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    PESTICIDALLY ACTIVE COMPOSITIONS COMPRISING 3-ACETYL-1-PHENYLPYRAZOLE COMPOUNDS
    1.
    发明申请
    PESTICIDALLY ACTIVE COMPOSITIONS COMPRISING 3-ACETYL-1-PHENYLPYRAZOLE COMPOUNDS 审中-公开
    包含3-乙酰基-1-苯基甲基吡唑化合物的农药活性组合物

    公开(公告)号：WO2008092851A2

    公开(公告)日：2008-08-07

    申请号：PCT/EP2008051026

    申请日：2008-01-29

    Applicant: BASF SE ,  KORADIN CHRISTOPHER ,  LANGEWALD JUERGEN ,  ANSPAUGH DOUGLAS D ,  COTTER HENRY VAN TUYL

    Inventor： KORADIN CHRISTOPHER ,  LANGEWALD JUERGEN ,  ANSPAUGH DOUGLAS D ,  COTTER HENRY VAN TUYL

    CPC classification number: A01N43/56 ,  A01N47/02 ,  A01N43/58 ,  A01N43/80 ,  A01N51/00 ,  A01N2300/00

    Abstract: The present invention relates to pesticidal compositionscomprising as active componentsat least one 3-acetyl-1-phenylpyrazole compound of the formula (I) or a salt thereof: wherein X is N or C-R 5 ; R 1 is C 1 -C 4 -alkyl or C 1 -C 4 -haloalkyl; R 2 is NR 6 R 7 or S(O) n R 8 ; R 3 is halogen, C 1 -C 4 -haloalkyl, C 1 -C 4 -haloalkoxy, SF 5 or S(O) p R 9 ; R 4 is hydrogen or halogen; R 5 is halogen; R 6 is hydrogen, C 1 -C 4 -alkyl, C 1 -C 4 -haloalkyl,C(O)R 10 , S(O) q CF 3 ; R 7 is hydrogen or C 1 -C 4 -alkyl, or R 6 and R 7 are joined so as together form a C 4 - C 6 -alkylene moiety, wherein one CH 2 -group may be replaced by oxygen or a radical N-R 11 ; R 8 , R 9 , R 10 , R 11 are each independently hydrogen, C 1 -C 4 -alkylorC 1 -C 4 -haloalkyl; m, n, p and q are each independently 0, 1 or 2; and at least one further pesticidally active compound II, selected from A.1GABA-gated chloride channel antagonists; A.2Nicotinic acetylcholine receptor agonists/antagonists A.3Juvenile hormone mimics; A.4Compounds affecting the oxidative phosphorylation; A.5Inhibitors of the chitin biosynthesis; A.6Moulting disruptors; A.7Mitochondrial electron transport inhibitors;. A.8Voltage-dependent sodium channel blockers; A.9Inhibitors of the lipid synthesis; and A.10group of various compounds.

    Abstract translation: 本发明涉及具有式（I）的至少一种3-乙酰基-1-苯基吡唑化合物或其盐的活性成分的杀虫组合物：其中X是N或C-R 5; R 1是C 1 -C 4 - 烷基或C 1 -C 4 - （C 1 -C 4）烷基或C 1 -C 4 - > - 卤代烷基; R 2是NR 6 R 7或S（O）n R 8， ; R 3是卤素，C 1 -C 4 - 卤代烷基，C 1 -C 4烷基， / SO 2 - 烷基，SF 5或S（O）n R 9。 R 4是氢或卤素; R 5是卤素; R 6是氢，C 1 -C 4 - 烷基，C 1 -C 4 - C（O）R 10，S（O）q CF 3 3， R 7是氢或C 1 -C 4 - 烷基，或R 6和R 7 连接在一起形成C 4 -C 6亚烷基部分，其中一个CH 2 - 亚基可以被取代 通过氧或自由基NR 11; R 9，R 9，R 10，R 11，各自独立地为氢，C 1〜 / SUB> -C 4 -alkylorC 1 -C 4 - 卤代烷基; m，n，p和q各自独立地为0,1或2; 和至少一种另外的选自A.1GABA门控氯化物通道拮抗剂的杀虫活性化合物II; A.2烟碱乙酰胆碱受体激动剂/拮抗剂A.3避孕激素模拟物; A.4影响氧化磷酸化的化合物; A.5壳多糖生物合成抑制剂 A.6造成破坏者 A.7线粒体电子传递抑制剂 A.8电压依赖性钠通道阻滞剂; A.9脂质合成抑制剂; 和A.10组各种化合物。

    METHOD FOR THE PRODUCTION OF HALOGEN-SUBSTITUTED 2-(AMINOMETHYLIDENE)-3- OXOBUTYRIC ACID ESTERS
    2.
    发明申请
    METHOD FOR THE PRODUCTION OF HALOGEN-SUBSTITUTED 2-(AMINOMETHYLIDENE)-3- OXOBUTYRIC ACID ESTERS 审中-公开
    用于生产方法卤素取代的2-（氨基亚甲基）-3-氧代丁酸

    公开(公告)号：WO2009133179A3

    公开(公告)日：2010-02-25

    申请号：PCT/EP2009055285

    申请日：2009-04-30

    Applicant: BASF SE ,  ZIERKE THOMAS ,  MAYWALD VOLKER ,  RACK MICHAEL ,  SMIDT SEBASTIAN PEER ,  KEIL MICHAEL ,  WOLF BERND ,  KORADIN CHRISTOPHER

    Inventor： ZIERKE THOMAS ,  MAYWALD VOLKER ,  RACK MICHAEL ,  SMIDT SEBASTIAN PEER ,  KEIL MICHAEL ,  WOLF BERND ,  KORADIN CHRISTOPHER

    IPC: C07D231/14 ,  C07D295/145

    CPC classification number: C07D295/145 ,  C07D231/14

    Abstract: The present invention relates to a method for producing 2- (aminomethylidene)-4,4dihalo-3-oxobutyric acid esters of the formula (I), where R1, R2, R3 are C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C3-C10-cycloalkyl or benzyl and/or R2 together with R3 and the nitrogen atom, to which both radicals are bound, are a heterocyclic radical, wherein a corresponding 3-aminoacrylic acid ester is reacted with a halogen-substituted acetyl fluoride in the presence of at least one alkali or earth alkali metal fluoride. The invention also relates to the further reaction of halogen-substituted 2-(aminomethylidene)-3-oxobutyric acid esters of the formula (1) into halomethyl-substituted pyrazole-4-ylcarboxylic acids and the esters thereof.

    Abstract translation: 本发明涉及2-（氨基 - 亚甲基）的制备方法中，式-4,4-二卤代-3-氧代丁酸酯（I）其中R1，R2，R3是C1-C6烷基，C1-C6卤代烷基 ，C2-C6链烯基，C3-C10环烷基或与R 3苄基和/或R 2在一起并到两个基团连接的氮原子代表的杂环基团，其中一个相应的3-氨基丙烯酸酯是具有 卤乙酰氟取代反应是在至少一种碱金属或碱土金属氟化物的存在; 和卤素 - 取代的2-（氨基亚甲基）-3-氧代丁酸的式（I）的酯的进一步反应卤代甲基取代的吡唑-4-基甲酸和它们的酯。

    METHOD FOR PREPARING 1,3,4-SUBSTITUTED PYRAZOL COMPOUNDS
    4.
    发明申请
    METHOD FOR PREPARING 1,3,4-SUBSTITUTED PYRAZOL COMPOUNDS 审中-公开
    用于生产取代1,3,4-吡唑

    公开(公告)号：WO2009135808A2

    公开(公告)日：2009-11-12

    申请号：PCT/EP2009055328

    申请日：2009-05-04

    Applicant: BASF SE ,  WOLF BERND ,  MAYWALD VOLKER ,  KEIL MICHAEL ,  KORADIN CHRISTOPHER ,  RACK MICHAEL ,  ZIERKE THOMAS ,  SUKOPP MARTIN

    Inventor： WOLF BERND ,  MAYWALD VOLKER ,  KEIL MICHAEL ,  KORADIN CHRISTOPHER ,  RACK MICHAEL ,  ZIERKE THOMAS ,  SUKOPP MARTIN

    IPC: C07D231/14

    CPC classification number: C07D409/12 ,  C07C251/76 ,  C07C251/84 ,  C07C251/86 ,  C07D231/14

    Abstract: The present invention relates to a method for preparing 1,3-substituted pyrazol compounds of formula (I), where X stands for a group CX1X2X3, with X1, X2 and X3 being hydrogen, fluorine or chlorine, independently of one another, R1 being an C1-C4 alkyl or cyclopropyl, and R2 being hydrogen, CN or a group CO2R2a, where R2a stands for C1-C6 alkyl in particular, comprising the following steps: i) reacting a compound of formula II with a hydrazone of formula (III), wherein in formula (II) the variables X and R2 have the same meaning as indicated for formula (I), Y stands for oxygen, a group NRy1 or a group [NRy2Ry3]+Z- , R3 stands for OR3a or a group NR3bR3c, and wherein in formula (III) the variable R1 has the same meaning as indicated for formula (I), R4 and R5 stand for hydrogen, C1-C6 alkyl, alternatively substituted phenyl, independent of one another, wherein at least one of the radicals R4 or R5 is different from hydrogen and where R4 and R5 can also stand for a 5 to 10-membered saturated carbocycle together with the carbon atom connected thereto; treatment of the reaction product obtained thereby with an acid in the presence of water.

    Abstract translation: 本发明涉及一种方法，用于制备1,3-取代的式（I），其中X是特别的一组CX1X2X3，其中X1，X2和X3独立地为特别是氢，氟或氯的吡唑化合物中，R1是C1 〜C 4烷基或环丙基，和R 2是氢，CN或基团CO2R2a，其中R 2a是特别C1-C6烷基，所述方法包括以下步骤：i）将式II的化合物与下式的腙反应 （III）其中在式（II）中，变量，X和R 2具有对式（I）所给出的含义，Y是氧，一组或一组NRy1 [NRy2Ry3] + Z-，R 3表示OR3a或一组NR3bR3c ，并且其中，在式（III）中，变量R1具有式（I）中给出的含义，R4和R5独立地是氢，C1-C6烷基，其任选被取代的苯基，其中至少一个基团 ëR4或R5是不同于氢，并且其中可以与它们所连接为一个5至10元饱和碳环，R4和R5的碳原子一起; 在水存在下用酸处理所得到的反应产物。

    PRODUCTION OF PYRIPYROPENES FROM DRY BIOMASS
    5.
    发明公开
    PRODUCTION OF PYRIPYROPENES FROM DRY BIOMASS 审中-公开
    HERSTELLUNG VON PYRIPYROPENEN AUS TROCKENER BIOMASSE

    公开(公告)号：EP2978852A4

    公开(公告)日：2016-10-26

    申请号：EP14774843

    申请日：2014-03-03

    Applicant: BASF SE

    Inventor： ERNST BURKHARD ,  EHRESMANN MANFRED ,  KORADIN CHRISTOPHER ,  PLETSCH ANDREAS ,  BONNEKESSEL MELANIE ,  KAEDING THOMAS ,  SCHEIN-ALBRECHT KARIN ,  DEMMING STEFANIE ,  WEBER FRANZ ,  SIEGEL WOLFGANG ,  SCHRÖDER HARTWIG ,  FREYER STEPHAN ,  ÖDMAN PETER

    IPC: C12P17/18 ,  A01N43/40

    CPC classification number: C07D493/04 ,  A01N43/40 ,  C12P17/181

    Abstract: The invention pertains to processes to produce dry biomass of pyripyropene producer organisms, processes to obtain pyripyropenes from such dry biomass, as well as to processes to produce compounds of Formula III and/or Formula IV and/or Formula V from the pyripyropenes obtained from the dry biomass. The invention does further pertain to the dry biomass itself, as well as processes using said dry biomass to obtain pyripyropenes for the production of compounds of Formula III and/or Formula IV and/or Formula V, including processes using said dry biomass to obtain pyripyropenes or compounds of Formula III and/or Formula IV and/or Formula V in order to produce pest control compositions, in particular insecticides, comprising such compounds.

    Abstract translation: 本发明涉及产生拟南芥生产生物体的干燥生物质的方法，从这种干燥生物质中获得拟南芥的方法，以及从得自二氯苯的方法得到式III和/或式IV和/或式V化合物的方法 干生物量。 本发明进一步涉及干生物质本身，以及使用所述干生物质获得用于生产式III和/或式IV和/或式V化合物的吡啶并入的方法，包括使用所述干生物质获得吡啶并吡喃 或式III和/或式IV和/或式V的化合物，以便制备包含这些化合物的害虫控制组合物，特别是杀虫剂。

    Method for preparing a pyripyropene compound
    10.
    发明专利
    Method for preparing a pyripyropene compound 未知

    公开(公告)号：AU2014206958B2

    公开(公告)日：2017-08-10

    申请号：AU2014206958

    申请日：2014-01-15

    Applicant: BASF SE

    Inventor： BONNEKESSEL MELANIE ,  REICHERT WOLFGANG ,  HOOCK RALF ,  KAEDING THOMAS ,  KORADIN CHRISTOPHER ,  PLETSCH ANDREAS ,  EHRESMANN MANFRED ,  SCHRODER HARTWIG

    IPC: C07D493/04 ,  A01N43/90

    Abstract: The present invention relates to a method for preparing the pyripyropene compound of the formula (I) which method comprises the following steps: i) subjecting a pyripyropene compound of formula Pyripyropene A to an alkaline hydrolysis to yield a 1,7,11-trideacetylpyripyropene A, ii) reacting 1,7,11-trideacetylpyripyropene A obtained in step i) with cyclopropane carbonyl chloride to yield a raw product containing the pyripyropene compound of formula (I); iii) subjecting the raw product of step ii) to crystallization to yield a crystalline pyripyropene compound of formula (I) and a mother liquor;and iv) recycling the mother liquor or a pyripyropene compound containing fraction thereof to the alkaline hydrolysis of step i).

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