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公开(公告)号：JPH10298275A
公开(公告)日：1998-11-10
申请号：JP11052698
申请日：1998-04-21
Applicant: BASF AG
Inventor： KOENIGER RAINER DR , REICH WOLFGANG DR , BECK ERICH DR , GRUNER HELMUT , WOLF LOTHAR , MNICH JOHANNES
IPC: C08G65/32 , C07C67/08 , C08F290/06 , C08G18/83 , C08G59/00 , C08G59/16 , C08G59/42 , C08G63/21 , C08G63/47 , C08G63/52 , C08G63/676 , C08G63/78 , C08G63/91 , C08G65/332 , C08G65/48 , C09D167/06
Abstract: PROBLEM TO BE SOLVED: To provide a simple process for producing an ester of α,β- monoethylenically unsad. mono- and dicarboxylic acids and a hydroxylated polycondensate. SOLUTION: An ester E having a low residual acid content is produced from α,β-monoethylenically unsatd. 3-6C mono- and dicarboxylic acids S and a hydroxylated polycondensate P by reacting the acids S with the polycondensate P or a monomer component and/or an oligomer component and/or a polymer component for producing the polycondensate P in the presence or absence of a solvent and/or an esterification catalyst and/or other additives while removing water formed by the reaction and then removing unreacted acids S by distillation. In the step of distillation, water is added to distillate the acids S.
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公开(公告)号：JPH11269208A
公开(公告)日：1999-10-05
申请号：JP34168398
申请日：1998-12-01
Applicant: BASF AG
Inventor： KOENIGER RAINER DR , PAULUS WOLFGANG , REICH WOLFGANG DR , BECK ERICH , WOLF LOTHAR
IPC: C07C67/08 , C07C67/26 , C07C69/54 , C08F2/42 , C08F2/46 , C08F20/18 , C08F20/32 , C08F299/02 , C08G59/17 , C08L63/10 , C09D4/02 , C09D4/06 , C09D163/10
Abstract: PROBLEM TO BE SOLVED: To provide a mixture of acrylic compounds or methacrylic compounds comprising 40-95 wt.% of epoxide (meth)acrylate based on the acrylic compounds or the methacrylic compounds. SOLUTION: A mixture is obtained by a method comprising the following steps: (a) esterifying a hydroxy compound using acrylic acid or methacrylic acid; (b) if necessary, adding additional acrylic acid or methacrylic acid; and (c) subsequently, reacting an excess amount of acrylic acid or methacrylic acid with epoxides in the presence of the esterified product obtained in the step (a).
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公开(公告)号：DE10225943A1
公开(公告)日：2004-01-08
申请号：DE10225943
申请日：2002-06-11
Applicant: BASF AG
Inventor： JAWOREK THOMAS , DANIEL THOMAS , WOLF LOTHAR , KOENIGER RAINER , SCHWALM REINHOLD , HARTMANN GABRIELE , WICKEL STEFAN
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公开(公告)号：DE10161156A1
公开(公告)日：2003-06-18
申请号：DE10161156
申请日：2001-12-12
Applicant: BASF AG
Inventor： BRUCHMANN BERND , HAEBERLE KARL , HOERNER KLAUS DIETER , TREIBER REINHARD , RENZ THOMAS , SEYFFER HERMANN , MEYER BAERBEL , WOLF LOTHAR , KNOCHEL PAUL
IPC: C08G18/65 , C08G18/08 , C08G18/12 , C08G18/22 , C08G18/28 , C08G18/72 , C09D5/02 , C09D175/04 , C09J5/00 , C09J175/04 , C14C11/00 , C08G18/76 , C08G18/48 , C09D175/08 , C09J175/08
Abstract: The invention relates to aqueous dispersions comprising a polyurethane, produced from a) diisocyanates, b) diols, of which b1) 10 to 100 mol. %, relative to the total amount of diols (b), have a molecular weight of 500 to 5000 and b2) 0 to 90 mol. %, relative to the total amount of diols (b), have a molecular weight of 60 to 500 g/mol, c) various monomers from amongst the monomers (a) and (b) with at least one isocyanate group or at least one group reactive towards isocyanate groups, with furthermore, at least one hydrophilic or potentially hydrophilic group, by means of which the aqueous dispersibility of the polyurethane is affected, d) optionally additional polyfunctional compounds different from the monomers (a) to (c), said functions being alcoholic hydroxy groups, primary or secondary amino groups or isocyanate groups and e) optionally additional monofunctional compounds different from the monomers (a) to (d), said function being an alcoholic hydroxy group, a primary or secondary amino group or an isocyanate group. Said dispersions may be obtained by reaction of the monomers a), b), c) and optionally d) and e) in the presence of a caesium salt.
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公开(公告)号：DE59812499D1
公开(公告)日：2005-02-24
申请号：DE59812499
申请日：1998-10-28
Applicant: BASF AG
Inventor： KOENIGER RAINER DR , PAULUS WOLFGANG DR , REICH WOLFGANG DR , BECK ERICH DR , WOLF LOTHAR
IPC: C07C67/08 , C07C67/26 , C07C69/54 , C08F2/42 , C08F2/46 , C08F20/18 , C08F20/32 , C08F299/02 , C08G59/17 , C08L63/10 , C09D4/02 , C09D4/06 , C09D163/10
Abstract: A mixture (I) of acrylic or methacrylic compounds contains 40-95 wt.% epoxy (meth)acrylate and is prepared by: (a) esterification of hydroxyl compounds with acrylic acid or methacrylic acid; (b) optionally addition of further acrylic acid or methacrylic acid and (c) reaction of the excess acrylic or methacrylic acid with epoxide in the presence of the ester product from (a). Independent claims are included for: (i) a radiation curable composition (II) containing (I); and (ii) a process for the curing of (II) by subjecting (II) to energy intensive light or electron beams.
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Patent Agency Ranking
公开(公告)号：AU2003242636A1
公开(公告)日：2003-12-22
申请号：AU2003242636
申请日：2003-06-06
Applicant: BASF AG
Inventor： JAWOREK THOMAS , DANIEL THOMAS , WOLF LOTHAR , KONIGER RAINER , SCHWALM REINHOLD , HARTMANN GABRIELE , WICKEL STEFAN
IPC: C08G63/78 , A61L15/60 , C07C67/08 , C08G65/332 , C07C69/54
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公开(公告)号：AU2002349052A1
公开(公告)日：2003-06-23
申请号：AU2002349052
申请日：2002-12-06
Applicant: BASF AG
Inventor： WOLF LOTHAR , KNOCHEL PAUL , BRUCHMANN BERND , HABERLE KARL , HORNER KLAUS DIETER , TREIBER REINHARD , RENZ THOMAS , SEYFFER HERMANN , MEYER BARBEL
IPC: C08G18/65 , C08G18/08 , C08G18/12 , C08G18/22 , C08G18/28 , C08G18/72 , C09D5/02 , C09D175/04 , C09J5/00 , C09J175/04 , C14C11/00 , C08G18/66
Abstract: Aqueous dispersions comprising a polyurethane composed of a) diisocyanates, b) diols of which b 1 ) from 10 to 100 mol %, based on the total amount of diols (b), have a molecular weight of from 500 to 5000, and b 2 ) from 0 to 90 mol %, based on the total amount of diols (b), have a molecular weight of from 60 to 500 g/mol, c) monomers other than the monomers (a) and (b), containing at least one isocyanate group or at least one isocyanate-reactive group and further carrying at least one hydrophilic group or potentially hydrophilic group by means of which the polyurethane is made dispersible in water, d) if desired, further, polyfunctional compounds other than the monomers (a) to (c), containing reactive groups which are alcoholic hydroxyl groups, primary or secondary amino groups or isocyanate groups, and e) if desired, monofunctional compounds which are other than the monomers (a) to (d) and contain a reactive group which is an alcoholic hydroxyl group, a primary or secondary amino group or an isocyanate group, obtainable by reacting the monomers a), b), c), and, where used, d) and e) in the presence of a cesium salt.
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公开(公告)号：DE19716686A1
公开(公告)日：1998-10-22
申请号：DE19716686
申请日：1997-04-21
Applicant: BASF AG
Inventor： KOENIGER RAINER DR , REICH WOLFGANG DR , BECK ERICH DR , GRUNER HELMUT , WOLF LOTHAR , MNICH JOHANNES
IPC: C08G65/32 , C07C67/08 , C08F290/06 , C08G18/83 , C08G59/00 , C08G59/16 , C08G59/42 , C08G63/21 , C08G63/47 , C08G63/52 , C08G63/676 , C08G63/78 , C08G63/91 , C08G65/332 , C08G65/48 , C09D167/06 , C08G85/00 , C08G18/67 , C08G59/14 , C09D167/07 , C09D171/02 , C09D175/16
Abstract: A process for the production of esters (E) with a low content of residual acid from alpha , beta -mono-unsaturated 3-6C mono- or di-carboxylic acids (S) and hydroxyl group-containing polycondensates (P) comprises (a) reacting (S) and (P) (or the monomeric, oligomeric and/or polymeric components which form P) optionally in the presence of solvent and/or esterification catalyst and/or other additives and removing the water produced, and (b) removing unreacted (S) by distillation in the presence of added water.
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公开(公告)号：DE59811028D1
公开(公告)日：2004-04-29
申请号：DE59811028
申请日：1998-04-21
Applicant: BASF AG
Inventor： KOENIGER DR , REICH DR , BECK DR , WOLF LOTHAR , MNICH JOHANNES , GRUNER HELMUT
IPC: C08G65/32 , C07C67/08 , C08F290/06 , C08G18/83 , C08G59/00 , C08G59/16 , C08G59/42 , C08G63/21 , C08G63/47 , C08G63/52 , C08G63/676 , C08G63/78 , C08G63/91 , C08G65/332 , C08G65/48 , C09D167/06
Abstract: A process for the production of esters (E) with a low content of residual acid from alpha , beta -mono-unsaturated 3-6C mono- or di-carboxylic acids (S) and hydroxyl group-containing polycondensates (P) comprises (a) reacting (S) and (P) (or the monomeric, oligomeric and/or polymeric components which form P) optionally in the presence of solvent and/or esterification catalyst and/or other additives and removing the water produced, and (b) removing unreacted (S) by distillation in the presence of added water.
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公开(公告)号：DE19753322A1
公开(公告)日：1999-06-10
申请号：DE19753322
申请日：1997-12-02
Applicant: BASF AG
Inventor： KOENIGER RAINER DR , PAULUS WOLFGANG DR , REICH WOLFGANG DR , BECK ERICH DR , WOLF LOTHAR
IPC: C07C67/08 , C07C67/26 , C07C69/54 , C08F2/42 , C08F2/46 , C08F20/18 , C08F20/32 , C08F299/02 , C08G59/17 , C08L63/10 , C09D4/02 , C09D4/06 , C09D163/10 , C08L33/14 , C08L33/08 , C08L33/10 , C08J3/28
Abstract: A mixture (I) of acrylic or methacrylic compounds contains 40-95 wt.% epoxy (meth)acrylate and is prepared by: (a) esterification of hydroxyl compounds with acrylic acid or methacrylic acid; (b) optionally addition of further acrylic acid or methacrylic acid and (c) reaction of the excess acrylic or methacrylic acid with epoxide in the presence of the ester product from (a). Independent claims are included for: (i) a radiation curable composition (II) containing (I); and (ii) a process for the curing of (II) by subjecting (II) to energy intensive light or electron beams.
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