Catalyst component for the polymerization of olefins
    110.
    发明授权
    Catalyst component for the polymerization of olefins 有权
    用于烯烃聚合的催化剂组分

    公开(公告)号:US09587049B2

    公开(公告)日:2017-03-07

    申请号:US14380473

    申请日:2013-02-21

    CPC classification number: C08F110/06 C08F10/00 C08F4/651 C08F4/6565

    Abstract: The present invention relates to a catalyst component for polymerization of an olefin comprising a compound represented by the Fischer projection of: wherein R5 is substituted or unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R6 and R7 are different and independently selected from the group consisting of hydrogen, halogen and substituted or unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R5-R7 optionally containing one or more hetero-atoms replacing one or more carbon atoms, one or more hydrogen atom or both, wherein said hetero-atom is selected from the group consisting of nitrogen, oxygen, sulfur, silicon, phosphorus and halogen; and wherein the compound of Formula (I) is the only internal electron donor in the catalyst component. The present invention also relates to a process for preparing a polymerization catalyst component comprising the steps of i) contacting a compound R4zMgX2-z wherein R4 is aromatic, aliphatic or cyclo-aliphatic group containing 1 to 20 carbon atoms, X is a halide, and z is in a range of larger than 0 and smaller than 2, with an alkoxy- or aryloxy-containing silane compound to give a first intermediate reaction product; ii) contacting the first intermediate reaction product with at least one activating compound selected from the group formed by internal electron donors and compounds of formula M(OR2)v-w(R3)w, wherein M can be Ti, Zr, Hf, Al or Si, each R2 and R3, independently, represent an alkyl, alkenyl or aryl group, v is the valency of M and w is smaller than v and iii) contacting the second intermediate reaction product with a halogen-containing Ti-compound and an internal electron donor represented by the Fischer projection of formula (I); and optionally with at least one compound selected from a group comprising a monoester, a diester and a 1,3-diether.

    Abstract translation: 本发明涉及一种用于聚合烯烃的催化剂组分,其包含由Fischer投影表示的化合物:其中R5是取代或未取代的具有1至20个碳原子的烃基; R6和R7不同且独立地选自氢,卤素和具有1至20个碳原子的取代或未取代的烃基; 任选地含有一个或多个取代一个或多个碳原子的杂原子,一个或多个氢原子或两者的R 5 -R 7,其中所述杂原子选自氮,氧,硫,硅,磷和卤素; 并且其中式(I)的化合物是催化剂组分中唯一的内电子给体。 本发明还涉及一种制备聚合催化剂组分的方法,包括以下步骤:i)使化合物R4zMgX2-z与其中R4是芳族的,含有1至20个碳原子的脂族或环脂族基团,X是卤化物,和 z在大于0且小于2的范围内,与含烷氧基或芳氧基的硅烷化合物反应得到第一中间反应产物; ii)使第一中间反应产物与至少一种选自由内电子给体形成的基团和式M(OR 2)vw(R 3)w)的化合物接触,其中M可以是Ti,Zr,Hf,Al或Si ,每个R 2和R 3独立地表示烷基,烯基或芳基,v是M的化合价,w小于v,和iii)使第二中间体反应产物与含卤素的Ti化合物和内部电子 由式(I)的费舍尔投影表示的供体; 和任选地与至少一种选自包含单酯,二酯和1,3-二醚的化合物。

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