公开(公告)号：US06861385B2

公开(公告)日：2005-03-01

申请号：US10182037

申请日：2001-12-04

Applicant: Arrigo Arletti ,  Anna Fait

Inventor： Arrigo Arletti ,  Anna Fait

IPC: B01J27/138 ,  B01J35/08 ,  B01J37/00 ,  C01F5/30 ,  C08F4/02 ,  C08F4/614 ,  C08F10/00 ,  C08F110/06 ,  B01J31/00

CPC classification number: C08F10/00 ,  B01J27/138 ,  B01J35/08 ,  B01J37/0072 ,  C08F110/06 ,  C08F4/6545 ,  C08F4/022 ,  C08F2500/18 ,  C08F2500/24

Abstract: A process for preparing spherical support particles used in the preparation of catalytic components for the polymerization of olefins by (a) forming an emulsion of an adduct of a Mg dihalide and a Lewis base compound in a liquid medium, and (b) cooling the emulsion by transferring it into a cooling bath containing a cooling liquid in motion wherein the cooling liquid is moving inside a tubular zone and the ratio Ve/Vref of the velocity (Ve) of the emulsion coming from step (a) to the velocity of the cooling liquid (Vref) of step (b) is between 0.25 and 4. The resulting spherical support particles have a very narrow size distribution and particularly regular morphology.

Abstract translation: （a）在液体介质中形成二氢卤化镁和路易斯碱化合物的加合物的乳液，以及（b）冷却该乳液的制备用于制备用于烯烃聚合的催化组分的球形载体颗粒的方法 通过将其转移到包含运动中的冷却液体的冷却浴中，其中冷却液体在管状区域内移动，并且来自步骤（a）的乳液的速度（Ve）的比Ve / Vref与冷却速度 步骤（b）的液体（Vref）在0.25和4之间。所得的球形载体颗粒具有非常窄的尺寸分布和特别规则的形态。

公开(公告)号：US20040208811A1

公开(公告)日：2004-10-21

申请号：US10478408

申请日：2004-06-07

Inventor： Kjell Anflo ,  Jesper Brandt ,  Ola Lyckfeldt

IPC: C01F017/00

CPC classification number: C04B35/44 ,  B01J2/06 ,  B01J21/04 ,  B01J23/02 ,  B01J23/10 ,  B01J23/34 ,  B01J23/468 ,  B01J35/002 ,  B01J35/023 ,  B01J35/08 ,  B01J35/109 ,  B01J37/0018 ,  B01J37/0072 ,  B01J37/033 ,  C01F7/16 ,  C01F17/0025 ,  C01P2004/50 ,  C01P2006/13 ,  C04B35/634 ,  C04B2235/3205 ,  C04B2235/3217 ,  C04B2235/3224 ,  C04B2235/3227 ,  C04B2235/3262 ,  C04B2235/441 ,  C04B2235/443 ,  C04B2235/5409 ,  C04B2235/72 ,  C06D5/08

Abstract: A method of preparing spherical pellets from a slurry comprising a ceramic powder, a solvent, and any desired additives, by means of a drop-generating orifice to which said slurry is fed is described, wherein the drops are released from said orifice by means of a relative flow of a liquid medium which is a poor solvent for the solvent of the slurry, formed into spherical bodies in said liquid medium by means of the action of surface tension, and thereafter treated for consolidation. More specifically, the present invention relates to the preparation of pellets of a catalyst or catalyst support material, suitable for use in high temperature conditions.

Abstract translation: 描述了一种通过借助于所述浆料被供给的液滴产生孔口从包含陶瓷粉末，溶剂和任何所需添加剂的浆料制备球形颗粒的方法，其中所述液滴通过 作为浆料溶剂的不良溶剂的液体介质的相对流动，通过表面张力的作用在所述液体介质中形成球形体，然后处理固结。 更具体地说，本发明涉及适用于高温条件下的催化剂或催化剂载体材料颗粒的制备。

公开(公告)号：US06783569B2

公开(公告)日：2004-08-31

申请号：US09991464

申请日：2001-11-21

Applicant: Jin Woo Cheon ,  Jong Il Park

Inventor： Jin Woo Cheon ,  Jong Il Park

IPC: B22F916

CPC classification number: B82Y30/00 ,  B01J13/02 ,  B01J23/75 ,  B01J23/8913 ,  B01J35/0006 ,  B01J35/0013 ,  B01J35/08 ,  B22F1/0018 ,  B22F1/025 ,  B22F9/24 ,  B82Y25/00 ,  C23C16/4417 ,  G11B5/65 ,  G11B5/85 ,  H01F1/0054 ,  H01F1/0063 ,  Y10T428/2984

Abstract: Disclosed is a method for producing core-shell type metallic nanoparticles involving (i) providing a dispersion of a first metal as nanoparticles in an appropriate organic solvent; (ii) providing a solution of a metallic precursor containing a second metal in an appropriate organic solvent, in which the second metal has a reduction potential higher than that of the first metal; and (iii) combining the dispersion from (i) and the solution from (ii) together to carry out the transmetalation reaction of the first and second metals, thereby forming core-shell type metallic nanoparticles.

Abstract translation: 公开了一种生产核 - 壳型金属纳米颗粒的方法，其包括（i）提供作为纳米颗粒的第一金属在合适的有机溶剂中的分散体; （ii）在合适的有机溶剂中提供含有第二金属的金属前体溶液，其中第二金属的还原电位高于第一金属的还原电位; 和（iii）将来自（i）的分散体与来自（ii）的溶液结合在一起，进行第一和第二金属的转化反应，从而形成核 - 壳型金属纳米粒子。

公开(公告)号：US20040116723A1

公开(公告)日：2004-06-17

申请号：US10720905

申请日：2003-11-24

Inventor： Johannes Petrus Van Der Linden ,  Eduardus Petrus Simon Schouten

IPC: B01J027/06 ,  B01J027/135 ,  C07D301/06

CPC classification number: C07D301/19 ,  B01J21/063 ,  B01J21/08 ,  B01J31/0274 ,  B01J31/38 ,  B01J33/00 ,  B01J35/023 ,  B01J35/08 ,  B01J37/0209 ,  B01J37/0238 ,  B01J37/10 ,  B01J2231/72 ,  C07D301/12 ,  C07D303/04

Abstract: The invention relates to a process for the preparation of an epoxidation catalyst, which process involves impregnating a silicon containing carrier with a gas stream consisting of titanium halide. The invention also relates to a process for the preparation of alkylene oxide using such catalyst.

Abstract translation: 本发明涉及制备环氧化催化剂的方法，该方法包括用由卤化钛组成的气流浸渍含硅载体。 本发明还涉及使用这种催化剂制备环氧烷烃的方法。

公开(公告)号：US20040077911A1

公开(公告)日：2004-04-22

申请号：US10274693

申请日：2002-10-18

Inventor： Guy B. Woodle ,  Andrew S. Zarchy ,  Jeffery C. Bricker ,  Andrzej Z. Ringwelski

IPC: C07C002/64 ,  B01J027/224 ,  C07C004/06 ,  C07C002/68

CPC classification number: C10G45/62 ,  B01D53/86 ,  B01J21/04 ,  B01J23/005 ,  B01J23/58 ,  B01J23/60 ,  B01J23/62 ,  B01J23/626 ,  B01J23/63 ,  B01J23/6447 ,  B01J23/6567 ,  B01J35/0006 ,  B01J35/023 ,  B01J35/08 ,  B01J37/0009 ,  B01J37/0219 ,  B01J37/0221 ,  B01J37/0223 ,  B01J37/0236 ,  B01J37/024 ,  B01J37/0242 ,  B01J37/0248 ,  C01B5/00 ,  C07C5/48 ,  C10G29/205 ,  C10G45/00 ,  C10G2300/1096 ,  C10G2400/30 ,  C07C15/46

Abstract: A catalyst for the selective oxidation of hydrogen has been developed. It comprises an inert core such as cordierite and an outer layer comprising a lithium aluminate support. The support has dispersed thereon a platinum group metal and a promoter metal, e.g. platinum and tin respectively. This catalyst is particularly effective in the selective oxidation of hydrogen in a dehydrogenation process.

Abstract translation: 已经开发了用于选择性氧化氢的催化剂。 它包括惰性核心如堇青石和包含铝酸锂载体的外层。 载体上分散有铂族金属和助催化剂金属，例如， 铂和锡分别。 该催化剂在脱氢过程中对氢的选择性氧化特别有效。

公开(公告)号：US20040076563A1

公开(公告)日：2004-04-22

申请号：US10470362

申请日：2003-12-02

Inventor： Masayoshi Kitada

IPC: B01J019/08

CPC classification number: B01J19/08 ,  B01D53/8668 ,  B01J7/00 ,  B01J8/02 ,  B01J8/18 ,  B01J15/005 ,  B01J16/005 ,  B01J19/18 ,  B01J19/1806 ,  B01J19/2405 ,  B01J19/2475 ,  B01J19/2485 ,  B01J19/249 ,  B01J19/30 ,  B01J35/023 ,  B01J35/04 ,  B01J35/08 ,  B01J2208/00867 ,  B01J2219/185 ,  B01J2219/1923 ,  B01J2219/1943 ,  B01J2219/2453 ,  B01J2219/2458 ,  B01J2219/2467 ,  B01J2219/2477 ,  B01J2219/2482 ,  B01J2219/30207 ,  B01J2219/30211 ,  B01J2219/30215 ,  B01J2219/30219 ,  B01J2219/30242 ,  B01J2219/30296 ,  B01J2219/32296 ,  C01B3/04 ,  C01B3/042 ,  C01B3/26 ,  C02F1/005 ,  C02F1/02 ,  C02F1/70 ,  C02F1/722 ,  C10G15/00 ,  Y02E60/364

Abstract: Particles constituted of either a single element selected from the group consisting of silicon, titanium, nickel, and samarium or a carbon fluoride are disposed in such respective positions that the wave energy inherent in the element or carbon fluoride is amplified to thereby enable the particles to have, among these, a field where energy concentration occurs. Thus, an active structure is obtained which is capable of generating hydrogen by liberating hydrogen from the hydrogen bonds of water or a hydrocarbon without applying an external energy thereto.

Abstract translation: 从由硅，钛，镍和钐或氟化碳组成的组中选择的单一元素构成的颗粒被设置在这样的位置，即元素或氟化碳中固有的波能被放大，从而使颗粒能够 其中包括能量集中发生的领域。 因此，获得能够通过从水或烃的氢键释放氢而不向其施加外部能量而产生氢的活性结构。

公开(公告)号：US06673235B2

公开(公告)日：2004-01-06

申请号：US10164488

申请日：2002-06-06

Applicant: David H. Harris ,  Mingting Xu ,  David Stockwell ,  Rostam J. Madon

Inventor： David H. Harris ,  Mingting Xu ,  David Stockwell ,  Rostam J. Madon

IPC: B01J2908

CPC classification number: C10G11/05 ,  B01J21/16 ,  B01J29/06 ,  B01J29/084 ,  B01J29/088 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/08 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1066 ,  B01J35/1071 ,  B01J35/1076 ,  B01J35/108 ,  B01J37/0045 ,  B01J37/0246 ,  B01J2229/42 ,  B01J2229/64 ,  C10G2300/107

Abstract: A fluid catalytic cracking catalyst made from microspheres that initially contain kaolin, a dispersible boehmite alumina and a sodium silicate or silica sol binder. The kaolin portion contains hydrous kaolin and a particular kaolin which has been calcined through its characteristic exotherm and which produces a catalyst having a novel morphology comprising a macroporous matrix and crystallized zeolite freely coating the walls of the pores of the matrix. Calcination of the hydrous kaolin to metakaolin and formation of in-situ zeolite by treatment with sodium silicate yields a catalyst containing Y-faujasite and transforms the dispersible boehmite into a transitional alumina. The catalyst can be used to crack resid or resid-containing feeds as the alumina phase formed from the dispersible boehmite passivates nickel and vanadium contaminants.

Abstract translation: 由微球制成的流化催化裂化催化剂，其最初含有高岭土，可分散勃姆石氧化铝和硅酸钠或硅溶胶粘结剂。 高岭土部分含有含水高岭土和通过其特征放热煅烧的特定高岭土，并且其产生具有新颖形态的催化剂，其具有包含大孔基质和自由涂覆基质孔壁的结晶沸石。 通过用硅酸钠处理将含水高岭土煅烧成偏高岭土并形成原位沸石，产生含有Y型八面沸石的催化剂，并将可分散的勃姆石转化为过渡型氧化铝。 该催化剂可用于裂解残渣或渣油进料，因为由可分散勃姆石形成的氧化铝相钝化镍和钒污染物。

公开(公告)号：US20030203812A1

公开(公告)日：2003-10-30

申请号：US10425590

申请日：2003-04-29

Inventor： Daniel Ostgard ,  Monika Berweiler ,  Karsten Seelbach

IPC: B01J025/00

CPC classification number: C07C227/02 ,  B01J25/00 ,  B01J35/026 ,  B01J35/08 ,  B01J37/0018 ,  B01J37/0221 ,  B01J37/08 ,  C07C45/002 ,  C07C229/16

Abstract: A fixed bed Raney copper catalyst, which is doped with iron, noble metals or other metals, is employed as the fixed bed catalyst in the fixed bed dehydrogenation of alcohols.

公开(公告)号：US06623974B1

公开(公告)日：2003-09-23

申请号：US09532459

申请日：2000-03-23

Applicant: Martin Horan ,  Seamus O'Mahony

Inventor： Martin Horan ,  Seamus O'Mahony

IPC: G01N3300

CPC classification number: G01N33/1846 ,  B01J35/08 ,  C02F1/78 ,  G01N31/005 ,  Y10T436/203332 ,  Y10T436/204998 ,  Y10T436/206664 ,  Y10T436/23 ,  Y10T436/235

Abstract: The invention provides an ozone hydroxy radical analysis method for a liquid carrying a suspension of organic matter. The analyser includes a reactor vessel 2 having sample inlets and outlets 3 and 4 respectively for a liquid stream 5. The reactor vessel 2 is connected to a control system 10 and is fed from an acid vessel 15, a base vessel 16 and an ozone generator 20. The reactor vessel 2 contains glass beads and a catalyst is introduced into the reactor vessel. With a manganese catalyst and glass beads, the manganese coats the glass beads which therefore retain catalyst with the reactor vessel.

Abstract translation: 本发明提供了一种用于携带有机物悬浮液的液体的臭氧羟基自由基分析方法。 分析仪包括反应容器2，其具有分别用于液体流5的样品入口和出口3和4.反应器容器2连接到控制系统10，并从酸性容器15，基底容器16和臭氧发生器 反应容器2包含玻璃珠，并将催化剂引入反应器容器中。 使用锰催化剂和玻璃珠，锰涂覆玻璃珠，因此保留催化剂与反应器容器。

公开(公告)号：US20030139624A1

公开(公告)日：2003-07-24

申请号：US10336755

申请日：2003-01-06

Applicant: BP Chemicals Limited

Inventor： Michael James Baker ,  John William Couves ,  Kenneth George Griffin ,  Peter Johnston ,  James Colin McNicol ,  George Frederick Salem

IPC: B01J023/44 ,  C07C067/05

CPC classification number: B01J37/0201 ,  B01J35/0006 ,  B01J35/08 ,  C07C67/055 ,  C07C69/01 ,  C07C69/15

Abstract: A process for preparing a supported metal catalyst composition which comprises impregnating microspheroidal support particles with a solution of at least one catalytically active metal, or precursor, drying the impregnated support particles and then treating the mobile metal, or precursor in a mobile state with a liquid comprising at least one reducing agent to deposit and immobilize the metal, or its precursor, in the support particles such that the metal, or its precursor, is distributed in the support particle in a layer below the surface of the support particle, the layer being between an inner and an outer region having a lower concentration of metal or precursor. Also, a composition comprising microspheroidal support particles having at least one catalytically active metal or precursor thereof distributed in a layer below the surface of the particles, the layer being between an inner and an outer region of the support particle each having a lower concentration of metal or precursor.