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公开(公告)号：KR100524703B1
公开(公告)日：2005-10-31
申请号：KR1020030084761
申请日：2003-11-27
Applicant: 한국화학연구원
IPC: C09B31/043
Abstract: 본 발명은 섬유날염용 아조 적색 안료와 이의 제조방법에 관한 것으로서, 더욱 상세하게는 아미노-
N -치환된벤즈아미드 유도체를 디아조체로 사용하고 2-하이드록시-3-나프토일 아닐린 유도체를 커플러로 사용하여 상기 두 화합물을 커플링 반응하여 제조하는 다음 화학식 1로 표시되는 섬유날염용 신규 아조 적색 안료와 이의 제조방법에 관한 것이다.
상기 화학식 1에서, A는 C
1 ∼C
4 의 직쇄 또는 측쇄 알킬렌기를 나타내고; R
1 은 수소원자 또는 C
1 ∼C
4 의 알콕시기를 나타내고; R
2 는 수소원자, 염소원자, C
1 ∼C
4 의 알킬기, C
1 ∼C
4 의 알콕시기, 니트로기, 또는 아릴아미드기를 나타낸다.-
公开(公告)号：KR1020020031449A
公开(公告)日：2002-05-02
申请号：KR1020000061922
申请日：2000-10-20
Applicant: 한국화학연구원
IPC: C09B46/00
Abstract: PURPOSE: Provided are benzimidazolone-based yellow pigments which are excellent in solvent resistance and colorfastness to light and provides a high yield, and a method for preparing the same. CONSTITUTION: The benzimidazolone-based yellow pigments represented by formula 1 are characterized in that it is prepared by using amino benzimidazolone represented by formula 9, as a diazotized compound. In the formulas, R, R1 and R2 which are the same or different, are hydrogen, C1-C4 alkyl group, nitro(-NO2) group, C1-C2 alkoxy group, C1-C18 heterocycle, methyl ester(COOCH3) or halogen group such as chloro or bromo. The yellow pigments are prepared by the steps of (i) diazotizing amino benzimidazolone compound represented by formula 9; (ii) dissolving a coupler represented by formula 11 into a solvent; (iii) mixing two solutions obtained from the steps (i) and (ii) at 0-5 deg.C; and (iv) adding base to the solution mixed in the step(iii) to adjust pH to 6-7 with stirring. In the formula 11, R, R1 and R2 are the same as the above.
Abstract translation: 目的：提供耐溶剂性和耐光色牢度并且提供高产率的苯并咪唑酮基黄色颜料及其制备方法。 构成：由式1表示的基于苯并咪唑酮的黄色颜料的特征在于其通过使用由式9表示的氨基苯并咪唑酮作为重氮化化合物制备。 在式中，R 1，R 2和R 2相同或不同，是氢，C 1 -C 4烷基，硝基（-NO 2）基，C 1 -C 2烷氧基，C 1 -C 18杂环，甲酯（COOCH 3）或卤素 例如氯或溴。 黄色颜料通过以下步骤制备：（i）重氮化由式9表示的氨基苯并咪唑酮化合物; （ii）将由式11表示的成色剂溶解在溶剂中; （iii）在0-5℃下将从步骤（i）和（ii）获得的两种溶液混合; 和（iv）向步骤（iii）中混合的溶液中加入碱以在搅拌下将pH调节至6-7。 在式11中，R，R 1和R 2与上述相同。
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公开(公告)号：KR1020040066428A
公开(公告)日：2004-07-27
申请号：KR1020030003489
申请日：2003-01-18
Applicant: 한국화학연구원
IPC: C09B62/453
CPC classification number: C09B62/513
Abstract: PURPOSE: A reactive blue dye is provided to improve the color yield, reactivity, fixation ratio, light fastness and wash fastness by introducing 4-aminophenyl vinylsulfone group and lower the water solubility of the dye so as to produce the dye with high purity and lower the dye concentration in wastewater by introducing 4-acetaminophenyl group. CONSTITUTION: The reactive blue dye represented by a general formula 1 comprises both 4-aminophenyl vinylsulfone group and 4-acetaminophenyl group. In the formula 1, M is hydrogen or alkali metal. The reactive blue dye is prepared by: (a) carrying out diazotization of 4-aminophenyl-vinylsulfone and coupling with 1-naphtol-8-amino-3,6-disulfonic acid, and (b) carrying out diazotization of 4-amino acetanilide and adding it to the solution from (a) for further coupling.
Abstract translation: 目的：提供反应性蓝色染料，通过引入4-氨基苯基乙烯基砜基来降低色素的产率，反应性，固色比，耐光牢度和耐洗牢度，降低染料的水溶性，从而生产高纯度和低分子量的染料 通过引入4-乙酰氨基苯基的废水中的染料浓度。 构成：由通式1表示的活性蓝色染料包括4-氨基苯基乙烯基砜基团和4-乙酰氨基苯基。 在式1中，M是氢或碱金属。 反应性蓝色染料的制备方法为：（a）进行4-氨基苯乙烯砜的重氮化，并与1-萘酚-8-氨基-3,6-二磺酸偶联，（b）进行4-氨基乙酰苯胺的重氮化 并将其加入到（a）用于进一步偶联的溶液中。
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公开(公告)号：KR1020000036264A
公开(公告)日：2000-07-05
申请号：KR1019990001697
申请日：1999-01-20
Applicant: 한국화학연구원 , 주식회사 모리아 켐텍
IPC: D06P3/32
Abstract: PURPOSE: A transfer printing method of leather is provided that can enhances a photoresistance and a friction resistance, represents an elaborate pattern and particularly improves a cleaning resistance and dry cleaning property. CONSTITUTION: A transfer printing method of leather comprises the steps of using glutaraldehyde in a pretanning as a tanning assistant before chrome-tanning of raw leather; modifying a surface of tanned leather by coating the tanned leather with a composition comprising 45 to 55 parts of weight of water-dispersible polyester resin(10%), 10 to 20 parts of weight of acrylic resin, 3 to 8 parts of weight of polyurethane resin, 2 to 3 parts of weight of wax, 1 to 2 parts of weight of alcoholic permeating agent and 20 to 30 parts of weight of water; and printing a separately prepared transfer raw paper with a roller gravure printer.
Abstract translation: 目的：提供能够提高光致抗蚀剂和耐摩擦性的皮革的转印方式，代表精细的图案，特别是提高了清洁性和干洗性。 构成：皮革的转印方法包括以下步骤：在预鞣制前将戊二醛用作鞣制助剂，然后进行鞣制前的皮革; 通过涂覆鞣制皮革来改变鞣制皮革的表面，该组合物包含45至55重量份的水分散性聚酯树脂（10％），10至20重量份丙烯酸树脂，3至8重量份聚氨酯 树脂，2〜3重量份的蜡，1〜2重量份的醇渗透剂和20〜30重量份的水; 并用辊式凹版印刷机印刷单独制备的转印原纸。
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公开(公告)号：KR1019960007524A
公开(公告)日：1996-03-22
申请号：KR1019940019891
申请日：1994-08-12
Applicant: 한국화학연구원
IPC: C07C49/423
Abstract: 안트라퀴논을 유기용매 중에서 수소화 반응시켜 안트론을 제조하고 이를 글리세린과 축합반응시켜 벤즈안트론을 제조하는 방법에 있어서, 수소화 반응시 팔라듐-탄소와 산촉매를 사용하고 유기용매로서 안트라퀴논에 대하여 9-15 중량배의 클로로벤젠을 사용하고 안트론과 글리세린의 축합반응시 105∼130℃에서 황산을 사용하게 되면 전체 반응공정이 간편하고 안전하며 반응조절이 용이할 뿐아니라 반응후 폐기물의 양을 극소화 할 수 있어 환경오염의 부담을 줄이면서 비교적 싼비용으로 고순도의 벤즈안트론을 제조할 수 있다.
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Patent Agency Ranking
公开(公告)号：KR1019900006710B1
公开(公告)日：1990-09-17
申请号：KR1019870006974
申请日：1987-07-01
Applicant: 한국화학연구원
IPC: C07C333/02
Abstract: Thio carbamate cpd. of formula (I) is new. In the formula, R1 and R2 are H, C1-6 alkyl, cyano lower alkyl, lower alkoxycarbonylal, lower alkenyl, haloalkenyl, alkylamino, dialkylamino, or phenyl substd. by one or more H, alkyl, halogen or nitro, or substd. benzyl, substd. phenoxy phenyl, or benzene sulphonyl substd. by alky or halogen, or substd. pyridine-2-yl, substd. 1,3thiazole-2-yl, substd. 1,3,4- thiadizole-2-yl, substd. 1,3,5triazole, or R1 and R2 have opt. O together with N to be bonded; R3 is the gp. of formula (A); R4 and R5 are H, lower alkyl, haloalkyl, etc.; R6 is alkyl, haloalkyl, phthalimido, 2-oxypiperidino, etc.; Z and W are 0 or S.
Abstract translation: 硫代氨基甲酸酯cpd 式（I）的化合物是新的。 在该式中，R 1和R 2是H，C 1-6烷基，氰基低级烷基，低级烷氧基羰基，低级烯基，卤代烯基，烷基氨基，二烷基氨基或苯基。 或一个或多个H，烷基，卤素或硝基。 苄基， 苯氧基苯基或苯磺酰基。 通过烷基或卤素，或取代。 吡啶-2-基， 1,3噻唑-2-基， 1,3,4-噻二唑-2-基， 1,3,5-三唑或R1和R2具有选择性。 O与N键合; R3是gp。 的式（A）; R4和R5是H，低级烷基，卤代烷基等; R6是烷基，卤代烷基，苯二甲酰亚氨基，2-氧代哌啶子基等; Z和W为0或S.
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公开(公告)号：KR1020050051068A
公开(公告)日：2005-06-01
申请号：KR1020030084761
申请日：2003-11-27
Applicant: 한국화학연구원
IPC: C09B31/043
Abstract: 본 발명은 섬유날염용 아조 적색 안료와 이의 제조방법에 관한 것으로서, 더욱 상세하게는 아미노-
N -치환된벤즈아미드 유도체를 디아조체로 사용하고 2-하이드록시-3-나프토일 아닐린 유도체를 커플러로 사용하여 상기 두 화합물을 커플링 반응하여 제조하는 다음 화학식 1로 표시되는 섬유날염용 신규 아조 적색 안료와 이의 제조방법에 관한 것이다.
상기 화학식 1에서, A는 C
1 ∼C
4 의 직쇄 또는 측쇄 알킬렌기를 나타내고; R
1 은 수소원자 또는 C
1 ∼C
4 의 알콕시기를 나타내고; R
2 는 수소원자, 염소원자, C
1 ∼C
4 의 알킬기, C
1 ∼C
4 의 알콕시기, 니트로기, 또는 아릴아미드기를 나타낸다.-
公开(公告)号：KR100385299B1
公开(公告)日：2003-05-23
申请号：KR1020010002733
申请日：2001-01-17
Applicant: 한국화학연구원
IPC: C09B62/03
Abstract: PURPOSE: Provided is a water-insoluble dispersion-reactive dye having an acetoxy ethyl sulfone reactive group, which reduces pollution, dose not contain hazardous amine and metals, can be used in acidic and neutral condition, and is excellent in washing-fastness and properties. CONSTITUTION: The dispersion-reactive dye(formula 2) having the 4-aminophenyl-beta-acetoxy ethyl sulfone reactive group(formula 1) is produced by a process comprising the steps of: diazotizing the 4-aminophenyl-beta-acetoxy ethyl sulfone(formula 1); making a coupling solution by dissolving a coupler in water and concentrated hydrochloric acid; mixing the diazotized 4-aminophenyl-beta-acetoxy ethyl sulfone with the coupling solution at 0-5deg.C; adding a base to keep pH neutral condition and separating the produced dye. In the formula, R, R1, R2, and R3 are identically or differently hydrogen, alkyl, alkoxy, cyanoalkyl, amino acetyl, and amino ester.
Abstract translation: 用途：提供一种具有乙酰氧基乙基砜反应性基团的水不溶性分散体 - 活性染料，其可减少污染，不含有害胺和金属，可在酸性和中性条件下使用，并且具有优异的耐洗牢度和性能 。 构成：具有4-氨基苯基-β-乙酰氧基乙基砜反应性基团（式1）的分散体活性染料（式2）通过包括以下步骤的方法制备：将4-氨基苯基-β-乙酰氧基乙基砜（ 公式1）; 通过将偶合剂溶解在水和浓盐酸中制备偶联溶液; 在0-5℃将重氮化的4-氨基苯基-β-乙酰氧基乙基砜与偶联溶液混合; 加入碱以保持pH中性条件并分离产生的染料。 在该式中，R，R1，R2和R3相同或不同地为氢，烷基，烷氧基，氰基烷基，氨基乙酰基和氨基酯。
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公开(公告)号：KR100367142B1
公开(公告)日：2003-01-10
申请号：KR1020000061922
申请日：2000-10-20
Applicant: 한국화학연구원
IPC: C09B46/00
Abstract: PURPOSE: Provided are benzimidazolone-based yellow pigments which are excellent in solvent resistance and colorfastness to light and provides a high yield, and a method for preparing the same. CONSTITUTION: The benzimidazolone-based yellow pigments represented by formula 1 are characterized in that it is prepared by using amino benzimidazolone represented by formula 9, as a diazotized compound. In the formulas, R, R1 and R2 which are the same or different, are hydrogen, C1-C4 alkyl group, nitro(-NO2) group, C1-C2 alkoxy group, C1-C18 heterocycle, methyl ester(COOCH3) or halogen group such as chloro or bromo. The yellow pigments are prepared by the steps of (i) diazotizing amino benzimidazolone compound represented by formula 9; (ii) dissolving a coupler represented by formula 11 into a solvent; (iii) mixing two solutions obtained from the steps (i) and (ii) at 0-5 deg.C; and (iv) adding base to the solution mixed in the step(iii) to adjust pH to 6-7 with stirring. In the formula 11, R, R1 and R2 are the same as the above.
Abstract translation: 用途：本发明提供耐溶剂性和耐光性优异且提供高收率的苯并咪唑酮类黄色颜料及其制备方法。 构成：由式1表示的基于苯并咪唑酮的黄色颜料的特征在于其通过使用由式9表示的氨基苯并咪唑酮作为重氮化的化合物来制备。 在式中，相同或不同的R，R 1和R 2是氢，C 1 -C 4烷基，硝基（-NO 2），C 1 -C 2烷氧基，C 1 -C 18杂环，甲酯（COOCH 3）或卤素 如氯或溴。 所述黄色颜料通过以下步骤制备：（i）使由式9表示的氨基苯并咪唑酮化合物重氮化; （ii）将由式11表示的成色剂溶解于溶剂中; （iii）在0-5℃下将步骤（i）和（ii）中获得的两种溶液混合; 和（iv）向步骤（iii）中混合的溶液中加入碱以在搅拌下将pH调节至6-7。 在式11中，R，R1和R2与上述相同。
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公开(公告)号：KR100270810B1
公开(公告)日：2000-10-16
申请号：KR1019990001697
申请日：1999-01-20
Applicant: 한국화학연구원 , 주식회사 모리아 켐텍
IPC: D06P3/32
Abstract: 본 발명은 가죽의 전사날염방법에 관한 것으로, 원피를 크롬탄닝하기 전 예비탄닝시 탄닝 보조제로 글루타르알데히드(Glutaraldehyde)를 사용하며, 탄닝이 완료된 혁에 수분산형 폴리에스테르 수지(10%) 45∼55중량부, 아크릴수지 10∼20중량부, 폴리우레탄 수지 3∼8중량부, 왁스 2∼3중량부, 알콜계 침투제 1∼2중량부, 물 20∼30중량부로 구성되는 조성물로 피복하여 표면을 개질한 후, 별도로 제조된 전사원지를 로울러형 그라비아 인쇄기로 인쇄하는 것을 특징으로 하며, 본 발명에 의한 날염방법은 일광견뢰도와 마찰견뢰도를 향상시킬 수 있고 무늬를 정교하게 표현할 수 있을 뿐만 아니라, 특히 세탁견뢰도와 드라이크리닝성을 향상시켜 피혁제품을 수세탁이 가능하도록 하였다.
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