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公开(公告)号：JPH11255885A
公开(公告)日：1999-09-21
申请号：JP36937398
申请日：1998-12-25
Applicant: BASF AG
Inventor： BEER WULFRICH FRIEDEMANN , BEISER KLAUS , CIPRIAN JUERGEN DR , FRANZ LOTHAR DR , FRANZISCHKA WOLFGANG , PALM CHRISTOF DR , PAPE FRANK-FRIEDRICH DR , PAUL AXEL , PESSEL ULRICH-DIETER , WECK ALEXANDER
IPC: B01J39/04 , B01J39/05 , B01J47/02 , B01J47/026 , B01J49/00 , B01J49/06 , C08F6/08 , C08G65/20 , C08G65/30 , C08G65/331 , C08J5/20
Abstract: PROBLEM TO BE SOLVED: To provide a process for removing the sodium once more which derives from a catalyst after transesterification with minimum facilities. SOLUTION: For producing a hydroxyl group-containing polymer, especially a polytetrahydrofuran containing a hydroxyl end group, a corresponding acyloxy group-containing polymer, used as a start material, is transesterified with an alcohol in the presence of a sodium-containing catalyst, and for removing sodium cations, following the transesterification, in a catalytic amount of water, the polytetrahydrofuran solution is directly introduced into at least one ion exchanger and allowed to flow through it.
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2.发明专利
公开(公告)号：CA2311589A1
公开(公告)日：1999-06-24
申请号：CA2311589
申请日：1998-12-04
Applicant: BASF AG
Inventor： DOSTALEK ROMAN , FISCHER ROLF HARTMUTH , STEIN FRANK , KRUG THOMAS , PINKOS ROLF , PAUL AXEL
Abstract: The invention relates to a method for catalytically hydrogenating carboxylic acids or the anhydrides or esters thereof into alcohol on heterogeneous catalysts containing hydrogenating elements of groups 6, 7, 8, 9, 10 and 11 and optionally groups 2, 14 and 15 of the periodic table of elements or consisting thereof, in a liquid phase at temperatures of 100-300 ~C and at pressures of 10-300 bars, whereby 1-3,000 ppm of a basic alkali or earthalkaline compound in relation to the liquid hydrogenating feed and selected from a group consisting of hydroxides, carbonates, carboxylates and alcoholates is added to the hydrogenating reaction mixture.
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公开(公告)号：DE59601820D1
公开(公告)日：1999-06-10
申请号：DE59601820
申请日：1996-01-04
Applicant: BASF AG
Inventor： DOSTALEK ROMAN , FISCHER ROLF , HARDER WOLFGANG , PAUL AXEL , PINKOS ROLF
Abstract: PCT No. PCT/EP96/00023 Sec. 371 Date Jul. 1, 1997 Sec. 102(e) Date Jul. 1, 1997 PCT Filed Jan. 4, 1996 PCT Pub. No. WO96/20909 PCT Pub. Date Jul. 11, 1996Impurities are separated from aqueous solutions of 1,6-hexanediol or 1,6-hexanediol precursors, such as adipic and 6-hydroxycaproic acid, by a process which comprises adding at least one carboxylic acid to a solution (a) of 1,6-hexanediol and subjecting this solution (a) or a solution (b) containing carboxylic acid(s) as precursor(s) of 1,6-hexanediol to a heat treatment at temperatures above room temperature in the absence of hydrogen.
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公开(公告)号：DK277889D0
公开(公告)日：1989-06-07
申请号：DK277889
申请日：1989-06-07
Applicant: BASF AG
Inventor： URBAN DIETER , LADNER WOLFGANG , PAUL AXEL , SANNER AXEL
Abstract: Process for preparing a biocatalyst by mixing a) polyolefin fibres which have been rendered hydrophilic, b) crude porcine pancreatic lipase, c) at least one water-soluble dihydric to hexahydric alcohol with 2 to 6 carbon atoms and d) an aqueous buffer solution of pH 5 to 9 at 0 to 40 DEG C, filtering after 1 minute to 3 days, and washing the filter cake, and the use of the biocatalyst obtained in this way for resolving esters of racemic alcohols in aqueous medium.
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5.发明专利
公开(公告)号：MY133071A
公开(公告)日：2007-10-31
申请号：MYPI9805291
申请日：1998-11-20
Applicant: BASF AG
Inventor： PAUL AXEL , STEIN FRANK , FISCHER ROLF HARTMUTH , PINKOS ROLF , KRUG THOMAS
Abstract: A PROCESS FOR THE CATALYTIC HYDROGENATION OF CARBOXYLIC ACIDS OF ANHYDRIDES OR ESTERS THEREOF TO ALCOHOLS OVER HETEROGENEOUS CATALYSTS WHICH COMPRISE OR CONSIST OF HYDROGENARATING ELEMENTS FROM GROUPS 6, 7, 8, 9, 10 AND 11 AND, WHERE APPROPRIATE, FROM GROUPS 2, 14 AND 15 OF THE PERIODIC TABLE OF THE ELEMENTS IN LIQUID PHASE AT FROM 100 TO 300°C AND FROM 10 TO 300 BAR WHICH COMPRISES ADDING FROM 1 TO 3000 PPM, BASED ON THE LIQUID HYDROGENATION FEED, OF A BASIC ALKALI METAL COMPOUND OR ALKALINE EARTH METAL COMPOUND SELECTED FROM THE GROUP CONSISTING OF HYROXIDES, CARBONATES, CARBOXYLATES AND ALKOXIDES TO THE HYDROGENATION REACTION MIXTURE.
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Patent Agency Ranking
公开(公告)号：ES2130780T3
公开(公告)日：1999-07-01
申请号：ES96900564
申请日：1996-01-04
Applicant: BASF AG
Inventor： DOSTALEK ROMAN , FISCHER ROLF , HARDER WOLFGANG , PAUL AXEL , PINKOS ROLF
Abstract: PCT No. PCT/EP96/00023 Sec. 371 Date Jul. 1, 1997 Sec. 102(e) Date Jul. 1, 1997 PCT Filed Jan. 4, 1996 PCT Pub. No. WO96/20909 PCT Pub. Date Jul. 11, 1996Impurities are separated from aqueous solutions of 1,6-hexanediol or 1,6-hexanediol precursors, such as adipic and 6-hydroxycaproic acid, by a process which comprises adding at least one carboxylic acid to a solution (a) of 1,6-hexanediol and subjecting this solution (a) or a solution (b) containing carboxylic acid(s) as precursor(s) of 1,6-hexanediol to a heat treatment at temperatures above room temperature in the absence of hydrogen.
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公开(公告)号：DK277889A
公开(公告)日：1989-12-11
申请号：DK277889
申请日：1989-06-07
Applicant: BASF AG
Inventor： URBAN DIETER , LADNER WOLFGANG , PAUL AXEL , SANNER AXEL
Abstract: Process for preparing a biocatalyst by mixing a) polyolefin fibres which have been rendered hydrophilic, b) crude porcine pancreatic lipase, c) at least one water-soluble dihydric to hexahydric alcohol with 2 to 6 carbon atoms and d) an aqueous buffer solution of pH 5 to 9 at 0 to 40 DEG C, filtering after 1 minute to 3 days, and washing the filter cake, and the use of the biocatalyst obtained in this way for resolving esters of racemic alcohols in aqueous medium.
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公开(公告)号：ES2195440T3
公开(公告)日：2003-12-01
申请号：ES98964487
申请日：1998-12-04
Applicant: BASF AG
Inventor： DOSTALEK ROMAN , FISCHER ROLF HARTMUTH , KRUG THOMAS , PAUL AXEL , PINKOS ROLF , STEIN FRANK
Abstract: The invention relates to a method for catalytically hydrogenating carboxylic acids or the anhydrides or esters thereof into alcohol on heterogeneous catalysts containing hydrogenating elements of groups 6, 7, 8, 9, 10 and 11 and optionally groups 2, 14 and 15 of the periodic table of elements or consisting thereof, in a liquid phase at temperatures of 100-300 DEG C and at pressures of 10-300 bars, whereby 1-3,000 ppm of a basic alkali or earth-alkaline compound in relation to the liquid hydrogenating feed and selected from a group consisting of hydroxides, carbonates, carboxylates and alcoholates is added to the hydrogenating reaction mixture.
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公开(公告)号：DE59807773D1
公开(公告)日：2003-05-08
申请号：DE59807773
申请日：1998-12-04
Applicant: BASF AG
Inventor： DOSTALEK ROMAN , FISCHER HARTMUTH , KRUG THOMAS , PAUL AXEL , PINKOS ROLF , STEIN FRANK
Abstract: The invention relates to a method for catalytically hydrogenating carboxylic acids or the anhydrides or esters thereof into alcohol on heterogeneous catalysts containing hydrogenating elements of groups 6, 7, 8, 9, 10 and 11 and optionally groups 2, 14 and 15 of the periodic table of elements or consisting thereof, in a liquid phase at temperatures of 100-300 DEG C and at pressures of 10-300 bars, whereby 1-3,000 ppm of a basic alkali or earth-alkaline compound in relation to the liquid hydrogenating feed and selected from a group consisting of hydroxides, carbonates, carboxylates and alcoholates is added to the hydrogenating reaction mixture.
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公开(公告)号：DK613088A
公开(公告)日：1989-06-28
申请号：DK613088
申请日：1988-11-03
Applicant: BASF AG
Inventor： URBAN DIETER , LADNER WOLFGANG , PAUL AXEL
Abstract: A biocatalyst is produced by mixing… a) an insoluble, only slightly swellable copolymer of an N-vinyllactam with a cyclic amide which contains at least two ethylenically unsaturated copolymerisable groups, of which at least one is bonded directly to the amide nitrogen,… b) crude pig pancreatic lipase,… c) at least one water-soluble dihydric to hexahydric alcohol with 2 to 6 carbon atoms and… d) an aqueous buffer solution of pH 5 to 9… at 0 to 40 DEG C, filtering after 1 minute to 3 days and washing the filter cake, and is used for resolving esters of racemic alcohols.
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