2.
    发明专利
    未知

    公开(公告)号:DE1950671A1

    公开(公告)日:1971-04-22

    申请号:DE1950671

    申请日:1969-10-08

    Applicant: DEGUSSA

    Abstract: Alkali thiocyanates are prepared by reacting alkali cyanides with sulfur in the presence of alkali sulfide in a molar amount of 1:1000 to 1:2000 as a solubilizer for the sulfur. The reaction is carried out above the melting point of sulfur, preferably in an alkali thiocyanate solution. The alkali sulfide is then converted to the sulfate by oxidation with hydrogen peroxide.

    PRODUCTION OF ALKALI METAL THIOCYANATES

    公开(公告)号:GB1272900A

    公开(公告)日:1972-05-03

    申请号:GB4739570

    申请日:1970-10-06

    Applicant: DEGUSSA

    Abstract: 1,272,900. Alkali metal thiocyanates. DEUTSCHE GOLD UND SILBER SCHEIDEANSTALT. 6 Oct., 1970 [8 Oct., 1969], No. 47395/70. Heading C1A. An alkali metal thiocyanate is produced by reacting alkali metal cyanide and sulphur at a temperature above the m.pt. of sulphur (112À8‹ C.) in the presence of alkali metal sulphide used in a molar sulphide; sulphur ratio of from 1 : 1000 to 1 : 2000. The reaction is preferably carried out in a solution of the thiocyanate and in the presence of a wetting agent. On completion of the reaction, the sulphide may be oxidized to sulphate with H 2 O 2 and precipitated at BaSO 4 with BaCO 3 and filtered off. The solution may be concentrated to crystallize out, e.g. NaSCN.2H 2 O. The alkali metal may be Na or K.

Patent Agency Ranking