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公开(公告)号:JP2000084417A
公开(公告)日:2000-03-28
申请号:JP23423699
申请日:1999-08-20
Applicant: DEGUSSA
Inventor: FOERSTER MARTIN DR , PIROTH JOSEF , SCHLACHTER ULRICH DR , DOMESLE RAINER DR , KRAMPE WILLI DR
Abstract: PROBLEM TO BE SOLVED: To apply aspiration impact and quickly separate an excess coating dispersion from air current used for aspirating and releasing a catalyst support by vertically orienting a cylindrical axis, supplying a prescribed amount of a coating dispersion to the upper end face of the support from a storage container, passing the dispersion through flow routes by aspiration, removing the excess coating dispersion from the flow routes by opening the flow routes in aspirating condition, turning back the excess dispersion to the storage container, and firmly fixing the dispersion coating by firing. SOLUTION: Flow routes of a catalyst support are coated by passing a coating dispersion at 0.1-1 m/s flow rate by aspiration, removing the excess coating dispersion from the flow routes by applying aspiration impact from a lower side on completion of the passing of the dispersion by aspiration while controlling aspirating air flow rate at 40-1 m/s through the flow routes and removing the excess coating dispersion discharged together with the air flow from the air flow in less than 100 ms after discharge out of the catalyst support.
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公开(公告)号:JPH11350945A
公开(公告)日:1999-12-21
申请号:JP8438999
申请日:1999-03-26
Applicant: DEGUSSA
Inventor: STREHLAU WOLFGANG DR , GOEBEL ULRICH , LOX EGBERT DR , MUELLER WILFRIED , DOMESLE RAINER DR
IPC: B01D53/86 , B01D53/94 , B01J21/16 , F01N3/08 , F01N3/10 , F01N3/20 , F01N3/24 , F01N3/28 , F01N9/00 , F01N13/02 , F02D41/02 , F02D41/14
Abstract: PROBLEM TO BE SOLVED: To achieve the operation method of the exhaust emission control device for the internal combustion engine which is operated at lean air/fuel ratio for the main course of its operation. SOLUTION: An exhaust emission control device incorporating a nitrogen oxides storage catalytic converter and a sulfur trap, wherein: a) at the excess air factor higher than 1 and an exhaust gas temperature TK within an activity window ΔTNOX, the nitrogen oxides and the sulfur oxides contained in the exhaust gas are respectively stored on the nitrogen oxides storage catalyst and the sulfur oxides storage catalyst while simultaneously maintaining the exhaust gas temperature TS lower than the desulfurization temperature TS. De SOx and periodically reducing the excess air factor of the exhaust gas below 1 to discharge the stored nitrogen oxides (completion of 1 adsorption cycle); b) after each completion of a predetermined number N1 of cycles of nitrogen oxides adsorption cycle, the exhaust gas temperature TS is raised to a level at or higher than the desulfurization temperature TS. De SOx of the sulfur trap to desulfurize the sulfur trap and to reduce the excess air factor of the exhaust gas to below 1. The process a) and the process b) are periodically repeated.
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公开(公告)号:JPH10141049A
公开(公告)日:1998-05-26
申请号:JP30179297
申请日:1997-11-04
Applicant: DEGUSSA
Inventor: GIESHOFF JUERGEN DR , DOMESLE RAINER DR , LOX EGBERT DR , KREUZER THOMAS DR
Abstract: PROBLEM TO BE SOLVED: To prevent damage to a catalyst due to high thermal load and arrange a converter near an engine by connecting the wall of a converter, which performs radiative exchange with the end of the catalyst, to at least one heat sink. SOLUTION: A converter with an air-heat exchanger 7 arranged at the end and an exhaust gas inlet tube 2 provided at the side has a converter casing 1 incorporated with a monolith catalyst 4. The air-heat exchanger 7 facing the inflow plane 5 of the catalyst 4 performs radiative exchange, not being substantially disturbed, to cool the inflow plane 5 of the catalyst 4. The monolith catalyst 2 is preferably formed into a disc shape with a largest possible sectional area to improve its heat radiation. As a heat exchanger, a water-heat exchanger instead of the air-heat exchanger can be used. The water-heat exchanger, if used, must be piped and connected to a cooling circuit existing in a vehicle.
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公开(公告)号:JP2002011353A
公开(公告)日:2002-01-15
申请号:JP2001143804
申请日:2001-05-14
Applicant: DMC2 DEGUSSA METALS CATALYSTS CERDEC AG
Inventor: DOMESLE RAINER DR , KREUZER THOMAS DR , LOX EGBERT DR
Abstract: PROBLEM TO BE SOLVED: To provide a ceramic honeycomb body for a catalyst for cleaning exhaust gas, which has a cylindrical form provided with first and second end surfaces and a cylindrical outer circumference surface, in which a plurality of passages penetrate in parallel in the axis direction from one end surface to the other, in which the passages formed by passage walls are arranged in a regular pattern over the cross section, of which the center portion is encircled by the outer edge portion of the honeycomb body having the thickness of the plurality of passage diameters, and of which the compression strength is improved in a radius direction. SOLUTION: Ceramic materials of the outer circumference surface of the cylinder and the passage walls in the region of the outer end of the honeycomb body are reinforced by adhering or inserting single or plural inorganic materials to enhance the mechanical stability.
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公开(公告)号:JP2001276627A
公开(公告)日:2001-10-09
申请号:JP2001056601
申请日:2001-03-01
Applicant: DMC2 DEGUSSA METALS CATALYSTS CERDEC AG
Inventor: DOMESLE RAINER DR , KLEIN HARALD DR , KREUZER THOMAS DR , LOX EGBERT DR
IPC: F01N3/10 , B01D53/94 , B01J21/12 , B01J23/38 , B01J23/40 , B01J23/42 , B01J23/46 , B01J29/068 , B01J29/12 , B01J31/16 , B01J37/02 , B01J37/10 , F01N3/022 , F01N3/28
Abstract: PROBLEM TO BE SOLVED: To provide a catalyst for cleaning the exhaust gas of an automobile diesel engine. SOLUTION: The catalyst contains at least one kind of zeolite and additionally at least one kind of carrier oxide consisting of aluminum oxide, silicon dioxide, titanium dioxide and aluminum silicate and at least one kind of noble metal consisting of platinum, palladium, rhodium and iridium, and an atom of noble metal has an average oxidation number smaller than +2.5, and the atom has a metal ligand larger than 3 in average and an oxygen ligand smaller than 3, and the noble metals exist on the zeolite and the carrier oxide in the form of the fine crystal having 1-6 nm average particle size.
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公开(公告)号:JP2000084405A
公开(公告)日:2000-03-28
申请号:JP23604899
申请日:1999-08-23
Applicant: DEGUSSA
Inventor: STREHLAU WOLFGANG DR , GOEBEL ULRICH , MUSSMANN LOTHAR DR , DOMESLE RAINER DR
IPC: B01D53/86 , B01D53/94 , B01J20/04 , B01J20/30 , B01J23/02 , B01J23/10 , B01J23/58 , B01J23/63 , B01J35/02 , B01J37/03 , F01N3/08 , F02B1/04
Abstract: PROBLEM TO BE SOLVED: To provide nitrogen oxides-accumulating material having high accumulation efficiency and aging stability. SOLUTION: In the nitrogen oxides-accumulating material containing at least one kind of accumulating constituents of nitrogen oxides in a form of particles of oxides of an alkaline earth metal and alkali metal, a mixed oxide, a carbonate or a hydroxide, on a support material of a high surface area, the support material is selected from doped cerium oxide, cerium/zirconium-mixed oxide, calcium titanate, strontium titanate, barium titanate, barium stannate, barium zirconate, magnesium oxide, lanthanum oxide, praseodymium oxide, samarium oxide, neodymium oxide, yttrium oxide, zirconium silicate, barium yttrium cuprite, lead titanate, tin titanate, bismuth titanate, lanthanum cobaltate, lanthanum manganate, barium cuprate, and their mixtures, and particles of the nitrogen oxides accumulating constituent have an average particle diameter less than 1.5 μm.
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公开(公告)号:JP2001219077A
公开(公告)日:2001-08-14
申请号:JP2000387371
申请日:2000-12-20
Applicant: DEGUSSA
Inventor: DOMESLE RAINER DR , KREUZER THOMAS DR , LOX EGBERT DR
IPC: B01D53/86 , B01J19/00 , B01J35/04 , B01J37/02 , B05D7/00 , C04B38/00 , C04B41/52 , C04B41/85 , C04B41/87 , F01N3/28
Abstract: PROBLEM TO BE SOLVED: To provide a method for coating a honeycomb body, particularly an unbalanced honeycomb body so that flow passage in the peripheral region of the honeycomb body are hardly clogged. SOLUTION: The ceramic honeycomb body, which has a cylindrical shape having the first end face, the second end face and a body wall surface and the passages parallel to the axis that are formed by penetrating passage walls from one end face to the other end face, is partially made wet and them coated with a suspension colloid by an adequate method.
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公开(公告)号:JP2000246105A
公开(公告)日:2000-09-12
申请号:JP2000051700
申请日:2000-02-28
Applicant: DEGUSSA
Inventor: DOMESLE RAINER DR , GOEBEL ULRICH , MUSSMANN LOTHAR , LOX EGBERT , KREUZER THOMAS DR
IPC: B01D53/94 , B01J23/00 , B01J23/54 , B01J23/58 , B01J23/63 , B01J35/04 , B01J35/10 , B01J37/02 , B01J37/025
Abstract: PROBLEM TO BE SOLVED: To obtain an aluminum oxide-base catalyst material having a high surface area and high dispersion of a catalytically active component, containing at least one basic oxide besides aluminum oxide and containing at least one noble metal belonging to the platinum group of the Periodic Table as the catalytically active component. SOLUTION: A support material stabilized with a basic oxide is loaded with another basic oxide by new impregnation with the oxide, the impregnated material is dried and calcined at
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公开(公告)号:JP2000117110A
公开(公告)日:2000-04-25
申请号:JP29014699
申请日:1999-10-12
Applicant: DEGUSSA
Inventor: STREHLAU WOLFGANG DR , GOEBEL ULRICH , DOMESLE RAINER DR
IPC: B01D53/94 , B01J23/58 , B01J23/63 , B01J27/053 , B01J27/055
Abstract: PROBLEM TO BE SOLVED: To increase a load of a stored compound by a method wherein in a nitrogen oxide storage catalyst containing a fine catalytic material and a nitrogen oxide storage constituent, the nitrogen oxide storage constituent is so provided as to exist as fine barium sulfate and strontium sulfate after end of manufacturing the catalyst. SOLUTION: In a nitrogen oxide storage catalyst wherein a catalyst so structured as to provide a cover 2 on an inactive support 1 to be used for purifying an exhaust gas of a lean engine or the like, contains fine catalytic materials 3, 4 and a nitrogen oxide storing constituent 5, the nitrogen oxide storing constituent 5 is so formed as to exist as fine barium sulfate, and strontium sulfate, after end of manufacturing the catalyst, further a mixture or a mixed crystal of both sulfates, or as a decomposition product having at most 1 μm in average particle size. As the material 3, an activated aluminum oxide activated by use of platinum is used, and as the material 4, a constituent for storing oxygen or cerium/zirconium mixed oxide activated by use of rhodium is used.
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公开(公告)号:JP2000061288A
公开(公告)日:2000-02-29
申请号:JP13021399
申请日:1999-05-11
Applicant: DEGUSSA
Inventor: FOERSTER MARTIN DR , GUTSCH ANDREAS DR , DOMESLE RAINER DR , KEISLING RALF , STOEHR OLIVER
IPC: B01J2/00 , B01J2/04 , B01J19/08 , B01J19/12 , B01J20/02 , B01J20/30 , B01J32/00 , B01J37/00 , C01B13/34 , C03B19/00 , C04B35/622
Abstract: PROBLEM TO BE SOLVED: To eliminate the loss of powder, to shorten the operation time of a plant and to eliminate risk to the quality of a product by introducing a reaction mixture into a flowing-through pipe, further treating the powder in the pipe and feeding it to a washer, separator or filter. SOLUTION: A dispersion, suspension or emulsion, secondary gas, combustion air and fuel are introduced into a burner 1. The resultant reaction mixture is introduced into a flowing-through pipe 2. An atmosphere of a reducing or oxidizing gas may be established in the flowing-through pipe 2. After passing through the pipe 2, the powder is treated in a washer 3 so as to prepare a dispersion or to prevent contact with air. The powder that leaves the pipe 2 may be separated by a separator 4 for simple treatment at a high temp. or may be separated using a filter 5 for long treatment at a high temp. Waste gas is discharged by a fan 6.
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