公开(公告)号：DE3047126A1

公开(公告)日：1982-07-29

申请号：DE3047126

申请日：1980-12-13

Applicant: BASF AG

Inventor： LEHNER AUGUST ING GRAD ,  WERTHER HEINZ-ULRICH DIPL CHEM ,  NAEGELE DIETER DIPL CHEM DR ,  LENZ WERNER DIPL CHEM DR ,  JUN MONG-JON DIPL CHEM DR ,  REIMANN HORST DIPL CHEM DR ,  ECKELL ALBRECHT DIPL CHEM DR

IPC: C08G18/60 ,  C08G18/67 ,  C08G69/48 ,  G03F7/037 ,  G03F7/26 ,  G03C1/68 ,  G03F7/10

公开(公告)号：DE3045515A1

公开(公告)日：1982-07-08

申请号：DE3045515

申请日：1980-12-03

Applicant: BASF AG

Inventor： HOFFMANN GERHARD DIPL CHEM DR ,  BRONSTERT BERND DIPL CHEM DR ,  HAHN HERBERT DIPL CHEM DR ,  JUN MONG-JON DIPL CHEM DR

IPC: B41N1/06 ,  B41N1/12 ,  G03F7/09 ,  G03F7/11 ,  G03F7/16 ,  G03C1/80 ,  G03C1/68 ,  G03F7/26

Abstract: A photosensitive multi-layer material comprising a base, which may or may not be provided with an adhesion-promoting layer, and a photopolymerizable layer, consisting of a mixture of a photoinitiator, a binder and a photopolymerizable monomer, possesses, between the base and the photopolymerizable layer, an adhesive layer of a hardened mixture of a binder and an etherified melamine-formaldehyde condensate, hardenable at 60 DEG -120 DEG C.

公开(公告)号：DE3100175A1

公开(公告)日：1982-08-05

申请号：DE3100175

申请日：1981-01-07

Applicant: BASF AG

Inventor： JUN MONG-JON DIPL CHEM DR ,  RICHTER PETER DIPL CHEM DR ,  BARZYNSKI HELMUT DIPL CHEM DR

IPC: G03F7/09 ,  G03C1/93 ,  G03F7/11 ,  G03F7/30 ,  G03F7/02

公开(公告)号：DE3047026A1

公开(公告)日：1982-07-22

申请号：DE3047026

申请日：1980-12-13

Applicant: BASF AG

Inventor： LEHNER AUGUST ING GRAD ,  JUN MONG-JON DIPL CHEM DR ,  LENZ WERNER DIPL CHEM DR ,  RICHTER PETER DIPL CHEM DR ,  SANNER AXEL DIPL CHEM DR ,  SCHORNICK GUNNAR DIPL CHEM DR ,  WERTHER HEINZ-ULRICH DIPL CHEM ,  ECKELL ALBRECHT DIPL CHEM DR

IPC: G03F7/035 ,  C08G18/67 ,  C08G18/78 ,  G03F7/032 ,  G03F7/26 ,  G03C1/68 ,  G03F3/10

公开(公告)号：DE2942183A1

公开(公告)日：1981-05-07

申请号：DE2942183

申请日：1979-10-18

Applicant: BASF AG

Inventor： HEINZ GERHARD DIPL CHEM DR ,  RICHTER PETER DIPL CHEM DR ,  JUN MONG-JON DIPL CHEM DR

IPC: C08F2/00 ,  C08F2/48 ,  C08F16/12 ,  C08F16/14 ,  C08F20/10 ,  C08F20/18 ,  C08F287/00 ,  C08F297/00 ,  C08F297/04 ,  C08L53/02 ,  G03F7/033 ,  C08J3/28 ,  C09J3/14 ,  G03C1/68

Abstract: Photopolymerizable compositions based on an elastomeric styrene-diene block polymer, one or more photopolymerizable olefinically unsaturated monomers and one or more photopolymerization initiators exhibit improved properties if they contain, as an essential constituent, an elastomeric block copolymer of the general structure A-B-C, where A is a thermoplastic, non-elastomeric polymer block based on styrene compounds and having a second order transition point above +25 DEG C., B is an elastomeric polymer block based on butadiene and/or isoprene and having a second order transition point below -20 DEG C. and C is a polymer block, different from B, having a second order transition point of from -30 DEG C. to +15 DEG C., C being either a homopolymer or copolymer block based on butadiene or isoprene or a random copolymer block based on conjugated dienes and styrene compounds. The photopolymerizable compositions may be used, inter alia, for the production of photo-curable adhesives, resilient and flexible sheet material and, in particular, flexographic relief printing plates.

公开(公告)号：DE2759163A1

公开(公告)日：1979-07-12

申请号：DE2759163

申请日：1977-12-31

Applicant: BASF AG

Inventor： BRONSTERT BERND DIPL CHEM DR ,  KUESTERS WERNER DIPL CHEM DR ,  JUN MONG-JON DIPL CHEM DR ,  WALLBILLICH GUENTER DIPL CHEM

IPC: C08F2/48 ,  G03F7/031 ,  G03F7/10

Abstract: The compsns. contain (a) >=1 cpd. of low mol. wt. and contg. >=1 unsatd. photopolymerisable double bond; (b) >=1 compatible organic polymeric binder; (c) a photo-initiator; and (d) 0.001-0.1 wt. % of an etherified thioanthraquinone cpd. of formula (I):- in which R is 1-12C alkyl, 1-8C alkyl substd. by an opt. etherified and/or esterified OH gp. and/or an alkoxycarbonyl gp., or an opt. substd. phenyl gp. Pref. cpds. (I) are propyl-, n-butyl-, and isobutylthioanthraquinones, and esp. 2-butylthio-2-anthraquinone (II). Presence of the (I) in known photopolymerisable compsns. reduces undesired polymerisation of the compsn. in the shadow of fine opaque image elements during exposure in contact with a negative, thus giving improved image clarity. The presence of the (I) does not reduce the light sensitivity or exposure latitude of the material.

公开(公告)号：DE2722421A1

公开(公告)日：1978-11-23

申请号：DE2722421

申请日：1977-05-18

Applicant: BASF AG

Inventor： BRONSTERT BERND DIPL CHEM DR ,  KUESTERS WERNER DIPL CHEM DR ,  JUN MONG-JON DIPL CHEM DR ,  WALLBILLICH GUENTER DIPL CHEM

IPC: G03F7/031 ,  G03F7/10 ,  C08L77/00

Abstract: The compsn. is based on a mixt. of low-mol. (poly)olefinic cpd(s). (I) and compatible organic polymeric binder(s) (II) contg. a photoinitiator. The novelty is that the compsn. contains 0.001-0.1 wt. % homogeneously dispersed 1-12C-alkyl-thio-anthraquinone (III) and pref. also 0.01-1 wt. % of an organic tert. amine (IV) or an aromatic alpha-ketocarboxylic acid (V) or its 1-18 C-alkyl ester or 0.02-2 wt. % of an organic N-nitrosohydroxylamine salt (VI). The relief structure is improved by reducing undesired polymerisable in the complete shadow of fine opaque image elements, with simultaneous favourable exposure latitude and without impairing the speed.