 ml/min of hydrogen and oxygen at 60°C for 5 hours to give a phenol.
Abstract translation: 目的：标题化合物直接由氢和氧制备，在二元催化剂存在下不使用全氢氧化物。 构成：标题化合物是在氢气和氧气的制备下，在-10〜60℃，大气压下，在二元催化剂存在下，包含沸石催化剂，包括VIII-B过渡金属和烷基蒽醌衍生物，以及含有具有四面体配位结构的过渡金属的沸石催化剂 。 因此，将15ml苯和15ml乙酸以16ml / min的氢气和氧气的速度在60℃下混合5小时，得到苯酚。
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Patent Agency Ranking
公开(公告)号：KR1019970014833A
公开(公告)日：1997-04-28
申请号：KR1019950028862
申请日：1995-09-05
Applicant: 한국화학연구원
IPC: B01J23/58
CPC classification number: B01J23/002 , B01J2523/00 , Y10S502/525 , B01J2523/3706 , B01J2523/845 , B01J2523/847 , B01J2523/17 , B01J2523/3712
Abstract: 본 발명은 성분금속염에 유기산과 디히드록시 알콜 화합물을 첨가하여 얻어진 금속착염용액에 고표면적을 갖는 알루미늄 및 실리콘 함유 담체를 첨가하여 상온에서 액상으로 혼합하고 이를 70~150℃에서 감압증류 및 극초단파를 이용, 건조하여 겔화시킨 후에 300~700℃의 소성온도에서 열처리하여 혼합 금속산화물이 무정형으로 또 고표면적으로 담체에 균일하게 분산되어 있는 하기 식(Ⅰ)으로 표시되는 질소 산화물 제거 및 탄화수소 연소화반응에 촉매활성이 있는 혼합 금속산화물 담지촉매의 제조방법 :
(A
a O
x ·B
b O
y )·(C
c O
z ·C'
c' O
Z' )/S (Ⅰ)
상기 식에서, A와 B는 란탄계열 금속 또는 알칼리금속 또는 알카리토금속이고, C와 C
' 는 제1주기 전이금속 또는 귀금속이고, a, b, c 및 c
' 는 양론적으로 0 내지 1의 값을 가지며, a+b=1, c+c
' =1이고 또〔a+b〕대 〔c+c
' 〕의 비율은 0.1~3.0:1.0의 범위이고, S는 제올라이트, 알루미나, 실리카, 알루미나-실리카 등의 알루미늄 및/또는 실리콘 함유 담체에 관한 것이다.-
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公开(公告)号：KR1019960009892B1
公开(公告)日：1996-07-24
申请号：KR1019930016885
申请日：1993-08-25
Applicant: 한국화학연구원
IPC: C10J1/00
CPC classification number: B01J23/78 , C01B3/40 , C01B2203/1052 , Y02P20/52
Abstract: Synthetic gas is prepared by continuously reacting carbon dioxide with low grade hydrocarbon or natural gas containing methane and oxygen or steam in a mole ratio of 2:1-5:1 in the presence of a catalyst that comprises nickel, alkali and alkali earth metals supported on silicone such as zeolite, silica, silicate or silica-alumina at 600-1,000deg.C and 0.5-20 atms and a space velocity of 1,000-500,000. The ratio of carbon monoxide to hydrogen in the synthetic gas is 1:2-2:1.
Abstract translation: 在催化剂存在下，使二氧化碳与含有甲烷和氧气或蒸汽的摩尔比为2：1-5：1的低级烃或天然气连续反应制备合成气体，所述催化剂包含负载的镍，碱和碱土金属 在600-1000℃，0.5-20atms，空间速度为1000-500,000的硅氧烷如沸石，二氧化硅，硅酸盐或二氧化硅 - 氧化铝上。 合成气中一氧化碳与氢的比例为1:2.2:1。
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公开(公告)号：KR102211656B1
公开(公告)日：2021-02-04
申请号：KR1020180031678
申请日：2018-03-19
Applicant: 보드 오브 리전츠, 더 유니버시티 오브 텍사스 시스템 , 한국화학연구원
Abstract: 본발명은 2가금속이온과피리딘계카르복시산리간드로부터얻어진유무기하이브리드나노세공체를포함하는흡착제및 이의용도에관한것으로, 더욱상세하게는 2가금속이온과피리딘계카르복시산리간드로부터얻어짐으로인해저온에서탈착재생이가능하고, 낮은상대습도하에서도수분또는알코올에대해유무기하이브리드나노세공체 1 그램또는 1 밀리리터당 0.15 그램이상, 0.3 그램에가까운높은흡착량을보유하고, 특히저온에서탈착재생이가능하고, 낮은상대습도하에서도높은흡착량을갖는수분및/또는알코올흡착제를제공할수 있다.
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公开(公告)号：KR101926169B1
公开(公告)日：2018-12-07
申请号：KR1020170035968
申请日：2017-03-22
Applicant: 한국화학연구원
IPC: C08B5/14 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1041 , H01M8/1004 , C08L1/16 , H01M8/1018
Abstract: 본 발명은 술폰화 셀룰로오스, 이를 이용한 수소이온 전도성 고분자 전해질 막 및 이를 구비하는 연료전지에 관한 것으로, 더욱 구체적으로는 기계적 특성과 화학적 안정성이 우수한 셀룰로오스 백본에 화학적 기능화를 통해 술폰기를 말단에 도입함으로서 상용 고분자 전해질 막에 비해 향상된 이온전도도를 가지는 술폰화 셀룰로오스, 이를 이용한 수소이온 전도성 고분자 전해질 막 및 이를 포함하는 연료전지에 관한 것이다.
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