83.
    发明专利
    未知

    公开(公告)号:AT506344T

    公开(公告)日:2011-05-15

    申请号:AT06754975

    申请日:2006-05-03

    Applicant: BASF SE

    Abstract: The invention relates to a process for isolating methylglycinenitrile-N,N-diacetonitrile (MGDN) from an aqueous emulsion which comprises MGDN and has an MGDN content of 3-50% by weight in a crystallizer, comprising the steps: (a) the aqueous emulsion is, starting from a temperature above the solidification point, cooled to a temperature below the solidification point, the cooling rate averaged over time not exceeding 5 K/h, until substantially the entirety of the emulsified MGDN has solidified, (b) the resulting aqueous suspension is cooled further and/or concentrated, and the cooling rate may be greater than in step (a).

    NEUTRALIZACION MEJORADA DE PRODUCTOS DE SINTESIS DE ISOFORON-NITRILO.

    公开(公告)号:ES2312835T3

    公开(公告)日:2009-03-01

    申请号:ES03782412

    申请日:2003-12-16

    Applicant: BASF SE

    Abstract: Procedimiento para la producción de 3-ciano-3,5,5-trimetilciclohexanona (isoforon-nitrilo) mediante la reacción de isoforona con cianuro de hidrógeno en presencia de una base como catalizador, seleccionada de cianuros alcalinos y alcalinotérreos, hidróxidos alcalinos y alcalinotérreos, óxidos alcalinos y alcalinotérreos y alcoholatos alcalinos y alcalinotérreos, obteniéndose un producto bruto de isoforon-nitrilo, y posterior destilación del producto bruto de isoforon-nitrilo, caracterizado porque antes de la destilación se añade al menos un ácido sulfónico seleccionado del grupo que consiste en ácido metanosulfónico, ácidos naftalenosulfónicos, ácidos naftalenosulfónicos alquilsustituidos y ácidos bencenosulfónicos alquilsustituidos con un resto alquilo con >_ 4 átomos de carbono.

    88.
    发明专利
    未知

    公开(公告)号:DE50310589D1

    公开(公告)日:2008-11-13

    申请号:DE50310589

    申请日:2003-12-16

    Applicant: BASF SE

    Abstract: The present invention relates to a process for preparing 3-cyano-3,5,5-trimethylcyclohexanone (isophoronenitrile) by reacting isophorone with hydrogen cyanide in the presence of a base as a catalyst to obtain a crude isophoronenitrile product, and subsequently distilling the crude isophoronenitrile product, with the addition before distillation of at least one specific sulfonic acid or specific carboxylic acid. In addition, the present invention relates to the use of a specific sulfonic acid or of a specific carboxylic acid as a neutralizing agent before distillation of a crude isophoronenitrile product which has been obtained by reacting isophorone with hydrogen cyanide in the presence of a base as a catalyst, in order to avoid precipitates in the neutralization of the base used as a catalyst with an acid.

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