公开(公告)号：JPH04200639A

公开(公告)日：1992-07-21

申请号：JP33435590

申请日：1990-11-29

Applicant: KAO CORP

Inventor： KAWAKAMI TAKAHIRO ,  MIURA HIROYUKI ,  HASHIBA IKIZOU ,  HATTORI YASUYUKI

IPC: B01J23/72 ,  B01J23/80 ,  B01J37/32 ,  C07B61/00 ,  C07C29/149

Abstract: PURPOSE:To obtain a catalyst having high activity and to produce an alcohol with high yield and high quality by carrying out the freeze drying in the process producing for catalyst precursor by using copper oxide or metallic oxide consisting essentially of copper oxide and a carrier. CONSTITUTION:A water soluble copper salt or mixture of a water soluble copper salt and a water soluble zinc salt reacts with an alkaline agent in an aqueous media in the presence of a carrier. When precipitate is washed, dried and burnt and the catalyst precursor is produced, freeze drying is carried out at about -50-0 deg.C and about 0.01-100Torr. Thus, obtained precipitate is kept as particulate state without solidifying to lumpy during washing or drying. Therefore, the highly active catalyst can be obtained, and when the alcohol is produced by hydrogenation of an organic carboxylic ester, high yield and high quality can be attained.

公开(公告)号：JPS61173791A

公开(公告)日：1986-08-05

申请号：JP1390385

申请日：1985-01-28

Applicant: KAO CORP

Inventor： TANIGAKI MASANOBU ,  WADA HIDETOSHI ,  SAKATA MASARU ,  HASHIBA IKIZOU

IPC: C12P7/64

Abstract: PURPOSE:To keep high decomposition ratio of fats and oils, to maintain enzyme activity and to continue a reaction stably for a long period, by hydrolyzing fats and oils with lipase while keeping always glycerin concentration in a water phase existing in a reaction system in a specific range. CONSTITUTION:In hydrolyzing fats and oils with lipase, glycerin concentration in a water phase existing in a reaction system is kept always at 10-40wt% to carry out the reaction. After the hydrolysis is over, the reaction mixture is separated into an oil layer, an emulsion layer and a water layer, the emulsion layer is taken out, used again for the following fats and oils hydrolysis, the enzyme dissolved in the water phase is concentrated and recovered from the water layer by the use of an ultrafilter, and preferably it is reused for the ensuring fats and oils hydrolysis.

公开(公告)号：JPS60126090A

公开(公告)日：1985-07-05

申请号：JP23092283

申请日：1983-12-07

Applicant: KAO CORP

Inventor： TANIGAKI MASANOBU ,  HASHIBA IKIZOU ,  WADA HIDETOSHI ,  SAKATA MASARU

IPC: C12P7/20 ,  C12P7/64

Abstract: PURPOSE:To prevent the inactivation of enzyme while keeping the degree of hydrolysis at a high level, and at the same time, to carry out the separation of the reaction product into glycerol and fatty acid, by pouring an oily phase containing lipase as a suspensoid in a cell, and an aqueous phase in the other cell separated from the oily phase cell with a separation membrane, and contacting the enzyme and oil with water through the membrane. CONSTITUTION:For example, the cellulose acetate membranes 1 and the gaskets 4 are arranged alternately in a reactor to form plural cells 11 partitioned from each other with the membranes 1. Water is supplied and circulated from the water-tank 5 through the pump 7 and the lines 9, 9' to the alternate cells 11. At the same time, the cells 11 adjacent to the cells supplied with water are supplied with lipase-suspended oil from the oil tank 6 with the pump 8 through the line 10, 10'. The flow rate of the oil phase and water phase is adjusted so as to apply about 0.2kg/cm pressure to the liquid phase. The oil in the oil phase is decomposed with lipase into glycerol and fatty acid, and the glycerol is transferred into the aqueous phase leaving the fatty acid in the oil phase.

公开(公告)号：JPS61236751A

公开(公告)日：1986-10-22

申请号：JP7777085

申请日：1985-04-12

Applicant: KAO CORP

Inventor： TORIMOTO YOSHIAKI ,  YOKOTA YUKINAGA ,  HASHIBA IKIZOU ,  MATSUTANI KAZUTO

IPC: C07C209/26 ,  C07C67/00 ,  C07C209/00 ,  C07C211/04 ,  C07C211/14 ,  C07C211/24

Abstract: PURPOSE:The reaction of a primary or secondary amine with formaldehyde is carried out under the pressure of hydrogen, then a primary or secondary amine is added to the reaction mixture and distillation is effected to obtain a tertiary amine which is readily purified with reduced discoloration and increased storage stability. CONSTITUTION:A primary or secondary amine and a hydrogenation catalyst are charged in a reactor, the mixture is stirred, as hydrogen is introduced into the reactor. When the hydrogen pressure and the temperature reach 3-20kg/cm G and 100-150 deg.C, respectively, formaldehyde, preferably 35-50% formalin, is continuously fed in a certain time to effect the reactions. After the completion of the reactions, the catalyst is filtered off, the filtrate is combined with a primary or secondary amine and they are heat treated and subjected to distilla tion to collect the tertiary amine. The amine which is added to the tiltrate is selected so that it has an appropriate difference in boiling point from the tertiary amine. EFFECT:The acid components such as formic acid which are formed in the reactions are varied by addition of amines to give the objective substance of lowered discoloration with the passage of time.

公开(公告)号：JPS61100196A

公开(公告)日：1986-05-19

申请号：JP22177284

申请日：1984-10-22

Applicant: Kao Corp

Inventor： TANIGAKI MASANOBU ,  HASHIBA IKIZOU ,  WADA HIDETOSHI ,  SAKATA MASARU

IPC: C12P7/64

Abstract: PURPOSE: To carry out the hydrolysis of an oil or fat in high rate of hydrolysis, without causing the deactivation of enzyme, by placing an oil or fat suspending a lipase to one side of a separation membrane, placing water to the other side, and contacting the oil with water through the membrane, wherein the water in the water-phase is made to react in the form of steam.
CONSTITUTION: An oil or fat suspending a lipase is placed to one side of a separation membrane, a water-phase is placed to the other side of the membrane, and the enzyme, the oil and the water are made to contact with each other through the membrane to effect the hydrolysis of the oil. In the above process, the water in the water-phase is made to react in the form of steam preferably by reducing the pressure. The pressure is preferably near or below the vapor pressure of water at the enzymatic reaction temperature.
COPYRIGHT: (C)1986,JPO&Japio

Abstract translation: 目的：以高水平的水解方式进行油脂的水解，不会引起酶的失活，通过将分离膜一侧的脂肪酶悬浮在油脂上，将水放置在另一侧， 使油与水通过膜接触，其中使水相中的水以蒸汽的形式反应。 构成：将分散膜的一侧放置脂肪酶的油脂，将水相置于膜的另一侧，使酶，油和水通过相互接触而通过 该膜进行油的水解。 在上述过程中，使水相中的水优选以蒸汽的形式进行反应，优选通过降低压力。 压力优选在酶反应温度下接近或低于水的蒸气压。

公开(公告)号：JPS5392395A

公开(公告)日：1978-08-14

申请号：JP705177

申请日：1977-01-25

Applicant: KAO CORP

Inventor： MIYA BUNJI ,  SAWAMOTO YUUJI ,  HASHIBA IKIZOU ,  HISAMITSU SHIZUO

IPC: C07D307/46 ,  B01J23/745 ,  B01J37/03 ,  C07B61/00 ,  C07C27/00 ,  C07C29/136 ,  C07C29/149 ,  C07C67/00

Abstract: PURPOSE:To obtain an easily separable catalyst with ferro-magnetism for reducing high press. hydrogen without discharging heavy metals in its production process by dissolving cupric, ferrous and aluminum salts in water and adding an alkali to the soln. at a temp. above 60 deg.C after which the resulting precipitate is separated, washed with water, dried, calcined, and pulverized.

公开(公告)号：JPH06313188A

公开(公告)日：1994-11-08

申请号：JP12548993

申请日：1993-04-28

Applicant: KAO CORP

Inventor： KAWAKAMI TAKAHIRO ,  TATSUMI NOBUHIRO ,  HIRAO MUNEKI ,  HASHIBA IKIZOU

IPC: C11C3/10

Abstract: PURPOSE:To produce a fatty acid ester simply in a high yield without pretreating free fatty acids contained in an oil or fat by reacting a triglyceride with an alcohol in the presence of a solid acid catalyst. CONSTITUTION:A fatty acid ester is produced by reacting a triglyceride (e.g. soy bean oil or beef tallow) with an alcohol (e. g. methanol) in the presence of a solid acid catalyst. Examples of the catalyst are a single or composite metal oxide (e.g. SiO2 Al2O3), a metal sulfate (e.g. aluminum sulfate), a synthetic zeolite, and an ion-exchange resin (e.g. a cation-exchange resin). The reaction, which may be of a batch-type or continuous, is pref. conducted by filling a fixed bed reactor with the catalyst and passing the triglyceride and the alcohol through the reactor at a liq. space velocity based on the triglyceride of 0.02-2/hr.

公开(公告)号：JPH05238970A

公开(公告)日：1993-09-17

申请号：JP23170591

申请日：1991-09-11

Applicant: KAO CORP

Inventor： TABATA OSAMU ,  MORI ATSUTO ,  KAWAKAMI TAKAHIRO ,  HASHIBA IKIZOU ,  TSUKADA KIYOSHI

IPC: C07B61/00 ,  C07C29/149 ,  C07C31/00 ,  C07C31/125

Abstract: PURPOSE:To produce a high-quality and high-purity alcohol reduced in hydrocarbons and aldehydes produced as by-products by improving a reaction ratio using two reactors and controlling the reaction temperature. CONSTITUTION:In a method for producing an alcohol by continuously passing a fatty acid ester, aliphatic acid triglyceride or fatty acid through a hydrogenation catalyst to carry out catalytic reduction reaction, two reactors consisting of a main reactor as the first reactor and the second reactor are arranged on upper stream side and lower stream side in series, and the reaction temperature in the main reactor is controlled so that the conversion degree at the outlet of the main reactor may be 20-100% and the hydrocarbon concentration as by-products may be

公开(公告)号：JPH04364140A

公开(公告)日：1992-12-16

申请号：JP23170491

申请日：1991-09-11

Applicant: KAO CORP

Inventor： TABATA OSAMU ,  HASHIBA IKIZOU ,  KAWAKAMI TAKAHIRO

IPC: B01J23/86 ,  C07B61/00 ,  C07C29/149 ,  C07C29/17 ,  C07C31/02 ,  C07C31/125

Abstract: PURPOSE:To provide a method for producing a fatty alcohol by continuously carrying out catalytic reduction of a fatty acid ester or a fatty acid triglyceride or a fatty acid in the presence of a hydrogenation catalyst. CONSTITUTION:A fatty acid ester, a fatty acid triglyceride or a fatty acid is continuously made to flow in the presence of a hydrogenation catalyst to produce a fatty alcohol by catalytic reduction. The aforementioned method is carried out by using a reactor that is a fixed bed reaction column in which a liquid phase and a vapor phase together are made to continuously flow in a downward cocurrent stream on the hydrogenation catalyst fixed in the interior of the reaction column and one or several means for cooling the reaction raw material are provided in the middle of the height direction in the above- mentioned reaction column. Thereby, the high-purity fatty alcohol can be produced in extremely high quality with hardly any hydrocarbons and aldehydes formed as by-products. Subsequent steps for removing the by-products can be omitted by the method of this invention.

公开(公告)号：JPH04295490A

公开(公告)日：1992-10-20

申请号：JP5859691

申请日：1991-03-22

Applicant: KAO CORP

Inventor： OKA KOJI ,  AIMONO KIYOSHI ,  TSUYUTANI SHINJI ,  HASHIBA IKIZOU

IPC: B01F17/56 ,  C07H15/04

Abstract: PURPOSE:To provide a process for the production of an alkylglycoside having minimized thermal history, capable of efficiently evaporating and removing excess unreacted higher alcohol to obtain the higher alcohol having sufficiently high quality to be usable for the production of alkylglycoside and effective for suppressing the facility cost to the lowest possible level. CONSTITUTION:An alkylglycoside containing unreacted higher alcohol is produced as a reaction product by directly reacting a sugar with a higher alcohol or reacting a sugar with a lower alcohol and then with a higher alcohol. The unreacted higher alcohol is removed from the reaction product using a spontaneous liquid film evaporator which does not necessitate mechanical force for the formation of liquid film. An alkylglycoside having unreacted higher alcohol content of