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公开(公告)号:JPH0676275A
公开(公告)日:1994-03-18
申请号:JP14930093
申请日:1993-06-21
Applicant: BASF MAGNETICS GMBH
Inventor: URURITSUHI IEEGAA , MIHIYAERU BOBURITSUHI , HERUMUUTO KOPUKE , RAINAA EDAA , HANSUUPEETAA SHIRUTOBERUKU , KURAUSU DEIITAA SHIYOOMAN , HAARARUTO KERAA
IPC: C09D5/23 , C09D175/00 , C09D175/04 , G11B5/64 , G11B5/72
Abstract: PURPOSE: To improve wear resistance and corrosion resistance by forming a protective layer comprising a specified polyurethane having specified mol.wt. obtd. by specified reaction on a ferromagnetic metal layer. CONSTITUTION: A protective layer formed on a metal layer consists of a polyurethane having 500 to 10000 average mol.wt. This polyurethane is obtd. by the following reaction. An isocyanate expressed by formula Q-(NCO)z is made to react with a compd. expressed by formula Rf -A-B and/or a compd. expressed by formula X-RH-B. In formulae, Q is an alkyl, cycloalkyl or heterocycloalkyl group, (z) is an integer 1 to 5, Rf is a perfluoro (cyclo) alkyl or perfluoroalkyl aryl group having 3 to 30 carbon atoms, A is -(CH2 )n -, wherein(n)= 1 to 10, B is -OH, =NK, -NH2 or -(COOH), RH is an alkyl or cycloalkyl group having 1 to 30 carbon atoms, and X is -H, -OH, =NH, -NH2 , -SO3 H or -SO3 Na.
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公开(公告)号:JPH0680805A
公开(公告)日:1994-03-22
申请号:JP8059393
申请日:1993-04-07
Applicant: BASF MAGNETICS GMBH
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公开(公告)号:JPH06295430A
公开(公告)日:1994-10-21
申请号:JP161594
申请日:1994-01-12
Applicant: BASF MAGNETICS GMBH
Inventor: HAARARUTO KERAA , URURIHI IEEGAA , HERUMUUTO SHIYUTAININGAA , HERUMUUTO KOPUKE , KURAUSU DEIITAA SHIYOOMAN , HANSUUPEETAA SHIRUTOBERUKU
IPC: C09D5/00 , C10M105/54 , C10M105/72 , C10N40/18 , G11B5/64 , G11B5/72 , G11B5/725
Abstract: PURPOSE: To obtain a magnetic recording medium having a ferromagnetic metal layer on a nonmagnetic substrate and having a protective layer thereon which shows excellent durability against repeated use by constituting the protective layer of a component expressed by specified formula. CONSTITUTION: This magnetic recording medium consists of a nonmagnetic substrate, at least one ferromagnetic metal layer on the substrate and a protective layer on the metal layer. This protective layer is formed of a compsn. expressed by formula Z-(CF2 )m -(CH2 )n -X-Y-(CH2 )n -(CF2 )m -Z. In formula, X is -S- or -CHOH, Y is -S- or -C=O, Z is -CH3 , -CF3 or -CH=CH2 , n is an integer 2 to 17, and m is an integer 0 to 7. Thereby, the obtd. magnetic recording medium has excellent surface mechanical characteristics showing special durability even when it is repeatedly used, and the medium is extremely stable against corrosion of the metal thin film by air of humidity in air. Therefore, a recording medium having excellent wear resistance and corrosion resistance can be obtd.
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公开(公告)号:JPH06301968A
公开(公告)日:1994-10-28
申请号:JP161494
申请日:1994-01-12
Applicant: BASF MAGNETICS GMBH
Inventor: HAARARUTO KERAA , URURIHI IEEGAA , HERUMUUTO SHIYUTAININGAA , HERUMUUTO KOPUKE , KURAUSU DEIITAA SHIYOOMAN , HANSUUPEETAA SHIRUTOBERUKU
Abstract: PURPOSE: To obtain a magnetic recording medium having a ferromagnetic metal layer on a nonmagnetic substrate and having a protective layer thereon which shows excellent wear resistance and corrosion resistance by constituting the protective layer of a material expressed by specified formula. CONSTITUTION: This magnetic recording medium has at least one ferromagnetic metal layer on a nonmagnetic substrate and has a protective layer on the metal layer. The protective layer comprises a compd. expressed by formula X-(CH2 )n -(CF2 )m -Y. In the formula, X is H2 O3 P, HO3 S, NaO3 SS, HS or H3 C-SO3 , Y is CH3 or CF3 , n is an integer 3 to 11, and m is an integer 0 to 7. Thereby, the obtd. medium has excellent wear resistance and corrosion resistance.
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公开(公告)号:JPH06187638A
公开(公告)日:1994-07-08
申请号:JP15353393
申请日:1993-06-24
Applicant: BASF MAGNETICS GMBH
Abstract: PURPOSE: To maximize the yield of a magnetic material by using a PVD method by vapor deposition of the magnetic material in an oblique angle direction at the time of forming a thin-film metallic layer on a polymer substrate. CONSTITUTION: The web-like substrate 2 passes over such a drum-like supporting body 1 which has a radius R and of which the revolving shaft is the origin of an x/y coordinate system. Coating screens 3, 3' condense the metallic vapor jet from a crucible evaporator 4 onto the substrate 2 at the point of a range 5. The angel range opened for coating on the substrate 2 is regulated by graduation angles Φ1 , Φ2 and is determined by the position of the evaporator 4. The coordinate base point of the angles Φ2, Φ1 is calculated in the counterclockwise direction starting from the position Xaxis of the coordinate system existing at the revolving shaft of the drum-like supporting body 1. The coordinate system of the evaporator 4 is like equation I. In the equation, A: the max. value of the quantity of the metal vapor butting against the substrate 2, β1 , β2 : the angles between the central perpendicular line of the evaporator 4 and the line connecting the center of the evaporator 4 and the ends of the coating screens 3, 3', (n): the evaporation rate specific to the evaporating metal source and is a value of 2 to 5.
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公开(公告)号:JPH06158286A
公开(公告)日:1994-06-07
申请号:JP19953893
申请日:1993-08-11
Applicant: BASF MAGNETICS GMBH
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公开(公告)号:JPH06157786A
公开(公告)日:1994-06-07
申请号:JP18975493
申请日:1993-07-30
Applicant: BASF MAGNETICS GMBH
Inventor: GERUTO FUITSUSHIYAA , ARUFUREETO HAAGEMAIYAA , HARUTOMUUTO HIBUSUTO , HANSU YURUGEN RIHITAA , HANSUUPEETAA SHIRUTOBERUKU , SHIRUBUAN RAZAARU , MATEIASU BORE
IPC: C08J7/00 , B23K26/00 , B29C35/08 , B29C59/16 , C08G63/88 , C08J5/18 , G11B5/73 , G11B5/84 , H05K3/38
Abstract: Sheet-like PET materials having slight surface roughness consisting of fine dot patterns in the submicron range are produced by double successive exposure of the surfaces to polarized UV light produced by a pulsed excimer laser and having planes of polarization arranged at an angle of from 20 DEG to 90 DEG relative to one another, and the PET films treated in this manner are used as a substrate for thin ferromagnetic metal layers.
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