Abstract:
Disclosed are expandable styrene polymers (EPS) containing, in relation to the styrene polymer, a) 0.05 to 5 percent by weight of an organic bromine compound containing a minimum of 50 percent by weight of bromine as a flameproofing agent, b) 0.05 to 2 percent by weight of a flameproofing synergist, c) 1 to 5 percent by weight of a metallic salt as an acid collector. Also disclosed is a method for producing said expandable styrene polymers.
Abstract:
Polymers comprising at least one unit of formula (1) wherein n is 0 or 1, m and p are independently from each other 0,1,2,3,4,5 or 6, provided that the sum of n, m and p is at least 2, and n and p are not 0 at the same time, Ar 1 and Ar 2 are independently from each other C 6-14-arylene or C 6-14-aryl,which may be substituted with 1 to 4 substituents independently selected from the group consisting of C 1-30-alkyl, C 2-30-alkenyl, C 2-30-alkynyl, C 5-8-cycloalkyl, C 6-14-aryl and 5 to 14 membered heteroaryl, and X 1,X 2 and X 3 are independently from each other and at each occurrence O or S, compositions comprising these polymers, and electronic devices comprising a layer formed from the compositions. Preferably, the electronic device is an organic field effect transistor and the layer is the dielectric layer.
Abstract:
A mixture comprising a) 5 to 95 wt.-% of a copolymer A that contains one or more copolymer blocks (B/S)A, each made of 65 to 95 wt.-% of vinyl aromatic monomers and 5 to 35 wt.-% dienes and having a glass transition temperature Tg A in the range of 40° to 90°C, b) 5 to 95 wt.-% of a block copolymer B containing at least one hard block S made of 95 to 100 wt.-% of vi-nyl aromatic monomers and 0 to 5 wt.-% dienes, one or more copolymer blocks (B/S)A, each made of 65 to 95 wt.-% of vinyl aro-matic monomers and 5 to 35 wt.-% dienes and having a glass transition temperature Tg A in the range of 40° to 90°C and one or more copolymer blocks (B/S)B, each made of 20 to 60 wt.-% of vinyl aromatic monomers and 40 to 80 wt.-% dienes and having a glass transition temperature Tg B in the range of -70° to 0°C, c) 0 to 45 wt.% of A and B of various thermoplastic polymers C and d) 0 to 6 wt.-% of processing aids D, wherein the total of A through D is 100 wt.-%, and use thereof for the production of shrink--wrap films.
Abstract:
Un proceso de producción de copolímeros en bloque con una estructura isotáctica en el bloque de poliestireno que comprenden al menos un bloque de poliolefina y al menos un bloque polivinilaromático mediante la polimerización secuencial de monómeros olefínicos y monómeros vinilaromáticos, donde la polimerización de los monómeros olefínicos y los monómeros vinilaromáticos se lleva a cabo en presencia de un complejo metálico del Grupo IV de una fenoxiimina como catalizador.
Abstract:
A mixture which comprises a) from 25 to 75% by weight of a block copolymer A which comprises at least one hard block S composed of vinylaromatic monomers and comprises one or more soft blocks BA in each case composed of from 0 to 5% by weight of vinylaromatic monomers and from 95 to 100% by weight of dienes, where the proportion by weight of the hard blocks S in the block copolymer A is from 65 to 90% by weight; b) from 5 to 25% by weight of a block copolymer B which comprises at least one hard block S composed of vinylaromatic monomers and comprises one or more copolymer blocks (B/S)B in each case composed of from 20 to 60% by weight of vinylaromatic monomers and from 80 to 40% by weight of dienes, where the proportion by weight of the hard blocks S in the block copolymer B is from 25 to 70% by weight; c) from 0 to 70% by weight of polystyrene or of a block copolymer C other than A and B, and d) from 0 to 6% by weight of a plasticizer D, where the entirety of components A) to D) gives 100% by weight, and use for transparent thermoforming foils or transparent injection-molded items.
Abstract:
Expandable styrene polymers (EPS) comprising, in each case based on the styrene polymer, a) from 0.05 to 5% by weight of an organic bromine compound whose bromine content is at least 50% by weight, as flame retardant, b) from 0.05 to 2% by weight of a flame retardant synergist, c) from 0.1 to 5% by weight of a metal salt as acid scavenger, and process for their production.
Abstract:
A mixture which contains a) a copolymer or block copolymer A comprising one or more copolymer blocks (B/S)A which are respectively composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes, and whose glass transition temperature TgA is in the range from 40° to 90° C., b) a block copolymer B comprising at least one hard block S which is composed of vinylaromatic monomers, and comprising one or more copolymer blocks (B/S)B which are respectively composed of from 20 to 60% by weight of vinylaromatic monomers and of from 80 to 40% by weight of dienes, and whose glass transition temperature TgB is in the range from -70° to 0° C., c) a polystyrene C, and its use for the production of packaging for electronics components.
Abstract:
A mixture which comprises from 5 to 50% by weight of a block copolymer A, which comprises one or more copolymer blocks (B/S)A each composed of from 65 to 95% by weight of vinylaromatic monomers and from 35 to 5% by weight of dienes and of a glass transition temperature TgA in the range from 40° to 90° C.; from 95 to 50% by weight of a block copolymer B, which comprises at least one hard block S composed of vinylaromatic monomers and comprises one or more copolymer blocks (B/S)B each composed of from 20 to 60% by weight of vinylaromatic monomers and from 80 to 40% by weight of dienes and of a glass transition temperature TgB in the range from −70° to 0° C.; from 0 to 45% by weight of polystyrene or of a block copolymer C other than A and B; and from 0 to 6% by weight of a plasticizer; and its use for production of shrink films.