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    PROCESS FOR THE GAS-PHASE POLYMERIZATION OF OLEFINS
    3.
    发明申请
    PROCESS FOR THE GAS-PHASE POLYMERIZATION OF OLEFINS 审中-公开
    油相的气相聚合方法

    公开(公告)号：WO2010026091A1

    公开(公告)日：2010-03-11

    申请号：PCT/EP2009/060997

    申请日：2009-08-26

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  MAZZUCCO, Antonio ,  SOFFRITTI, Silvia ,  CAPUTO, Tiziana ,  COLLINA, Gianni ,  RINALDI, Riccardo ,  PICA, Roberta

    Inventor： MAZZUCCO, Antonio ,  SOFFRITTI, Silvia ,  CAPUTO, Tiziana ,  COLLINA, Gianni ,  RINALDI, Riccardo ,  PICA, Roberta

    IPC: C08F10/00 ,  C08F4/64

    CPC classification number: C08F210/16 ,  C08F110/02 ,  C08F4/6543 ,  C08F2/34 ,  C08F2/001 ,  C08F2500/24

    Abstract: A process for the polymerisation of olefins in the presence of a solid catalyst component and a catalyst activator, the process being performed in a gas-phase reactor having interconnected polymerization zones, where the growing polymer particles flow upward through a first polymerization zone (riser) under fast fluidization conditions, leave said riser and enter a second polymerization zone (downcomer) through which they flow downward under the action of gravity, leave said downcomer and are reintroduced into the riser, thus establishing a polymer circulation between said riser and said downcomer, the process being characterized in that said solid catalyst component has an average size P50 ranging from 20 μm to 65 μm and the gas flows upward in said first polymerization zone at a velocity ranging from 0.8 to 2.0 m/s.

    Abstract translation: 一种在固体催化剂组分和催化剂活化剂存在下使烯烃聚合的方法，该方法在具有互连聚合区的气相反应器中进行，其中生长的聚合物颗粒向上流过第一聚合区（提升管） 在快速流化条件下，离开所述提升管并进入第二聚合区（降液管），通过它们在重力作用下向下流动，离开所述降液管并重新引入提升管，从而在所述提升管和所述降液管之间建立聚合物循环， 该方法的特征在于所述固体催化剂组分的平均尺寸P50为20μm至65μm，气体以0.8-2.0m / s的速度在所述第一聚合区域中向上流动。

    BUTENE-1 POLYMER HAVING A HIGH MELT FLOW RATE
    4.
    发明申请
    BUTENE-1 POLYMER HAVING A HIGH MELT FLOW RATE 审中-公开

    公开(公告)号：WO2019025582A1

    公开(公告)日：2019-02-07

    申请号：PCT/EP2018/071109

    申请日：2018-08-03

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： MARCHINI, Roberta ,  SPATARO, Stefano ,  PICA, Roberta

    IPC: C08F10/08 ,  C08F4/6592 ,  C09J123/20

    Abstract: A butene-1 polymer having: a) a Melt Flow Rate value of from 20 to less than 100 g/10 min., measured according to ISO 1133 at 190°C with a load of 2.16 kg; • b) an intrinsic viscosity (IV) measured in tetrahydronaphthalene (THN) at 135°C equal to lower than 0.95 dl/g; • c) a Mw/Mn value equal to or lower than 3.5, the lower limit being of 1.5; • d) a Mz value of 180,000 g/mol or higher; • e) a comonomer content, when comonomer is present, of up to 5% by weight.

    BUTENE-1 POLYMER COMPOSITION HAVING A HIGH MELT FLOW RATE
    6.
    发明申请
    BUTENE-1 POLYMER COMPOSITION HAVING A HIGH MELT FLOW RATE 审中-公开
    具有高熔体流动速率的丁烯-1聚合物组合物

    公开(公告)号：WO2018007279A1

    公开(公告)日：2018-01-11

    申请号：PCT/EP2017/066423

    申请日：2017-07-03

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： MARCHINI, Roberta ,  SPATARO, Stefano ,  BURGIN, Emanuele ,  PICA, Roberta

    IPC: C08L23/20 ,  C09J123/20 ,  C08F2/00 ,  C08F210/08

    Abstract: A butene-1 polymer composition having MFR values of from 400 to 2000 g/10 min, measured according to ISO 1133 at 190°C with a load of 2.16 kg, comprising: A) a butene-1 homopolymer or a copolymer of butene-1 with one or more comonomers selected from ethylene and higher alpha-olefins, having a copolymerized comonomer content of up to 5% by mole; B) a copolymer of butene-1 with one or more comonomers selected from ethylene and higher alpha-olefins, having a copolymerized comonomer content of from 6% to 25% by mole; said composition having a total copolymerized comonomer content from 5% to 18% by mole, referred to the sum of A) and B), and a content of fraction soluble in xylene at 0°C of 65% by weight or more, determined on the total weight of A) and B).

    Abstract translation: 根据ISO 1133在190℃和2.16kg的负荷下测量的MFR值为400-2000g / 10min的丁烯-1聚合物组合物，其包含：A）丁烯-1聚合物组合物， 1均聚物或丁烯-1与选自乙烯和更高级α-烯烃的一种或多种共聚单体的共聚物，共聚单体含量高达5％摩尔; B）丁烯-1与选自乙烯和更高级α-烯烃的一种或多种共聚单体的共聚物，共聚单体含量为6-25％（摩尔）; 所述组合物具有5％至18％摩尔的总共聚合共聚单体含量，相对于A）和B）的总和，以及在0℃下可溶于二甲苯的部分的含量为65重量％或更多， A）和B）的总重量。

    BUTENE-1 POLYMER COMPOSITION HAVING A HIGH MELT FLOW RATE
    7.
    发明申请
    BUTENE-1 POLYMER COMPOSITION HAVING A HIGH MELT FLOW RATE 审中-公开
    具有高熔体流动速率的丁烯-1聚合物组合物

    公开(公告)号：WO2018007280A1

    公开(公告)日：2018-01-11

    申请号：PCT/EP2017/066424

    申请日：2017-07-03

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： MARCHINI, Roberta ,  SPATARO, Stefano ,  BURGIN, Emanuele ,  PICA, Roberta

    IPC: C08L23/20 ,  C08F2/00 ,  C09J123/20

    Abstract: A butene-1 polymer composition having MFR values of from 400 to 2000 g/10 min, measured according to ISO 1133 at 190°C with a load of 2.16 kg, comprising: A) a butene-1 homopolymer or a copolymer of butene-1 with one or more comonomers selected from ethylene and higher alpha-olefins, having a copolymerized comonomer content of up to 5% by mole; B) a copolymer of butene-1 with one or more comonomers selected from ethylene and higher alpha-olefins, having a copolymerized comonomer content of from 6% to 20% by mole; said composition having a total copolymerized comonomer content from 4% to 15% by mole, referred to the sum of A) and B), and a content of fraction soluble in xylene at 0°C of 60% by weight or less, determined on the total weight of A) and B).

    Abstract translation: 根据ISO 1133在190℃和2.16kg的负荷下测量的MFR值为400-2000g / 10min的丁烯-1聚合物组合物，其包含：A）丁烯-1聚合物组合物， 1均聚物或丁烯-1与选自乙烯和更高级α-烯烃的一种或多种共聚单体的共聚物，共聚单体含量高达5％摩尔; B）丁烯-1与选自乙烯和更高级α-烯烃的一种或多种共聚单体的共聚物，共聚单体含量为6摩尔％至20摩尔％; 所述组合物具有4-15％（摩尔）的总共聚合共聚单体含量，相对于A）和B）的总和，以及0℃下溶于二甲苯的部分的含量为60％重量或更低， A）和B）的总重量。

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