Abstract:
PURPOSE: A cleaning solution for quartz parts is provided to effectively remove an impurity thin film and particle remaining on the surface of quartz parts applied to a semiconductor manufacturing apparatus without excessive damage to the quartz parts. CONSTITUTION: A cleaning solution for removing thin film and particle remaining on the surface of quartz parts applied to a semiconductor manufacturing apparatus comprises an ammonium compound 5-20 weight%, acidic oxidizer 10-55 weight%, fluorine compound 5-30 weight% and extra water. A method for cleaning the quartz parts comprises the steps of: (S120) providing the cleaning solution for quartz parts to the quartz parts with remaining impurity thin film; and (S130) removing the impurity thin film by a cleaning process.
Abstract:
A cleaning solution for removing a polymer, and a method for removing a polymer by using the cleaning solution are provided to remove the polymer adsorbed on a semiconductor manufacturing apparatus without the damage of parts. A cleaning solution for removing a polymer comprises 5-10 wt% of a fluorinated salt; 5-15 wt% of an acid or its salt; and 75-90 wt% of a glycol aqueous solution. Preferably the glycol is represented by OH-R-OH, wherein R is a C2-C5 alkyl group; the acid is sulfuric acid, hydrofluoric acid or nitric acid; the salt is ammonium nitrate, ammonium sulfate or ammonium hydrofluorate; and the fluorinated salt comprises at least one selected from the group consisting of ammonium fluoride, ammonium tetramethyl fluoride, ammonium tetraethyl fluoride, ammonium tetrapropyl fluoride and ammonium tetrabutyl fluoride.
Abstract:
노볼락계 포토레지스트를 선택적으로 제거할 수 있는 포토레지스트 제거용 조성물, 이를 이용한 포토레지스트 제거 방법 및 반도체 장치 제조 방법에서, 상기 포토레지스트 제거용 조성물은 케톤 화합물, 에테르 화합물 및 에스테르 화합물 중하나를 포함하는 제1 극성 비양자성 용매, 및 황을 함유하는 화합물 및 질소를 함유하는 화합물 중 하나를 포함하는 제2 극성 비양자성 용매를 포함한다. 또한, 상기 포토레지스트 제거용 조성물은 제1 극성 비양자성 용매 및 케톤 화합물로 이루어지거나, 제2 극성 비양자성 용매 및 케톤화합물로 이루어지거나, 또는 제1 극성 비양자성 용매 및 제2 극성 비양자성 용매로 이루어질 수도 있다. 씨모스 이미지 센서의 제조 공정에서, 씨모스 이미지 센서에 포함된 구조물의 손상을 최소화하면서 노볼락계 포토레지스트를 선택적으로 제거할 수 있다.
Abstract:
Composition for removing photoresist and its etching residue is provided to effectively remove photoresist and microfine residue after etching the photoresist, and considerably reduce damage of metal wire exposed during photoresist removal by comprising alcohol amide compound, polar non-protonic solvent and general additive. The composition comprises: 5-20wt.% of alcohol amide compound represented by a formula, wherein R1 is hydroxy or hydroxy alkyl group and R2 is hydrogen or hydroxyl alkyl group; 15-60wt.% of polar non-protonic solvent; 0.1-6wt.% of additive; and the balance of water. Alternatively, the composition includes; 5-20wt.% of alcohol amide compound; 15-60wt.% of polar non-protonic solvent; 1-30wt.% of hydroxyl amine or alkanol amine; 0.1-6wt.% of additive; and the balance of water. The composition is used in manufacturing semiconductor device by forming photoresist pattern on a substrate, and adding the prepared photoresist composition to the substrate so as to remove the photoresist pattern.
Abstract:
노볼락계 포토레지스트를 선택적으로 제거할 수 있는 포토레지스트 제거용 조성물, 이를 이용한 포토레지스트 제거 방법 및 반도체 장치 제조 방법에서, 상기 포토레지스트 제거용 조성물은 케톤 화합물, 에테르 화합물 및 에스테르 화합물 중하나를 포함하는 제1 극성 비양자성 용매, 및 황을 함유하는 화합물 및 질소를 함유하는 화합물 중 하나를 포함하는 제2 극성 비양자성 용매를 포함한다. 또한, 상기 포토레지스트 제거용 조성물은 제1 극성 비양자성 용매 및 케톤 화합물로 이루어지거나, 제2 극성 비양자성 용매 및 케톤화합물로 이루어지거나, 또는 제1 극성 비양자성 용매 및 제2 극성 비양자성 용매로 이루어질 수도 있다. 씨모스 이미지 센서의 제조 공정에서, 씨모스 이미지 센서에 포함된 구조물의 손상을 최소화하면서 노볼락계 포토레지스트를 선택적으로 제거할 수 있다.
Abstract:
According to a method for detecting the inhomogeneity of a film, at least two sections of a film are irradiated with light at a first incident angle. First lights reflected from the two sections are detected. The at least two sections of the film are irradiated with light at a second incident angle. Second lights reflected from the two sections are detected. The inhomogeneity of the film is obtained by comparing the first and second reflection lights. Thus, the present invention can compare the reflectances of the lights totally reflected from foreign materials in the film among the lights reflected from the film with each other by irradiating the lights to the at least two sections of the film at the two or more incident angles; thereby accurately detecting the inhomogeneity of the film. Also, the present invention can prevent pattern defects since it can detect the film having defect factors, such as the foreign materials, beforehand.
Abstract:
A method of monitoring the contamination level of metals in a chemical cleaning bath is provided to measure the contamination levels of aluminum and tungsten in a chemical cleaning solution in a chemical cleaning bath for a cleaning process of a semiconductor substrate. In a method of monitoring the contamination level of metals in a chemical cleaning bath, after making chelate compound into chelating aqueous solution, acid or base is added into the chelating aqueous solution to firstly adjust pH(S110). Most of metal ions can be contaminant in actual semiconductor process. As a result, property of semiconductors can be fatally affected by the contaminant. Chelate compound is further mixed with positive ion surfactant. The positive ion surfactant contains alkyl ammonium halide. The positive ion surfactant can be added to reduce low limit detection of ultraviolet ray-visible ray spectrophotometer. The chelate compound has a content of 0.0001 weight % to 1.5 weight % of the chelating aqueous solution. The chelating aqueous solution is mixed with chemical cleaning solution at a predetermined ratio to secondly adjust pH(S120).
Abstract:
PURPOSE: A plating method using a photo-resist residue analysis method for a plating solution is provided to determine the use of plating solution by analyzing the content of photo-resist residue in a plating solution. CONSTITUTION: A plating method using a photo-resist residue analysis method for a plating solution is as follows. The plating solution(15) is provided to a plating bath(10). A first wafer(51) having lower metal wires and photo-resist pattern is dipped in the plating bath. The plating processes are composed of first and second steps. An analyzing step analyzing photo-resist residue is performed between the two steps.
Abstract:
A semiconductor wet etchant is provided to remove an insulating layer and a metal layer positioned in the peripheral area of a semiconductor substrate while covering an insulating layer and a metal layer positioned in the central area of a semiconductor substrate with a protective film. A semiconductor wet etchant is manufactured by mixing ionized water, fluorine compound 0.25~10.0 wt%, oxidizer 0.45~3.6 wt% and inorganic salt 1.0~5.0 wt%. The inorganic salt comprises at least one of ammonium ion (NH4+) and chlorine ion (Cl-). The fluorine compound comprises at least one selected from hydrofluoric acid (HF), ammonium fluoride (NH4F), ammonium fluoride (NH4HF2), tetramethyl amonium (TMAF: (CH3)4NF) and tetrabutylammonium fluoride (TBMA: (CH3CH2CH2CH2)4NF). The oxidizer comprises at least one selected from hydrogen peroxide (H2O2), nitric acid (HNO3), sulfuric acid (H2SO4), ammonium nitrate (NH4NO3), ammonium iodate (NH4IO3) and ammonium die sulfite ((NH4) 2S2O5).
Abstract translation:提供了一种半导体湿式蚀刻剂,用于除去位于半导体衬底的周边区域中的绝缘层和金属层,同时用保护膜覆盖位于半导体衬底的中心区域中的绝缘层和金属层。 通过混合电离水,0.25〜10.0重量%的氟化合物,0.45〜3.6重量%的氧化剂和1.0〜5.0重量%的无机盐,制造半导体湿蚀刻剂。 无机盐包括铵离子(NH 4 +)和氯离子(Cl - )中的至少一种。 氟化合物包括选自氢氟酸(HF),氟化铵(NH 4 F),氟化铵(NH 4 HF 2),四甲基铵(TMAF:(CH 3)4 NF)和四丁基氟化铵(TBMA:(CH 3 CH 2 CH 2 CH 2)4 NF)中的至少一种。 氧化剂包括选自过氧化氢(H 2 O 2),硝酸(HNO 3),硫酸(H 2 SO 4),硝酸铵(NH 4 NO 3),碘酸铵(NH 4 O 3)和铵亚硫酸铵((NH 4)2 SO 5)的至少一种。