公开(公告)号：WO2010066601A3

公开(公告)日：2011-06-16

申请号：PCT/EP2009066063

申请日：2009-11-30

Applicant: BASF SE ,  SCHLIEPHAKE VOLKER ,  FRIESE THORSTEN ,  BOTT KLAUS ,  BLECHSCHMITT MICHAEL ,  BLUM TILL ,  MUELLER-ENGEL KLAUS JOACHIM

Inventor： SCHLIEPHAKE VOLKER ,  FRIESE THORSTEN ,  BOTT KLAUS ,  BLECHSCHMITT MICHAEL ,  BLUM TILL ,  MUELLER-ENGEL KLAUS JOACHIM

IPC: C07C51/42

CPC classification number: C07C51/42 ,  C07C57/04

Abstract: The invention relates to a method for cleaving Michael adducts that are contained in a fluid F at a weight proportion of = 10 wt % and that were formed in the production of acrylic acid or esters thereof, in a cleaving device, which comprises a pump P and a separation column K having installations that effect separation and a recirculation heat exchanger UW, wherein for the purpose of feeding the cleaving energy, the pump P draws sump fluid from the sump chamber of the separation column K and continuously feeds said sump fluid back into the sump chamber above the level of the sump fluid through the recirculation heat exchanger UW, and wherein the pump P is a radial centrifugal pump having an open impeller.

Abstract translation: 已经形成在制备丙烯酸或其酯的一种的流体F的裂解具有以重量计= 10重量％含有迈克尔加成物的比例的方法，用分离的背间隙装置，包括一个泵P，分离塔K 内部和循环热交换器UW，其特征在于，用于供给所述间隙能量的目的，泵P吸入ķ从分离塔的底部空间底部液体并经由再循环热交换器UW在底部空间底部液体的对象的上方连续地循环，并且所述泵P的径向离心泵开 是叶轮。

公开(公告)号：WO2011000808A2

公开(公告)日：2011-01-06

申请号：PCT/EP2010059161

申请日：2010-06-29

Applicant: BASF SE ,  BLUM TILL ,  ZUROWSKI PETER ,  RISSEL STEFFEN ,  HAREMZA SYLKE ,  FRIESE THORSTEN ,  JAEGER ULRICH ,  SCHLIEPHAKE VOLKER ,  MUELLER-ENGEL KLAUS JOACHIM ,  HAMMON ULRICH ,  HOEFER FRANK

Inventor： BLUM TILL ,  ZUROWSKI PETER ,  RISSEL STEFFEN ,  HAREMZA SYLKE ,  FRIESE THORSTEN ,  JAEGER ULRICH ,  SCHLIEPHAKE VOLKER ,  MUELLER-ENGEL KLAUS JOACHIM ,  HAMMON ULRICH ,  HOEFER FRANK

IPC: C07C51/25

CPC classification number: C07C51/252 ,  C07C51/44 ,  C07C57/04

Abstract: The invention relates to a method for separating a raw acrylic acid from a product gas mixture comprising glyoxal as auxiliary product of a heterogeneously catalyzed partial gas phase oxidation of at least one C3-precursor compound, comprising the absorption of the acrylic acid in a high-boiling absorption agent and the rectificative processing of the resulting absorbent, and wherein, in a distillation unit, an absorption agent contained in the sump fluid that has been removed from the sump chamber of the absorption column is distilled and is fed back into the absorption before remaining high-boiling components are removed, and wherein the glyoxal content of the raw acrylic acid is reduced by limiting the duration of the high-boiling components in the distillation unit.

Abstract translation: 从乙二醛作为分离粗丙烯酸的方法的副含有产物的至少一种C3-前体化合物的非均相催化部分气相氧化，其包括在所得到的吸收物的高沸点吸收剂和整流后处理丙烯酸的吸收的产物气体混合物，并且在从底部空间中的 包含在蒸馏装置的液体除去塔底的吸收柱在其中吸收剂蒸馏除去而剩余的高沸点组分被除去之前再循环到吸收，并通过在粗丙烯酸在乙二醛含量的蒸馏单元限制Schwersiederverweilzeit降低。

公开(公告)号：WO2009133042A3

公开(公告)日：2010-01-14

申请号：PCT/EP2009055014

申请日：2009-04-27

Applicant: BASF SE ,  BLUM TILL ,  ZUROWSKI PETER ,  RISSEL STEFFEN ,  HAREMZA SYLKE ,  FRIESE THORSTEN ,  JAEGER ULRICH ,  SCHLIEPHAKE VOLKER ,  MUELLER-ENGEL KLAUS JOACHIM ,  RUMPF BERND

Inventor： BLUM TILL ,  ZUROWSKI PETER ,  RISSEL STEFFEN ,  HAREMZA SYLKE ,  FRIESE THORSTEN ,  JAEGER ULRICH ,  SCHLIEPHAKE VOLKER ,  MUELLER-ENGEL KLAUS JOACHIM ,  RUMPF BERND

IPC: B01J19/00 ,  C07C57/04

CPC classification number: B01J19/0013 ,  B01J2219/00094

Abstract: A method is disclosed for transferring heat to a liquid F containing dissolved monomeric acrylic acid, acrylic acid oligomers obtained by Michael addition, and acrylic acid polymer with the help of an indirect heat exchanger to which the liquid F is fed at a temperature TF = 150°C and a heat transfer fluid W is fed at a temperature Tw > TF. In said method, gas bubbles or thin layers of liquid F bordering a gas phase are generated in the liquid F while said liquid F flows through the heat exchanger.

Abstract translation: 一种用于将热量传递至单体丙烯酸的方法，丙烯酸迈克尔低聚物和丙烯酸聚合物溶解使用间接换热器，其是具有温度TF = 150℃，用一个温度Tw的流体热载体W上的液体含有F F型液状 > TF，供给气体的气泡或邻近F液的薄层气相的通过热交换器的流动期间，在液F被实现的形成。

公开(公告)号：BRPI0911187A2

公开(公告)日：2015-10-13

申请号：BRPI0911187

申请日：2009-04-27

Applicant: BASF SE

Inventor： RUMPF BERND ,  MULLER-ENGEL KLAUS JOACHIM ,  ZUROWSKI PETER ,  RISSEL STEFFEN ,  HAREMZA SYLKE ,  FRIESE THORSTEN ,  BLUM TILL ,  JAGER ULRICH ,  SCHLIEPHAKE VOLKER

IPC: C07C57/04 ,  B01J19/00

公开(公告)号：DE102008054587A1

公开(公告)日：2010-06-17

申请号：DE102008054587

申请日：2008-12-12

Applicant: BASF SE

Inventor： SCHLIEPHAKE VOLKER ,  FRIESE THORSTEN ,  BOTT KLAUS ,  BLECHSCHMITT MICHAEL ,  BLUM TILL ,  MUELLER-ENGEL KLAUS JOACHIM

IPC: C07C69/54 ,  C07C51/42

Abstract: Ein Verfahren zur Rückspaltung von in einer Flüssigkeit F mit einem Gewichtsanteil von ≧ 10 Gew.-% enthaltenen Michael-Addukten, die bei der Herstellung von Acrylsäure oder deren Ester gebildet wurde, in einer Rückspaltvorrichtung, die eine Pumpe P, eine Trennkolonne K mit trennwirksamen Einbauten und einem Umlaufwärmeaustauscher UW umfasst, wobei zum Zwecke der Zufuhr der Spaltenergie die Pumpe P aus dem Sumpfraum der Trennkolonne K Sumpfflüssigkeit ansaugt und über dem Umlaufwärmeaustauscher UW laufend oberhalb des Stands der Sumpfflüssigkeit in den Sumpfraum zurückführt und wobei die Pumpe P eine Radialkreiselpumpe mit offenem Laufrad ist.

公开(公告)号：DE102008041573A1

公开(公告)日：2010-03-04

申请号：DE102008041573

申请日：2008-08-26

Applicant: BASF SE

Inventor： BLUM TILL ,  ZUROWSKI PETER ,  RISSEL STEFFEN ,  HAREMZA SYLKE ,  FRIESE THORSTEN ,  JAEGER ULRICH ,  SCHLIEPHAKE VOLKER ,  MUELLER-ENGEL KLAUS JOACHIM ,  HAMMON ULRICH ,  HEILEK JOERG ,  MUELLER IMKE BRITTA

IPC: C07C57/05 ,  C07C57/07

Abstract: Separating acrylic acid, contained as main constituent and glyoxal, contained as by-product from a gaseous product mixture of a partial gas phase oxidation of 3C-precursor compound of acrylic acid comprises producing a liquid phase containing at least 70 wt.% of acrylic acid and at least 200 mol.ppm of glyoxal in relation to the contained molar quantity of acrylic acid and separating glyoxal from the acrylic acid by crystallization from the liquid phase, where the acrylic acid is formed in crystallite form and the glyoxal is enriched in the mother liquor remained after crystallization.

公开(公告)号：DE102008001435A1

公开(公告)日：2009-10-29

申请号：DE102008001435

申请日：2008-04-28

Applicant: BASF SE

Inventor： BLUM TILL ,  ZUROWSKI PETER ,  RISSEL STEFFEN ,  HAREMZA SYLKE ,  FRIESE THORSTEN ,  JAEGER ULRICH ,  SCHLIEPHAKE VOLKER ,  MUELLER-ENGEL KLAUS JOACHIM ,  RUMPF BERND

IPC: C07C57/07

Abstract: A process for transferring heat to a liquid F comprising dissolved monomeric acrylic acid, Michael acrylic acid oligomers, and acrylic acid polymer with the aid of an indirect heat exchanger to which are supplied the liquid F with a temperature TF of >=150° C. and a fluid heat carrier W with a temperature of TW>TF, wherein the formation of gas bubbles and/or of thin layers of liquid F adjoining a gas phase is brought about in the liquid F during the flow through the heat exchanger.

公开(公告)号：SG10201604016TA

公开(公告)日：2016-07-28

申请号：SG10201604016T

申请日：2012-10-25

Applicant: BASF SE

Inventor： CRONE SVEN ,  RYLL OLIVER ,  BLUM TILL ,  WECK ALEXANDER ,  PAPP RAINER ,  KROKOSZINSKI ROLAND ,  BLANKERTZ HEINRICH-JOSEF

公开(公告)号：BR112013008419A2

公开(公告)日：2016-06-28

申请号：BR112013008419

申请日：2011-10-04

Applicant: BASF SE

Inventor： MARTIN FRIEDRICH-GEORG ,  ZUROWSKI PETER ,  RISSEL STEFFEN ,  HAREMZA SYLKE ,  FRIESE THORSTEN ,  BLUM TILL ,  KORN TOBIAS JOHANNES ,  JAGER ULRICH ,  SCHLIEPHAKE VOLKER

IPC: C07C51/50 ,  C07C57/04

Abstract: processo para inibir a polimerização por radical livre não desejada do ácido acrílico, e, fase líquida. um processo para inibir a polimerização por radical livre não desejada do ácido acrílico presente em uma fase líquida p cujo teor do ácido acrílico é de pelo menos 10% em peso e que, com base no peso do ácido acrílico presente neste, adicionalmente compreende pelo menos 100 ppm em peso de ácido propiônico e de pelo menos 100ppm em peso de glioxal, em que pelo menos um composto químico do elemento cobre é adicionado à fase líquida p e as fases p líquidas resultantes às quais um composto líquido do elemento cobre foi adicionado.

公开(公告)号：RU2515279C9

公开(公告)日：2015-02-20

申请号：RU2011107104

申请日：2009-07-14

Applicant: BASF SE

Inventor： BLUM TILL ,  TSUROVSKI PETER ,  RISSEL SHTEFFEN ,  KHAREMTSA ZIL KE ,  FRIZE TORSTEN ,  JEGER UL RIKH ,  SHLIPKHAKE FOL KER ,  MJULLER-EHNGEL KLAUS JOAKHIM ,  KHAMMON UL RIKH ,  KHAJLEK JORG ,  MJULLER IMKE BRITTA

IPC: C07C51/25 ,  C07C51/16 ,  C07C51/43 ,  C07C51/44 ,  C07C57/04 ,  C07C57/05 ,  C07C57/07

Abstract: Изобретениеотноситсяк способуразделенияакриловойкислоты, содержащейсяв качествеосновногопродукта, иглиоксаля, содержащегосяв качествепобочногопродукта, всмесипродуктовчастичногогетерогеннокатализируемогопарофазногоокислениясоединения-предшественникаакриловойкислоты, содержащего 3 атомауглерода, прикоторомполучаютжидкуюфазуР, котораяпоменьшеймерена 70% отсвоеймассысостоитизакриловойкислоты, атакже, впересчетенамолярноеколичествосодержащейсяв нейакриловойкислоты, содержитпоменьшеймере 200 мол. м.д. глиоксаля, прикоторомэтоотделениеглиоксаляотакриловойкислотыосуществляетсяпутемкристаллизацииизжидкойфазыР. Способпозволяетпредотвратитьнежелательнуюполимеризациюакриловойкислоты. 24 з.п. ф-лы.