公开(公告)号：JP2004034019A

公开(公告)日：2004-02-05

申请号：JP2002367784

申请日：2002-12-19

Applicant: Basf Ag ,  ビーエーエスエフ アクチェンゲゼルシャフト

Inventor： KAIBEL GERD DR ,  MILLER CHRISTIAN ,  KLAS KATRIN ,  KINDLER ALOIS ,  AQUILA WERNER ,  DOBLER WALTER ,  BREUER KLAUS ,  POMMER ACHIM ,  DIRNSTEINER THOMAS

IPC: B01D3/26 ,  B01D3/14

CPC classification number: B01D3/141 ,  B01D3/14 ,  Y10S203/11 ,  Y10S203/20

Abstract: PROBLEM TO BE SOLVED: To provide a distillation column having high separation efficiency, in which the vapor amount is made constant all over the column including a feed section and a side steam take-off section.
SOLUTION: Partition walls DW are arranged substantially along the longitudinal direction of the distillation column so that the inside of the distillation column is divided into an upper zone 2 and a lower zone 4 of the feed section, an upper zone 3 and a lower zone 5 of the side stream take-off section, an upper common column section 1 and a lower common column section 6. A feeding mixture to be separated between the zones 2 and 4 of the feed section is in a wholly or partially vaporized state and/or the side stream to be taken off from the zones 3 and 5 of the side stream take-off section is in a wholly or partially vaporized state.
COPYRIGHT: (C)2004,JPO

公开(公告)号：DE10352336A1

公开(公告)日：2005-06-09

申请号：DE10352336

申请日：2003-11-06

Applicant: BASF AG

Inventor： ARNDT JAN-DIRK ,  KLAS KATRIN ,  LAAR FREDERIK VAN ,  HERWIG STEPHAN ,  HENKELMANN JOCHEM

IPC: B01J21/08 ,  B01J23/46 ,  B01J33/00 ,  B01J37/18 ,  C07C29/141 ,  C07C31/18 ,  C07C31/26 ,  C08B31/00

Abstract: A continuous process for the production of sugar alcohols by catalytic hydrogenation of an aqueous solution of a saccharide in the presence of a ruthenium catalyst prepared by treatment of an amorphous silicon dioxide based support material with a halogen-free aqueous solution of a low mol. wt. ruthenium compound followed by drying of the treated support at below 200 [deg]C and reduction of the resulting solid with hydrogen at 100-350 [deg]C.

公开(公告)号：DE10319452A1

公开(公告)日：2004-11-18

申请号：DE10319452

申请日：2003-04-30

Applicant: BASF AG

Inventor： KLAS KATRIN ,  BECKER HEIKE ,  VOGELSANG REGINA ,  HAUK ALEXANDER ,  SIEGERT MARKUS ,  HENKELMANN JOCHEM

IPC: C07C41/08 ,  C07C43/16 ,  B01J31/02

Abstract: A process for continuously preparing methyl vinyl ether by reacting methanol with ethyne in the liquid phase in the presence of a basic alkali metal or alkaline earth metal compound at a temperature of from 40 to 300° C. and a pressure of from 0.1 to 5 MPa abs, by carrying out the reaction in the absence of a continuous gas phase and at a methyl vinyl ether concentration in the entire liquid phase of

公开(公告)号：DE10258089A1

公开(公告)日：2004-06-24

申请号：DE10258089

申请日：2002-12-11

Applicant: BASF AG

Inventor： ARNDT JAN-DIRK ,  KLAS KATRIN ,  LAAR FREDERIK VAN ,  HERWIG STEPHAN ,  HENKELMANN JOCHEM

IPC: B01J21/08 ,  B01J23/46 ,  B01J33/00 ,  B01J37/18 ,  C07C29/141 ,  C07C31/125

Abstract: A continuous process for the production of sugar alcohols by catalytic hydrogenation of an aqueous solution of a saccharide in the presence of a ruthenium catalyst prepared by treatment of an amorphous silicon dioxide based support material with a halogen-free aqueous solution of a low mol. wt. ruthenium compound followed by drying of the treated support at below 200 degrees C and reduction of the resulting solid with hydrogen at 100-350 degrees C.

公开(公告)号：DE102004009311A1

公开(公告)日：2005-09-08

申请号：DE102004009311

申请日：2004-02-26

Applicant: BASF AG

Inventor： KLAS KATRIN ,  HAHN THILO ,  HENKELMANN JOCHEM

IPC: C07C29/17 ,  C07C29/38 ,  C07C29/42 ,  C07C29/56 ,  C07C33/042 ,  C07B41/02 ,  C07C41/26

Abstract: Process for preparing a propargyl alcohol of the formula I in which R 1 is a C 130 -alkyl, C 3-8 -cycloalkyl, C 2-20 -alkoxyalkyl, C 6-14 -aryl, C 7-20 -alkoxyarl, C 7-20 -aralkyl, C 7-20 -alkylaryl radical or H, by reacting a corresponding aldehyde of the formula R 1 -CHO with acetylene in the presence of ammonia and a catalytic amount of an alkali metal hydroxide, alkaline earth metal hydroxide or alkali metal alkoxide in the range from 0.6 to 10 mol % based on the aldehyde used, and also processes for preparing an allyl alcohol of the formulae II and III starting from the propargyl alcohol I prepared in accordance with the invention.

公开(公告)号：DE10350105A1

公开(公告)日：2005-05-25

申请号：DE10350105

申请日：2003-10-27

Applicant: BASF AG

Inventor： MILLER CHRISTIAN ,  HEYDRICH GUNNAR ,  KLAS KATRIN ,  BECKER MICHAEL

IPC: C07C41/60 ,  C07C43/32

公开(公告)号：DE102004038109A1

公开(公告)日：2006-03-16

申请号：DE102004038109

申请日：2004-08-05

Applicant: BASF AG

Inventor： HOEFER FRANK ,  BRAND ALEXANDRA ,  BOETTCHER ARND ,  KLAS KATRIN ,  VOGELSANG REGINA

IPC: C07B43/00 ,  C07B43/06 ,  C07D207/263

公开(公告)号：DE102004052041A1

公开(公告)日：2005-05-25

申请号：DE102004052041

申请日：2004-10-26

Applicant: BASF AG

Inventor： KLAS KATRIN ,  HEYDRICH GUNNAR ,  RICHTER INGO ,  HENKELMANN JOCHEM

IPC: C07C41/60 ,  C07C41/42 ,  C07C43/32

Abstract: Preparation of orthoformate esters (I) comprises reacting methyl orthoformate (II) and an alcohol (III) with at least 2 C atoms, in contact with a heterogeneous acidic catalyst (A). (A) is silicic acid; and aluminosilicate, or an oxide/mixed oxide of aluminum, zinc, zirconium and/or titanium.

公开(公告)号：DE10236578A1

公开(公告)日：2004-02-19

申请号：DE10236578

申请日：2002-08-08

Applicant: BASF AG

Inventor： HENKELMANN JOCHEM ,  KINDLER ALOIS ,  ARNDT JAN-DIRK ,  KLAS KATRIN

IPC: C07B61/00 ,  C07C29/42 ,  C07C33/042 ,  C07C33/048 ,  C07C33/14 ,  C07C33/48 ,  C07C403/00

Abstract: A method for the production of acetylene alcohols by mono-ethynylation of ketones comprising: (a) reaction of lithium with a 1-10C alkyl halide; (b) introduction of acetylene gas; and (c) addition of the ketone. A method for the production of acetylene alcohols of formula (I) by mono-ethynylation of ketones of formula R1-CO-R2 comprising: (a) reaction of lithium with a 1-10C alkyl halide, (b) introduction of acetylene gas and (c) addition of the ketone. HCequivalent toC-CR1R2-OH (I) R1, R2 = H or optionally unsaturated 1-30C alkyl, aryl, cycloalkylalkyl or cycloalkyl (all optionally substituted), or groups of formula -CH2CH2CHR3R4 or -CH2CH=CR3R4; and R3, R4 = H or optionally unsaturated, optionally substituted 1-30C alkyl, aryl, cycloalkylalkyl or cycloalkyl.

公开(公告)号：DE10163335A1

公开(公告)日：2003-07-10

申请号：DE10163335

申请日：2001-12-21

Applicant: BASF AG

Inventor： KAIBEL GERD ,  MILLER CHRISTIAN ,  KLAS KATRIN ,  KINDLER ALOIS ,  AQUILA WERNER ,  DOBLER WALTER ,  BREUER KLAUS ,  POMMER ACHIM ,  DIRNSTEINER THOMAS

IPC: B01D3/26 ,  B01D3/14 ,  B01D3/00

Abstract: Distillation column has a dividing wall which divides it into inflow and extraction sections, and upper and lower column zones. The mixture for distillation comprises a vapor feed which enters between the upper and lower inflow sections, between which the side extraction point removes vapor. The inflow and the extraction zones are offset relative too the dividing wall. The vapor feed rate is equal in all zones of the column. The distillation column has a dividing wall (TW) which divides it into an inflow section (2,4), an extraction section (3,5), and common upper (1) and lower (6) column zones. The mixture for distillation is at least partially a vapor feed (F) which enters between the upper and lower inflow sections, and the side extraction point (B) removes vapor between the upper and lower extraction zones. The cross sectional surfaces of the inflow and the extraction zones are set by an offset in the dividing wall. The F-factor is equal in all the zones of the column, defined as the product of the gas flow speed in m/seconds multiplied with the square root of the gas density in kg/m3.