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    2.
    发明专利
    未知

    公开(公告)号：DE50311061D1

    公开(公告)日：2009-02-26

    申请号：DE50311061

    申请日：2003-09-12

    Applicant: BASF SE

    Inventor： VOLLAND MARTIN ,  AHLERS WOLFGANG ,  EBEL KLAUS ,  PACIELLO ROCCO ,  ROEPER MICHAEL ,  MACKEWITZ THOMAS ,  BOEHM VOLKER ,  SAVA XAVIER ,  LOEBER OLIVER ,  BEY OLIVER ,  STEPHAN JUERGEN ,  HAESE FRANK

    IPC: C07C45/50 ,  C07B61/00 ,  C07C47/12 ,  C07C47/21 ,  C07F9/572 ,  C07F9/655 ,  C07F9/6558 ,  C07F9/6584 ,  C07F9/6596

    Abstract: A process for the production of dialdehydes and/or ethylenically unsaturated monoaldehydes by reaction of at least one compound having at least two ethylenically unsaturated double bonds with carbon monoxide and hydrogen in the presence of a hydroformylation catalyst comprising at least one complex of a Group VIII metal with at least one ligand comprising a pnicogen chelate compound. A process for the production of dialdehydes and/or ethylenically unsaturated monoaldehydes by reaction of at least one compound having at least two ethylenically unsaturated double bonds with carbon monoxide and hydrogen in the presence of a hydroformylation catalyst comprising at least one complex of a Group VIII metal with at least one ligand comprising a pnicogen chelate compound of formula (1). Q = bridging group of formula (2); A1, A2 = O, S, SiRaRb, NRc or CRdRe; Ra-Rc = H, alkyl, cycloalkyl, heterocycloalkyl, aryl or heteroaryl; Rd, Re = H, alkyl, cycloalkyl, heterocycloalkyl, aryl or heteroaryl or two Rd groups and/or two Re groups form an intermolecular bridging group D; D = bivalent bridging group of formula (3)-(6); R9,R10 = H, alkyl, cycloalkyl, aryl, halo, trifluoromethyl, carboxyl, carboxylate or cyano or together form a 3-4C alkylene bridge; R11-R14 = H, alkyl, cycloalkyl, aryl, halo, trifluoromethyl, COOH, carboxylate, cyano, alkoxy, SO3H, sulfonate, NE1E2, alkylene-NE1E2E3+X-, acyl or nitro; C = 0 or 1; Y = chemical bond; RI-RVI = H, alky, cycloalkyl, heterocycloalkyl, aryl or heteroaryl; COORf, COO-M+, SO3Rf, SO3-M+, NE1E2, NE1E2E3+X-, alkylene-NE1E2E3+X-, ORf, SRf, (CHRgCH2O)xRf, (CH2N(E1))xRf, (CH2CH2N(E1))xRf, halo, trifluoromethyl, nitro, acyl or cyano or 2 neighboring groups, together with two neighboring C atoms of the benzene ring to which they are bonded form a condensed ring system of 1-3 further rings; Rf, E1-E3 = H, alkyl, cycloalkyl or aryl; R9 = H, methyl or ethyl; M+ = cation, X-=anion; x = 1-120; a, b = 0 or 1; Pn = P, As or Sb; R1-R4 = heteroaryl, heteroaryloxy, alkyl, alkoxy, aryl, aryloxy, cycloalkyl, cycloalkoxy, heterocycloalkyl, heterocycloalkoxy or NE1E2 with the proviso that is R1 and R3 are bonded via the N atom to the pnicogen atom bonded pyrrole ring or R1 with R2 and/or R3 together with R4 form a divalent group E of formula Py-I-W or R1 and R2 and/or R3 and R4 form a bispyrrole group of formula Py-I-Py; Py = pyrrole group that is bonded via its N atom to Pn; I = chemical bond, O, S, SiRaRb, NRc, optionally substituted 1-10C alkylene or CRhCRi; W = cycloalkyl, cycloalkoxy, aryl, aryloxy, heteroaryl or heteroaryloxy; Rh and Ri = H, alkyl, cycloalkyl, heterocycloalkyl, aryl or heteroaryl

    3.
    发明专利
    未知

    公开(公告)号：AT420065T

    公开(公告)日：2009-01-15

    申请号：AT03748014

    申请日：2003-09-12

    Applicant: BASF SE

    Inventor： VOLLAND MARTIN ,  AHLERS WOLFGANG ,  EBEL KLAUS ,  PACIELLO ROCCO ,  ROEPER MICHAEL ,  MACKEWITZ THOMAS ,  BOEHM VOLKER ,  SAVA XAVIER ,  LOEBER OLIVER ,  BEY OLIVER ,  STEPHAN JUERGEN ,  HAESE FRANK

    IPC: C07C45/50 ,  C07B61/00 ,  C07C47/12 ,  C07C47/21 ,  C07F9/572 ,  C07F9/655 ,  C07F9/6558 ,  C07F9/6584 ,  C07F9/6596

    Abstract: A process for the production of dialdehydes and/or ethylenically unsaturated monoaldehydes by reaction of at least one compound having at least two ethylenically unsaturated double bonds with carbon monoxide and hydrogen in the presence of a hydroformylation catalyst comprising at least one complex of a Group VIII metal with at least one ligand comprising a pnicogen chelate compound. A process for the production of dialdehydes and/or ethylenically unsaturated monoaldehydes by reaction of at least one compound having at least two ethylenically unsaturated double bonds with carbon monoxide and hydrogen in the presence of a hydroformylation catalyst comprising at least one complex of a Group VIII metal with at least one ligand comprising a pnicogen chelate compound of formula (1). Q = bridging group of formula (2); A1, A2 = O, S, SiRaRb, NRc or CRdRe; Ra-Rc = H, alkyl, cycloalkyl, heterocycloalkyl, aryl or heteroaryl; Rd, Re = H, alkyl, cycloalkyl, heterocycloalkyl, aryl or heteroaryl or two Rd groups and/or two Re groups form an intermolecular bridging group D; D = bivalent bridging group of formula (3)-(6); R9,R10 = H, alkyl, cycloalkyl, aryl, halo, trifluoromethyl, carboxyl, carboxylate or cyano or together form a 3-4C alkylene bridge; R11-R14 = H, alkyl, cycloalkyl, aryl, halo, trifluoromethyl, COOH, carboxylate, cyano, alkoxy, SO3H, sulfonate, NE1E2, alkylene-NE1E2E3+X-, acyl or nitro; C = 0 or 1; Y = chemical bond; RI-RVI = H, alky, cycloalkyl, heterocycloalkyl, aryl or heteroaryl; COORf, COO-M+, SO3Rf, SO3-M+, NE1E2, NE1E2E3+X-, alkylene-NE1E2E3+X-, ORf, SRf, (CHRgCH2O)xRf, (CH2N(E1))xRf, (CH2CH2N(E1))xRf, halo, trifluoromethyl, nitro, acyl or cyano or 2 neighboring groups, together with two neighboring C atoms of the benzene ring to which they are bonded form a condensed ring system of 1-3 further rings; Rf, E1-E3 = H, alkyl, cycloalkyl or aryl; R9 = H, methyl or ethyl; M+ = cation, X-=anion; x = 1-120; a, b = 0 or 1; Pn = P, As or Sb; R1-R4 = heteroaryl, heteroaryloxy, alkyl, alkoxy, aryl, aryloxy, cycloalkyl, cycloalkoxy, heterocycloalkyl, heterocycloalkoxy or NE1E2 with the proviso that is R1 and R3 are bonded via the N atom to the pnicogen atom bonded pyrrole ring or R1 with R2 and/or R3 together with R4 form a divalent group E of formula Py-I-W or R1 and R2 and/or R3 and R4 form a bispyrrole group of formula Py-I-Py; Py = pyrrole group that is bonded via its N atom to Pn; I = chemical bond, O, S, SiRaRb, NRc, optionally substituted 1-10C alkylene or CRhCRi; W = cycloalkyl, cycloalkoxy, aryl, aryloxy, heteroaryl or heteroaryloxy; Rh and Ri = H, alkyl, cycloalkyl, heterocycloalkyl, aryl or heteroaryl

    LAMINATED LIGHTING UNIT
    4.
    发明专利
    LAMINATED LIGHTING UNIT 未知

    公开(公告)号：CA3022335A1

    公开(公告)日：2017-11-02

    申请号：CA3022335

    申请日：2017-04-26

    Applicant: BASF SE

    Inventor： KROEGER MICHAEL ,  ROEDER JENS CARSTEN ,  BOEHM VOLKER ,  HEMGESBERG MAXIMILIAN ,  SCHWALL DENIS ,  MAYER CHRISTIAN ,  DIESNER MORITZ ,  CUNZ THILO

    IPC: G02B5/02 ,  B32B17/10 ,  F21V8/00

    Abstract: The present invention concerns a lighting unit in form of laminated layers comprising a layer (A), a layer (B), wherein at least one of the layers (A) or (B) is optically transparent and the layers (A) and (B) are arranged parallel to each other, at least one functional interlayer (C), arranged between the layers (A) and (B) and arranged parallel to the layers (A) and (B) and at least one light source;the preparation of said lighting unit and the use of said lighting unit in buildings, furniture, cars, trains, planes and ships as well as in facades, skylights, glass, roofs, stair treads, glass bridges, canopies and railings.

    5.
    发明专利
    未知

    公开(公告)号：AT472561T

    公开(公告)日：2010-07-15

    申请号：AT06819481

    申请日：2006-11-15

    Applicant: BASF SE

    Inventor： HANEFELD PHILLIP ,  SIGL MARCUS ,  BOEHM VOLKER ,  ROEPER MICHAEL ,  WALTER HANS-MICHAEL ,  KROSSING INGO

    IPC: C08F4/12 ,  C08F10/10

    Abstract: Preparation of highly reactive isobutene homo- or copolymers having Mn=from 500 to 1 000 000 by polymerizing isobutene in the liquid phase in the presence of a dissolved, dispersed or supported metal-containing catalyst complex by using, as the catalyst complex, a compound I Zn+[MXa(OR)b]n-.Lx (I) M metal atom from the group of boron, aluminum, gallium, indium and thallium, R each independently aliphatic, heterocyclic or aromatic hydrocarbon radicals which have in each case from 1 to 18 carbon atoms and may comprise fluorine atoms, or silyl groups comprising C1 to C18 hydrocarbon radicals, X halogen atoms, Z proton (n=1), optionally substituted ammonium (n=1) or n-valent metal cation, L neutral solvent molecules, a integer from 0 to 3, b integer from 1 to 4, where a+b=4, and x>=0.

    New chelated transition metal complexes useful as catalysts for coupling reactions, preferably Heck-reaction, Suzuki-Miyaura-coupling, Sonogashira-Hagihara-reaction and Stille-reaction
    8.
    发明专利
    New chelated transition metal complexes useful as catalysts for coupling reactions, preferably Heck-reaction, Suzuki-Miyaura-coupling, Sonogashira-Hagihara-reaction and Stille-reaction 未知

    公开(公告)号：DE102008000077A1

    公开(公告)日：2008-07-31

    申请号：DE102008000077

    申请日：2008-01-17

    Applicant: BASF SE

    Inventor： BOEHM VOLKER ,  ROEPER MICHAEL ,  WUERTHWEIN ERNST-ULRICH ,  WIGBERS CHRISTOF ,  CHABANAS MATTHIEU ,  TELES JOAQUIM HENRIQUE ,  ALTENHOFF ANSGAR GEREON

    IPC: C07C257/20 ,  C07F1/08 ,  C07F15/00

    Abstract: Chelated transition metal complexes (Q), are new. Chelated transition metal complexes (Q) of formula (I), (II) or (III), are new. A : N'-substituted N-acylamidine of formula (O=C(R3>)-NH-C(R2>)=N-R1>) (IV) or (O=C(R3>)-N->-C(R2>)=N-R1>) (V) and/or its tautomer and/or mesomer structures, where one of R1>-R3> are bridged to per unit of A by Q, which connects at least 2 units of A together; Q : hydrocarbon bridge with 1 and/or 3 to 20 carbon atoms, a cyclic hydrocarbon bridge with 3-20C, where the hydrocarbon bridge can be mono or poly unsaturated, or a heterocycle, (hetero)aromate with 5-14 ring members, which is bonded directly or over 1-6C-alkyl or 2-6C-alkenyl; R1>-R3>hydrocarbon with 1 and/or 3 to 20 carbon atoms or 3-20C-cyclic hydrocarbon, where the hydrocarbon bridge can be mono or poly unsaturated, or a heterocycle, (hetero)aromate with 6-14 ring members, which is bonded directly or over 1-6C-alkyl or 2-6C-alkenyl, where the hydrogen atoms in Q and/or R1>-R3 are optionally substituted by one or more 1-6C-alkyl, 1-4C-haloalkyl, OR4>, NR5>R6>, COOR7>, Si(R8>)3, Si(R6>)2R9>, halo, aryl or 3-8C-cycloalkyl; R4>, R7>, R9>1-12C-alkyl, 7-12C-aralkyl, 6-10C-aryl, 3-8C-cycloalkyl or 3-8C-cycloalkyl, in which CH2 group is substituted by O, NH or NR10>; either R5>, R8>H, 1-12C-alkyl, 7-12C-aralkyl, 6-10C-aryl, 3-8C-cycloalkyl or 3-8C-cycloalkyl, in which CH2-group is substituted by O, NH or NR10>; or R5>R8>-(CH2)y; y : 4-7; R8>, R10>1 and/or 3- carbon to 12C-alkyl or 7-12C-aralkyl; M : Cu, Co, Pd, Pt (all preferred), Zn, Fe, Ni, Ru, Rh, Os or Ir; X : coordinating anion or a weakly coordinated anion; L : a ligand; n, m : 0-3; and p, q : 1-3. Independent claims are included for: (1) a process for preparing (Q); (2) a chelated N'-substituted N-acylamidine compound of formula ((A)p-Q-(A)q) (VI), where (VI) is excluded, when Q is 1,4-phenyl, R1> is n-butyl and R3> is tert.butyl; (3) a process for the preparation of (VI) comprising reacting N'-substituted amidine compound of formula (R1>-NH-C(=NH)-R2>) (X) with a dicarboxylic acid compound of formula (Z-C(=O)-Q-C(=O)-Z) (XI) in the presence of a base; and (4) a process for the preparation of bridged (VI) comprising reacting a diamine compound of formula (H2N-Q-NH2) (XII) with an acylimide acid derivative of formula (Z-C(R2>)=N-C(=O)-R3>) (XIII). Z : a nucelophilic substituted leaving group. [Image].

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