Abstract:
PROBLEM TO BE SOLVED: To remove a part of a face which is in the shadow region of a reflux sprayed and inhibited in polymerization of the internal structure included in a separating column suitable for a thermal separation method from the shadow region by using a method as simple as possible without a high cost, and also without a spraying nozzle to be used. SOLUTION: The problem is solved by the separating column which includes a continuity of a substance exchanging tray in which a covered double-T support and/or a covered U-shaped support are incorporated as a supporting element. COPYRIGHT: (C)2010,JPO&INPIT
Abstract:
The invention relates to a method for stabilising acrylic compounds, wherein a liquid phase, which contains at least one acrylic compound from the group acrylic acid, methacrylic acid and their respective esters, is mixed with at least one metal from the group copper, manganese and cerium and at least one ligand from the group consisting of a) quinoline compounds of formula (I), wherein the symbols have the following meanings: X is OH, NH2, O-C1-C4-alkyl, preferably OCH3, O-C(O)-C1-C4-alkyl, preferably O-C(O)-CH3, O-C(O)-C2H5 or O-C(O)-phenyl; R1 is H, or (C1-C4)-alkyl, preferably methyl; R2 is H, C1-C4-alkyl, preferably methyl, Cl, Br or SO3H and R3 is H, Cl or Br; and N-oxides of compounds of formula (I), b) 2,2'-bis(2,3-dihydro-3-oxoindolylides) and c) aliphatic y-dentate ligands where y = 2-6, containing at least two nitrogen atoms and y-2 further coordinating aliphatic or aromatic C1-C4 carbon bridges containing nitrogen atoms or heteroatoms.
Abstract:
The invention relates to a method for separating a raw acrylic acid from a product gas mixture comprising glyoxal as auxiliary product of a heterogeneously catalyzed partial gas phase oxidation of at least one C3-precursor compound, comprising the absorption of the acrylic acid in a high-boiling absorption agent and the rectificative processing of the resulting absorbent, and wherein, in a distillation unit, an absorption agent contained in the sump fluid that has been removed from the sump chamber of the absorption column is distilled and is fed back into the absorption before remaining high-boiling components are removed, and wherein the glyoxal content of the raw acrylic acid is reduced by limiting the duration of the high-boiling components in the distillation unit.
Abstract:
A method is disclosed for transferring heat to a liquid F containing dissolved monomeric acrylic acid, acrylic acid oligomers obtained by Michael addition, and acrylic acid polymer with the help of an indirect heat exchanger to which the liquid F is fed at a temperature TF = 150°C and a heat transfer fluid W is fed at a temperature Tw > TF. In said method, gas bubbles or thin layers of liquid F bordering a gas phase are generated in the liquid F while said liquid F flows through the heat exchanger.
Abstract:
processo para inibir a polimerização por radical livre não desejada do ácido acrílico, e, fase líquida. um processo para inibir a polimerização por radical livre não desejada do ácido acrílico presente em uma fase líquida p cujo teor do ácido acrílico é de pelo menos 10% em peso e que, com base no peso do ácido acrílico presente neste, adicionalmente compreende pelo menos 100 ppm em peso de ácido propiônico e de pelo menos 100ppm em peso de glioxal, em que pelo menos um composto químico do elemento cobre é adicionado à fase líquida p e as fases p líquidas resultantes às quais um composto líquido do elemento cobre foi adicionado.
Abstract:
Process for transferring heat to a liquid mixture comprising at least one (meth)acrylic monomer with the aid of an indirect heat exchanger comprises introducing the liquid mixture simultaneously into the primary side of the heat exchanger by a liquid heat carrier and secondary side of the heat exchanger, where: the liquid mixture comprising at least one (meth)acrylic monomer contains at least one added active compound other than (meth)acrylic monomers from tertiary amine or salts formed from a tertiary amine and Bronsted acid, and quaternary ammonium compounds. Process for transferring heat to a liquid mixture comprising at least one (meth)acrylic monomer with the aid of an indirect heat exchanger comprises introducing the liquid mixture simultaneously into the primary side of the heat exchanger by a liquid heat carrier and secondary side of the heat exchanger, where: the liquid mixture comprising at least one (meth)acrylic monomer contains at least one added active compound other than (meth)acrylic monomers from tertiary amine or salts formed from a tertiary amine and Bronsted acid, and quaternary ammonium compounds, with proviso that none of the tertiary and quaternary nitrogen atoms in the active compound bears a phenyl group, but at least partly contains an alkyl group.
Abstract:
Process for transferring heat to a liquid mixture comprising at least one (meth)acrylic monomer with the aid of an indirect heat exchanger comprises introducing the liquid mixture simultaneously into the primary side of the heat exchanger by a liquid heat carrier and secondary side of the heat exchanger, where: the liquid mixture comprising at least one (meth)acrylic monomer contains at least one added active compound other than (meth)acrylic monomers from tertiary amine or salts formed from a tertiary amine and Bronsted acid, and quaternary ammonium compounds. Process for transferring heat to a liquid mixture comprising at least one (meth)acrylic monomer with the aid of an indirect heat exchanger comprises introducing the liquid mixture simultaneously into the primary side of the heat exchanger by a liquid heat carrier and secondary side of the heat exchanger, where: the liquid mixture comprising at least one (meth)acrylic monomer contains at least one added active compound other than (meth)acrylic monomers from tertiary amine or salts formed from a tertiary amine and Bronsted acid, and quaternary ammonium compounds, with proviso that none of the tertiary and quaternary nitrogen atoms in the active compound bears a phenyl group, but at least partly contains an alkyl group.
Abstract:
A process for transferring heat to a liquid F comprising dissolved monomeric acrylic acid, Michael acrylic acid oligomers, and acrylic acid polymer with the aid of an indirect heat exchanger to which are supplied the liquid F with a temperature TF of >=150° C. and a fluid heat carrier W with a temperature of TW>TF, wherein the formation of gas bubbles and/or of thin layers of liquid F adjoining a gas phase is brought about in the liquid F during the flow through the heat exchanger.