Abstract:
PROBLEM TO BE SOLVED: To develop an improved PUR dispersion having a high level of hydrolysis stability even when together not using an expensive carbodiimide. SOLUTION: This aqueous dispersion for hydrolysis-resistant coatings contains a polyurethane capable of being obtained by reacting (a) a diisocyanate, (b) a diol, (c) a monomer having at least one isocyanato group or at least one group having reactivity with the isocyanato group, further having at least one hydrophilic or latent hydrophilic group, and thereby enabling the aqueous dispersion of a polyurethane, (d), if necessary, another polyvalent compound having a reactive group, and (e), if necessary, a monovalent compound having a reactive group in the absence of a metal organic catalyst at a temperature of 100 to 180 deg.C for an average reaction time of 1 to 20 hr.
Abstract:
Disclosed is a formulation containing (a) at least one polymer or copolymer that is produced in the presence of at least one photoinitiator, (b) at least one plasticizer, and (c) at least one branched compound comprising at least two terminal double bonds.
Abstract:
The invention relates to an automated method for inspecting and correcting the surfaces of flat materials, for example, leather. The invention particularly relates to a method for classifying surfaces of flat materials involving the following steps: (a) preparing a material; (b) optoelectronically sensing the surface of the material; (c) determining the number of defects; (d) determining the volume of defects and subsequently conducting an automatic classification of the flat materials based on the number and volume of defects.
Abstract:
The production of polyurethane dispersions involves: (a) making an NCO-terminated prepolymer from macro-ols, ionic or potentially ionic polyols and excess polyisocyanate; (b) reacting with compounds with at least two isocyanate-reactive amino groups at an NCO/NH group ratio of not more than 1:1; then (c) neutralizing; and (d) dispersing with water. An Independent claim is also included for polyurethane dispersions obtained by this method.
Abstract:
Composition comprising a polymer produced in the presence of a photoinitiator, a plasticizer and a branched compound with at least two terminal double bonds is new. Independent claims are also included for: (1) producing compositions as above by mixing a plasticizer with a dispersion comprising the polymer, optionally the branched compound and optionally water; (2) coating fibrous substrates by treating them with a composition as above and then exposing them to actinic radiation; (3) fibrous substrates produced as above.
Abstract:
Aqueous dispersions for hydrolysis resistant coatings containing a polyurethane synthesized from di isocyanates, diols, various monomers, if required further different monovalent compounds and different monovalent compounds from monomers. Aqueous dispersions for hydrolysis resistant coatings containing a polyurethane synthesized from (a) di isocyanates,(b) diols, of which (b1) 10-100 mole% on the diol (b) have a molecular weight of 500-5000 g/mole, and (b2) 0-90 mole% on diol (b) having a molecular weight of 60-500 g/mole, (c) various monomers from monomers (a) and (b), having at least one isocyanate group or at least one group reactive to isocyanates, and at least one hydrophilic group, or a potentially hydrophilic group, imparting water dispersibility to the polyurethane, (d) if required further different monovalent compounds from (a) and (b) having reactive groups, i.e. alcoholic OH groups, primary or secondary amine groups, or isocyanate groups, and (e) if required different monovalent compounds from monomers (a) and (b) containing a reactive group, obtained by reaction of monomers a, b, and c, and optionally d and e in the presence of organometallic catalysts at a temperature of 100 -180 degrees C and mean reaction times of 1-20 hours. Independent claims are included for: (1) a process for preparation of the aqueous dispersions containing a polyurethane as under (a) to (e) above; (2) an object coated, bonded, or impregnated with the aqueous dispersion; (3) a process for coating objects in metal, synthetic plastic, paper, textiles, leather, and wood, by application of a film from an aqueous dispersion and drying of the film; (4) a process for adhesive bonding of objects in metal, synthetic plastic, paper, textiles, leather, or wood, in which an aqueous dispersion is applied as a film, and is joined to another object before or after drying; and (5) a process for impregnation of objects in textiles, leather. or paper, in which the object is steeped in the aqueous solution and dried.
Abstract:
A composition contains (a) a (co)polymer obtained in the presence of a photoinitiator; (b) a plasticizer; and (c) a branched compound with >=2 terminal double bonds. An independent claim is also included for production of the composition by mixing plasticizer (b) with a dispersion containing (a), (c) and optionally also water.
Abstract:
The invention relates to aqueous dispersions comprising a polyurethane, produced from a) diisocyanates, b) diols, of which b1) 10 to 100 mol. %, relative to the total amount of diols (b), have a molecular weight of 500 to 5000 and b2) 0 to 90 mol. %, relative to the total amount of diols (b), have a molecular weight of 60 to 500 g/mol, c) various monomers from amongst the monomers (a) and (b) with at least one isocyanate group or at least one group reactive towards isocyanate groups, with furthermore, at least one hydrophilic or potentially hydrophilic group, by means of which the aqueous dispersibility of the polyurethane is affected, d) optionally additional polyfunctional compounds different from the monomers (a) to (c), said functions being alcoholic hydroxy groups, primary or secondary amino groups or isocyanate groups and e) optionally additional monofunctional compounds different from the monomers (a) to (d), said function being an alcoholic hydroxy group, a primary or secondary amino group or an isocyanate group. Said dispersions may be obtained by reaction of the monomers a), b), c) and optionally d) and e) in the presence of a caesium salt.
Abstract:
Mixtures containing:(A) an isocyanate and/or biuret of 1,6-diisocyanatohexane (HDI), (B) an isocyanurate of 1-isocyanato-3,5,5-trimethyl-5-isocyanatomethyl-cyclohexane (IPDI), (C) at least one emulsifier obtainable by reaction of at least one of a group of diisocyanates, and (D) optionally a solvent are new. Mixtures containing:(A) an isocyanate and/or biuret of 1,6-diisocyanatohexane (HDI), (B) an isocyanurate of 1-isocyanato-3,5,5-trimethyl-5-isocyanatomethyl-cyclohexane (IPDI), (C) at least one emulsifier obtainable by reaction of at least one diisocyanato (C2) selected from:tetramethylene-, hexamethylene-, dodecamethylene diisocyanate, 1,4-disocyanatocyclohexane, 4,4'-di(isocyanatocyclohexyl)methane, trimethylhexane diisocyanate, tetramethylhexane diisocyanate, tetramethylhexanediisocyanate, 1-isocyanato-3,3,5-trimethyl-5-(isocyanatomethyl)cyclohexane (PDI), 2,4- or 2,6-toluylene diisocyanate, and their isomeric mixtures, tetramethyxylyene diisocyanate, p-xylyene diisocyanate, 2,4' or 4,4'-diisocyanatodipohenylmethane, with at least one component (C1) having at least one group reactive to isocyanate groups and at least hydrophilic group, and (D) optionally a solvent. Independent claims are included for: (1) a polymer dispersion obtainable from the mixt ure; (2) A coating composition containing the mixture or polydispersion.