Abstract:
Alkali thiocyanates are prepared by reacting alkali cyanides with sulfur in the presence of alkali sulfide in a molar amount of 1:1000 to 1:2000 as a solubilizer for the sulfur. The reaction is carried out above the melting point of sulfur, preferably in an alkali thiocyanate solution. The alkali sulfide is then converted to the sulfate by oxidation with hydrogen peroxide.
Abstract:
The pastes are suitable for thick film technology and give a surface resistance advantageous for technical applications, even when fired without a protective gas atmos. The sulphides can be pptd. in very finely-divided form, obviating the need for grinding. A wide range of resistance values is possible (101 - 106 ohm/sq.) if noble metal(alloy) powder is incorporated and this also improves the temp. coefft., noise ration and long-term stability. Sulphides of Pd and Ru are pref.
Abstract:
Alkali thiocyanates are prepared by reacting alkali cyanides with sulfur in the presence of alkali sulfide in a molar amount of 1:1000 to 1:2000 as a solubilizer for the sulfur. The reaction is carried out above the melting point of sulfur, preferably in an alkali thiocyanate solution. The alkali sulfide is then converted to the sulfate by oxidation with hydrogen peroxide.
Abstract:
1,272,900. Alkali metal thiocyanates. DEUTSCHE GOLD UND SILBER SCHEIDEANSTALT. 6 Oct., 1970 [8 Oct., 1969], No. 47395/70. Heading C1A. An alkali metal thiocyanate is produced by reacting alkali metal cyanide and sulphur at a temperature above the m.pt. of sulphur (112À8‹ C.) in the presence of alkali metal sulphide used in a molar sulphide; sulphur ratio of from 1 : 1000 to 1 : 2000. The reaction is preferably carried out in a solution of the thiocyanate and in the presence of a wetting agent. On completion of the reaction, the sulphide may be oxidized to sulphate with H 2 O 2 and precipitated at BaSO 4 with BaCO 3 and filtered off. The solution may be concentrated to crystallize out, e.g. NaSCN.2H 2 O. The alkali metal may be Na or K.
Abstract:
Alkali thiocyanates are prepared by reacting alkali cyanides with sulfur in the presence of alkali sulfide in a molar amount of 1:1000 to 1:2000 as a solubilizer for the sulfur. The reaction is carried out above the melting point of sulfur, preferably in an alkali thiocyanate solution. The alkali sulfide is then converted to the sulfate by oxidation with hydrogen peroxide.