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公开(公告)号:DE3238652A1
公开(公告)日:1983-05-05
申请号:DE3238652
申请日:1982-10-19
Applicant: BASF AG
Inventor: REFFERT RUDI WILHELM DIPL ING , BRONSTERT KLAUS DIPL CHEM DR , WULZ KLAUS DIPL CHEM DR , GOETHLICH LUTZ DIPL ING DR , RATH HANS PETER DIPL CHEM DR , WEISS STEFAN DIPL CHEM DR , HETTCHE ALBERT DIPL CHEM DR
Abstract: The process for the preparation of oxidised polymers of ethylene or copolymers of ethylene with other 1-olefins, such as 1-butene, by means of oxygen or oxygen-containing gases in aqueous suspension at temperatures below the crystallite melting point of the (co)polymers in the presence of small amounts of a quaternary ammonium or phosphonium salt.
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公开(公告)号:DE2840554A1
公开(公告)日:1980-03-27
申请号:DE2840554
申请日:1978-09-18
Applicant: BASF AG
Inventor: HERTEL OTTO DIPL CHEM DR , BEYER KARLHEINZ DIPL CHEM DR , WALLIS ALBRECHT DIPL CHEM DR , WULZ KLAUS DIPL CHEM DR , IZI KAMURAN DIPL ING
IPC: C07C305/06 , C07C141/04 , C07C139/10
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公开(公告)号:DE2744982A1
公开(公告)日:1979-04-19
申请号:DE2744982
申请日:1977-10-06
Applicant: BASF AG
IPC: C08G73/00 , C02F1/54 , C08G59/50 , C08G73/02 , C10M169/00 , C07C87/14 , C07C85/02 , D21H1/10 , B05D3/10 , B05D5/08 , C25D3/02 , C10M1/32 , C08L63/00 , C08J3/24
Abstract: A process for the manufacture of polyalkylenepolyamines by reacting a primary or secondary amine with a compound of the formula (I) where X is -Cl, -Br, or -OSO3H and R1 and R2 are H or saturated alkyl of 1 to 4 carbon atoms, and with at least the stoichiometric amount, based on the compound of the formula I, of an aqueous solution, of from 15 to 45 percent strength, of an alkali metal hydroxide or alkaline earth metal hydroxide, at from 60 DEG to 200 DEG C., cooling the reaction mixture to a temperature at which 2 aqueous phases form, and separating off the upper phase, containing polyalkylenepolyamnines. The rate of reaction can be increased by adding catalytic amounts of compounds which initiate the polymerization of alkyleneimines.
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公开(公告)号:DE2500874A1
公开(公告)日:1976-07-15
申请号:DE2500874
申请日:1975-01-10
Applicant: BASF AG
Abstract: Parent Patent discloses a process for continuous addn. of 1-12 moles ethylene oxide and/or propylene oxide to a cpd. contg. >=1 active H, in a heat exchanger-surrounded spiral tube reactor, under pressures at which reaction mixt. is liquid, in presence of alkaline-reacting catalysts. Reaction takes place at 190-240 degrees C, kept constant over tube length. Peak temps. in 1st half of reactor are =30 degrees C above inlet temp. and =240 degrees C. Ratio tube length:tube dia. is 105:(1-10). Tube length is 100-160m. and reaction mixt. is passed through at 20-60kg/hr. In present Patent of Addn., the reaction mixt. leaving the reactor is continuously monitored spectrophotometrically. In the presence of free ethylene oxide or propylene oxide, an electrical signal appearing in spectrophotometer functions as controlled for a regulator which switches off plant operation. Hazard of explosion through free alkylene oxide in presence of catalysts can be prevented. Plant can be operated without supervision, and can be switched on again, by hand or automatically, with a slight rise in reactor temp., for alkylene oxide-free prod. generation.
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公开(公告)号:DE3111712A1
公开(公告)日:1982-10-07
申请号:DE3111712
申请日:1981-03-25
Applicant: BASF AG
Inventor: DEGEN HANS-JUERGEN DIPL CHEM D , GUENDER WOLF DIPL CHEM DR , FREY GUENTER DIPL CHEM DR , STREIT WERNER DIPL CHEM DR , FIKENTSCHER ROLF DIPL CHEM DR , WULZ KLAUS DIPL CHEM DR
Abstract: A process for coloring paper with an acid dye and/or direct dye in an aqueous medium in the presence of a water-soluble reaction product of an alkylating agent, possessing an aromatic substituent, with a cationic polyelectrolyte. The process gives papers with high color strength and substantially avoids cylinder twosidedness of the coloration.
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公开(公告)号:DE2927118A1
公开(公告)日:1981-01-08
申请号:DE2927118
申请日:1979-07-05
Applicant: BASF AG
Inventor: FREY GUENTER DIPL CHEM DR , FIKENTSCHER ROLF DIPL CHEM DR , WITTMER PETER , POSCHMANN FRANZ DIPL CHEM DR , WULZ KLAUS DIPL CHEM DR , MUELLER RICHARD DIPL CHEM DR
Abstract: Mixt. of 0.5-10 pts. wt. trimethylamine per 100 pts. wt. of another tert. amine is used as the tert. amine in fatty alkyl diketene, (I), prepn. by (a) reacting fatty acid halides with tert. amines in inert, organic solvents at up to 90 deg.C; (b) washing out the reaction mixt. with water; (c) separating the organic phase; and (d) recovering (I) by organic solvent evaporation. Aq. emulsions of (I), or mixts. of (I), are used as bulk sizing agents for paper, e.g. in 0.05-0.15% concn., calculated as solids, w.r.t. pulp. Trimethylamine addn. suppresses viscosity increase during amine addn. and increases purity of (I).
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公开(公告)号:DE2756747A1
公开(公告)日:1979-06-28
申请号:DE2756747
申请日:1977-12-20
Applicant: BASF AG
IPC: C10M137/04 , C23F11/16 , C23F11/167 , C09K15/32 , C09K5/00 , C10M1/46
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