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公开(公告)号：WO2016091644A1
公开(公告)日：2016-06-16
申请号：PCT/EP2015/078127
申请日：2015-12-01
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor： BAITA, Pietro , DALL'OCCO, Tiziano , DI DIEGO, Maria , LIGUORI, Dario , MARTURANO, Lorella , MAUS, Andreas , MEI, Gabriele , MEIER, Gerhardus , MORINI, Giampiero , PICA, Roberta , SCHUELLER, Ulf
IPC: C08F2/34 , C08F4/649 , C08F110/02
CPC classification number: C08F2/34 , C08F4/6493 , C08F4/6494 , C08F110/02 , C08F2410/02 , C08F2500/12 , C08F2500/18 , C08F4/6543 , C08F210/02
Abstract: Halogenated alcohols used in gas phase polymerization of ethylene in combination with a Ti based catalyst component and aluminum alkyls as co-catalyst allows to efficiently suppress ethane formation and to simultaneously increase the polymerization activity.
Abstract translation: 用于乙烯与Ti基催化剂组分和烷基铝作为助催化剂组合的气相聚合中的卤代醇允许有效地抑制乙烷形成并同时增加聚合活性。
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公开(公告)号：WO2010076289A1
公开(公告)日：2010-07-08
申请号：PCT/EP2009/067906
申请日：2009-12-23
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , BAITA, Pietro , KARER, Rainer , MEIER, Gerhardus , FUNK, Guido , MEI, Gabriele
Inventor： BAITA, Pietro , KARER, Rainer , MEIER, Gerhardus , FUNK, Guido , MEI, Gabriele
CPC classification number: B01J8/0015 , B01J8/1827 , B01J2208/00752 , B01J2208/00769 , C08F10/00 , C08F210/16 , C08F2/34 , C08F210/08 , C08F2500/12
Abstract: A process for introducing a catalyst powder based on a titanium compound supported on magnesium halide into a gas-phase olefin polymerization reactor, characterized in that it comprises: (a) storing the catalyst powder under an atmosphere of a liquid C 3 -C 12 alkane; (b) withdrawing from step (a) a measured amount of said catalyst powder by means of a rotary valve; (c) transferring said metered amount of catalyst powder to a catalyst activation section by a continuous pick-up flow of a liquid C 3 -C 12 alkane; (d) contacting the catalyst powder with a liquid phase comprising an organo-aluminum compound and optionally an external donor compound, at a temperature ranging from -20 °C to 60 °C; (e) introducing the activated catalyst powder in one or more gas-phase olefin polymerization reactors, where a gaseous mixture comprising at least one alpha-olefin is subjected to polymerization.
Abstract translation: 将基于负载在卤化镁上的钛化合物的催化剂粉末引入气相烯烃聚合反应器的方法，其特征在于，其包括：（a）将催化剂粉末在液体C 3 -C 12烷烃的气氛下储存; （b）通过旋转阀从步骤（a）中取出测量量的所述催化剂粉末; （c）通过液体C 3 -C 12烷烃的连续提取流将所述计量的催化剂粉末转移到催化剂活化部分; （d）在-20℃至60℃的温度范围内使催化剂粉末与包含有机铝化合物和任选的外部供体化合物的液相接触; （e）将活化的催化剂粉末引入一个或多个气相烯烃聚合反应器中，其中包含至少一种α-烯烃的气体混合物进行聚合。
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3.发明申请
公开(公告)号：WO2021104837A1
公开(公告)日：2021-06-03
申请号：PCT/EP2020/081425
申请日：2020-11-09
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor： CAPISANI, Paolo , ARICH DE FINETTI, Nicolò , BAITA, Pietro
Abstract: A process and a system for collecting samples of a polymerization catalyst or of a catalyst-containing polymer from an operation unit of a polymerization plant, the operation unit comprising an upper end and a lower end, the process comprising: a) extracting a prefixed amount of product from the lower end of the operation unit through a discharge valve; b) directing said product towards a filtering unit through an inlet valve; c) flushing an inert gas through the filtering unit; d) outgassing the filtering unit, through the outlet valve; e) displacing the filtering unit in order to collect the polymerization catalyst or the catalyst-containing polymer sample.
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公开(公告)号：WO2016050555A1
公开(公告)日：2016-04-07
申请号：PCT/EP2015/071674
申请日：2015-09-22
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor： BAITA, Pietro , DALL'OCCO, Tiziano , DI DIEGO, Maria , LIGUORI, Dario , MARTURANO, Lorella , MEI, Gabriele , MORINI, Giampiero , PICA, Roberta
CPC classification number: C08F110/02 , C08F2410/02 , C08F2500/12 , C08F2500/18 , C08F4/6494 , C08F4/6493 , C08F4/6492 , C08F4/6543
Abstract: A catalyst system for the (co)polymerization of olefins, comprising (A) a solid catalyst component comprising a titanium compound supported on magnesium dichloride (B) an aluminum alkyl compound and (C) an halogenated organic ester of formula A-COOR in which R is a C 1 C 10 hydrocarbon group and A is a C 1 C 5 saturated or unsaturated hydrocarbon group in which at least one of the hydrogen atoms is replaced by chlorine. Said catalyst systems has improved polymerization activity and reduced ethane generation.
Abstract translation: 一种用于（共）聚合烯烃的催化剂体系，包括（A）固体催化剂组分，其包含负载在二氯化镁上的钛化合物（B）烷基铝化合物和（C）式A-COOR的卤代有机酯，其中 R是C1C10烃基，A是C1C5饱和或不饱和的烃基，其中至少一个氢原子被氯代替。 所述催化剂体系具有改善的聚合活性和减少的乙烷产生。
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5.发明申请
公开(公告)号：WO2015028265A1
公开(公告)日：2015-03-05
申请号：PCT/EP2014/066801
申请日：2014-08-05
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor： COVEZZI, Massimo , MEI, Gabriele , DI DIEGO, Maria , GESSI, Piero , BAITA, Pietro , PICA, Roberta
IPC: C01B33/14 , C01B33/157 , C08F2/00 , C09C1/28 , C09C1/30
CPC classification number: C09J151/06 , B32B7/12 , B32B15/085 , B32B27/06 , B32B2307/718 , C08F10/00 , C08F110/02 , C08F2410/02 , C08L23/06 , C08L23/20 , C08L51/06 , C08L2205/02 , C08L2205/03 , C08L2207/062 , C09J5/02 , C09J123/06 , C09J123/20 , C09J2205/306 , C09J2400/166 , C09J2423/00 , C09J2423/04 , C09J2451/00 , C09J2463/008 , C08F2/005 , C08F2/007 , C08F2500/07 , C08F2500/12 , C08F2500/18 , C08F2500/24 , C08F4/025 , C08F110/06 , C08F4/6492
Abstract: Feeding a supported antistatic compound that does not comprise a transition- metal-based catalyst component to an olefin polymerization reactor allows avoiding the formation of polymer agglomerates in the reactor while at the same time minimizing negative effects on catalyst yield.
Abstract translation: 将不包含过渡金属基催化剂组分的负载抗静电化合物加入到烯烃聚合反应器中允许避免在反应器中形成聚合物附聚物，同时最小化对催化剂产率的负面影响。
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Patent Agency Ranking
公开(公告)号：WO2006120187A1
公开(公告)日：2006-11-16
申请号：PCT/EP2006/062148
申请日：2006-05-09
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , MEI, Gabriele , PATER, T.M. Joachim , MEIER, Gerben , BAITA, Pietro
Inventor： MEI, Gabriele , PATER, T.M. Joachim , MEIER, Gerben , BAITA, Pietro
CPC classification number: C08F210/06 , B01J8/1863 , B01J8/388 , B01J19/2435 , B01J2208/00548 , B01J2208/00557 , B01J2219/00164 , B01J2219/00166 , C08F210/16 , Y10S526/901 , C08F2/01 , C08F2/34 , C08F2/001 , C08F2500/12 , C08F2500/05 , C08F210/14
Abstract: A process for the gas-phase polymerization of α-olefÊns CH 2 =CHR, where R is hydrogen or a hydrocarbon radical having 1-12 carbon atoms, carried out in a first and a second interconnected polymerization zones, wherein the growing polymer particles flow through the first of said polymerization zones (riser) under fast fluidization conditions, leave said riser and enter the second of said polymerization zones (downcomer) through which they flow downward in a densified form, leave said downcomer and are reintroduced into said riser, in which process: (a) the gas mixture present in the riser is totally or partially prevented from entering the downcomer, and (b) the gaseous composition inside a portion of the downcomer is maintained substantially similar to the gaseous composition reacting in the riser.
Abstract translation: 其中R是氢或具有1-12个碳原子的烃基的α-烯烃CH 2 R 2 = CHR的气相聚合方法是在第一和第二互连聚合区 ，其中生长的聚合物颗粒在快速流化条件下流过第一个所述聚合区（提升管），离开所述提升管并进入其中以致密化形式向下流动的所述聚合区（降液管）中的第二个，离开所述降液管和 重新引入所述提升管中，在该过程中：（a）存在于提升管中的气体混合物完全或部分地被阻止进入降液管，并且（b）降液管的一部分内的气态组合物保持基本上类似于气体 组合物在提升管中反应。
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公开(公告)号：WO2021099106A1
公开(公告)日：2021-05-27
申请号：PCT/EP2020/080795
申请日：2020-11-03
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor： ARICH DE FINETTI, Nicolò , BAITA, Pietro , MAZZUCCO, Antonio , PICA, Roberta
IPC: C08F210/16 , C08F4/6592 , C08F2/02 , C08F2/06
Abstract: There is described a process for the continuous solution polymerization comprising polymerizing olefins of formula CH2=CHR, wherein R is hydrogen or a hydrocarbon radical having from 1 to 8 carbon atoms, and wherein one of the olefins has at least five carbon atoms, in the presence of a polymerization catalyst and in the absence of an inert solvent, at a polymerization temperature (Tp) satisfying the following relationship: Tp ≥ Tm + 20°C wherein Tm is the melting temperature of the obtained polymer.
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公开(公告)号：WO2018206321A1
公开(公告)日：2018-11-15
申请号：PCT/EP2018/060916
申请日：2018-04-27
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor： BAITA, Pietro , LIGUORI, Dario , MAVRIDIS, Harilaos , MORINI, Giampiero , PICA, Roberta
IPC: C08F210/16
Abstract: The present disclosure generally relates to a catalyst (i) which comprises a titanium compound, a magnesium compound and an ether, where the catalyst is activated by using two different alkyl compounds (ii) and (iii) in sequence and under specific molar ratios relative to each other and to the ether of the solid catalyst component (i). In some embodiments, the activated catalyst has an increased polymerization activity.
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公开(公告)号：WO2018083161A1
公开(公告)日：2018-05-11
申请号：PCT/EP2017/078033
申请日：2017-11-02
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor： BAITA, Pietro , COVEZZI, Massimo , DI DIEGO, Maria , MARTURANO, Lorella , MAZZUCCO, Antonio , MEI, Gabriele , PICA, Roberta
IPC: C08F110/02 , C08F2/34 , C08F4/654 , C08F4/649
Abstract: A gas-phase process for the homo or copolymerization of olefins carried out in the presence of a catalyst system formed by a contacting in a liquid hydrocarbon and in the presence of hydrogen (a) a solid catalyst component comprising a Ti, Mg and C1, and optionally an internal electron donor compound, (b) an aluminum alkyl compound and optionally (c) an external donor compound.
Abstract translation: 在催化剂体系存在下进行烯烃的均相或共聚的气相方法，所述催化剂体系通过在液态烃中和在氢存在下接触而形成（a）固体催化剂组分 （b）烷基铝化合物和任选的（c）外部给体化合物，其中所述化合物包含Ti，Mg和C1以及任选的内部电子给体化合物。
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10.发明申请CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS AND CATALYSTS THEREFROM OBTAINED 审中-公开用于获得烯烃和催化剂聚合的催化剂组分
公开(公告)号：WO2011076675A1
公开(公告)日：2011-06-30
申请号：PCT/EP2010/070033
申请日：2010-12-17
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , BRITA, Diego , COLLINA, Gianni , EVANGELISTI, Daniele , FAIT, Anna , GADDI, Benedetta , MORINI, Giampiero , BAITA, Pietro , MARTURANO, Lorella , MAVRIDIS, Harry
Inventor： BRITA, Diego , COLLINA, Gianni , EVANGELISTI, Daniele , FAIT, Anna , GADDI, Benedetta , MORINI, Giampiero , BAITA, Pietro , MARTURANO, Lorella , MAVRIDIS, Harry
CPC classification number: C08F10/00 , C08F110/02 , C08F2410/03 , C08F4/6543 , C08F4/6545 , C08F4/6494 , C08F2/001 , C08F2500/07 , C08F2500/04 , C08F2500/12 , C08F2500/14 , C08F2500/18 , C08F2500/11
Abstract: Catalyst component comprising Mg, Ti, and halogen atoms, and is characterized in that (a) the Ti atoms are present in an amount higher than 4% based on the total weight of the said catalyst component, (b) the amount of Mg and Ti atoms is such that the Mg/Ti molar ratio is higher than 2 and (c) by a X-ray diffraction spectrum, in which, in the range of 2θ diffraction angles between 47° and 52°, at least two diffraction lines are present at diffraction angles 2θ of 48.3 ± 0.2°, and 50.0 ± 0.2°, the most intense diffraction lines being the one at 2θ of 50.0 ± 0.2°, the intensity of the other diffraction line being equal to or lower than the intensity of the most intense diffraction line.
Abstract translation: 包含Mg，Ti和卤素原子的催化剂组分，其特征在于（a）Ti原子以基于所述催化剂组分的总重量高于4％的量存在，（b）Mg和 Ti原子使得Mg / Ti摩尔比高于2，（c）通过X射线衍射光谱，其中在2θ的范围内， 在47°和52°之间的衍射角，至少两条衍射线存在于衍射角2θ 为48.3±0.2°，50.0±0.2°，最强的衍射线为2？ 为50.0±0.2°，其他衍射线的强度等于或低于最强衍射线的强度。
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